Relationship between footwall composition,crustal contamination,and fluid–rock interaction in the Platreef,Bushveld Complex,South Africa

In the northern limb of the 2.06-Ga Bushveld Complex, the Platreef is a platinum group elements (PGE)-, Cu-, and Ni-mineralized zone of pyroxenite that developed at the intrusion margin. From north to south, the footwall rocks of the Platreef change from Archaean granite to dolomite, hornfels, and quartzite. Where the footwall is granite, the Sr-isotope system is more strongly perturbed than where the footwall is Sr-poor dolomite, in which samples show an approximate isochron relationship. The Nd-isotope system for samples of pyroxenite and hanging wall norite shows an approximate isochron relationship with an implied age of 2.17 ± 0.2 Ga and initial Nd-isotope ratio of 0.5095. Assuming an age of 2.06 Ga, the ɛNd values range from −6.2 to −9.6 (ave. −7.8, n = 17) and on average are slightly more negative than the Main Zone of the Bushveld. These data are consistent with local contamination of an already contaminated magma of Main Zone composition. The similarity in isotope composition between the Platreef pyroxenites and the hanging wall norites suggests a common origin. Where the country rock is dolomite, the Platreef has generally higher plagioclase and pyroxene δ ¹⁸O values, and this indicates assimilation of the immediate footwall. Throughout the Platreef, there is considerable petrographic evidence for sub-solidus interaction with fluids, and the Δ _{plagioclase–pyroxene} values range from −2 to +6, which indicates interaction at both high and low temperatures. Whole-rock and mineral δD values suggest that the Platreef interacted with both magmatic and meteoric water, and the lack of disturbance to the Sr-isotope system suggests that fluid–rock interaction took place soon after emplacement. Where the footwall is granite, less negative δD values suggest a greater involvement of meteoric water. Consistently higher values of Δ _{plagioclase–pyroxene} in the Platreef pyroxenites and hanging wall norites in contact with dolomite suggest prolonged interaction with CO₂-rich fluid derived from decarbonation of the footwall rocks. The overprint of post crystallization fluid–rock interaction is the probable cause of the previously documented lack of correlation between PGE and sulfide content on the small scale. The Platreef in contact with dolomite is the focus of the highest PGE grades, and this suggests that dolomite contamination played a role in PGE concentration and deposition, but the exact link remains obscure. It is a possibility that the CO₂ produced by decarbonation of assimilated dolomite enhanced the process of PGE scavenging by sulfide precipitation.     

The intertidal erosion rate of cohesive sediment: a case study from Long Island Sound

Over the past decades, many attempts have been made to generate useful bottom erosion models for the study of cohesive sediment movement. This study addresses some of the key questions involved in determining the functional relationship between erosion rate and bottom shear stress. Current, wave, and turbidity data were collected from a bottom mounted instrument array in a moderately energetic estuarine environment. The bottom shear stress was calculated from a wave–current interaction model. The erosion rate was derived from the observed sediment concentration using a vertical mixing model. Examination of the relationship between erosion rate and bottom stress showed that the erosion rate varied at intertidal frequency. When averaged over the tidal fluctuation, the erosion rate remained approximately constant at low stress, but increased sharply when the shear stress rose above a critical value. This suggests two-stage erosion. The bed has a layered structure, in which a thin layer of loose, high water content material overlies a more consolidated bed. The top layer of high water content material (fluff) was easily disturbed and re-suspended by tidal currents, but the consolidated bottom layer was eroded only under conditions of high shear stress.     

Mechanism for the rapid motion of the Qianjiangping landslide during reactivation by the first impoundment of the Three Gorges Dam reservoir, China

The first impoundment of the Three Gorges Dam reservoir in China started from a water surface elevation of 95 m on June 1, 2003 and reached 135 m on June 15, 2003. Shortly after the water level reached 135 m, many slopes began to deform and some landslides occurred. The Qianjiangping landslide is the largest one; it occurred on the early morning of July 14, 2003 and caused great loss of lives and property. Field investigation revealed that, although failure occurred after the reservoir reached 135 m, the stability of the slope was already reduced by preexisting sheared bedding planes. To study the mechanism of the rapid motion of this reactivated landslide, two soil samples were taken from a yellow clay layer and a black silt layer in the sliding zone, respectively, and a series of ring shear tests were conducted on the samples. One series of ring shear tests simulates the creep deformation behavior, while the other series simulates different shear rates. Conclusions drawn from analysis of the ring shear tests indicate that the mechanism of the rapid motion of the reactivated landslide was caused by the rate effect of the black silt layer during the motion phase after the creep failure. The yellow clay layer did not play any important role in the rapid motion in the 2003 event.     

Evolution of cool skin and direct air-sea gas transfer coefficient during daytime

Absorption of solar radiation within the thermal molecular sublayer of the ocean can modify the temperature difference across the cool skin as well as the air-sea gas transfer. Our model of renewal type is based on the assumption that the thermal and diffusive molecular sublayers below the ocean surface undergo cyclic growth and destruction, the heat and gas transfer between the successive burst events are performed by molecular diffusion. The model has been upgraded to include heating due to solar radiation. The renewal time is parameterized as a function of the surface Richardson number and the Keulegan number. A Rayleigh number criterion characterizes the convective instability of the cool skin under solar heating. Under low wind speed conditions, the solar heating can damp the convective instability, strongly increasing the renewal time and correspondingly decreasing the interfacial gas exchange. In the ocean, an additional convective instability caused by salinity flux due to evaporation becomes of importance in such cases. The new parameterization is compared with the cool skin data obtained in the western equatorial Pacific during the Tropical Ocean Global Atmosphere Coupled Ocean Atmosphere Response Experiment in February 1993. In combination with a model of the diurnal thermocline it describes main features of the field data both in nighttime and daytime. Under low wind speed conditions (< 5 m s^-1) diurnal variations of the sea surface temperature due to the formation of a diurnal thermocline were substantially larger than those across the cool skin. Under wind speeds > 5 m s^-1, diurnal variations of the surface temperature due to the variations of the thermal molecular sublayer become more important.     

Hydrogeochemical evolution of groundwater in a Mediterranean coastal aquifer, Mersin-Erdemli basin (Turkey)

In this study, hydrogeologic and hydrochemical information from the Mersin-Erdemli groundwater system were integrated and used to determine the main factors and mechanisms controlling the chemistry of groundwaters in the area and anthropogenic factors presently affecting them. The PHREEQC geochemical modeling demonstrated that relatively few phases are required to derive water chemistry in the area. In a broad sense, the reactions responsible for the hydrochemical evolution in the area fall into four categories: (1) silicate weathering reactions; (2) dissolution of salts; (3) precipitation of calcite, amorphous silica and kaolinite; (4) ion exchange. As determined by multivariate statistical analysis, anthropogenic factors show seasonality in the area where most contaminated waters related to fertilizer and fungicide applications that occur during early summer season.     

Soluble organic compounds in fog and cloud droplets: what have we learned over the past few years?

We have recently set up a new procedure for characterising the water soluble organic compounds (WSOC) in fog water, for which information is still rather limited. Fog samples collected during the 1998–1999 fall–winter season in the Po Valley (Italy) were analysed following this procedure, which allows a quantitative determination of three main classes of organic compounds (neutral species, mono- and di-carboxylic acids, polycarboxylic acids), together accounting for ca. 85% of the total WSOC. This procedure also provides information on the main chemical characteristics of these three classes of compounds (functional groups, aliphatic vs. aromatic character, etc.). The enhanced chemical knowledge on fog/cloud chemical composition opens new scenarios as far as chemical and microphysical processes in clouds and fogs are concerned.     

Effect of asymmetry and irregularity of seismic waves on earthquake-induced differential settlement of buildings on natural subsoil

The effect of asymmetry and irregularity of the inputted seismic waves on the earthquake-induced differential settlement of the buildings on natural subsoil is investigated in terms of the earthquake damage phenomena, theoretical analyses, dynamic triaxial tests and shaking table tests. A conclusion can be drawn from the investigation results that, the asymmetrical and irregular character of the inputted seismic waves themselves may have a significant contribution to the differential settlement of subsoil and buildings in some cases, and this is a necessary factor to be considered in reasonable evaluation for the differential settlement and other problems relating to the soil deformation due to earthquakes.     

Inelastic dynamic analysis of RC bridges accounting for spatial variability of ground motion,site effects and soil–structure interaction phenomena. Part 1: Methodology and analytical tools

During strong ground motion it is expected that extended structures (such as bridges) are subjected to excitation that varies along their longitudinal axis in terms of arrival time, amplitude and frequency content, a fact primarily attributed to the wave passage effect, the loss of coherency and the role of local site conditions. Furthermore, the foundation interacts with the soil and the superstructure, thus significantly affecting the dynamic response of the bridge. A general methodology is therefore set up and implemented into a computer code for deriving sets of appropriately modified time histories and spring–dashpot coefficients at each support of a bridge with account for spatial variability, local site conditions and soil–foundation–superstructure interaction, for the purposes of inelastic dynamic analysis of RC bridges. In order to validate the methodology and code developed, each stage of the proposed procedure is verified using recorded data, finite‐element analyses, alternative computer programs, previous research studies, and closed‐form solutions wherever available. The results establish an adequate degree of confidence in the use of the proposed methodology and code in further parametric analyses and seismic design. Copyright © 2003 John Wiley & Sons, Ltd.     

流体地质作用的构造效应

许多事实证明，在地壳及地球深部存在着大量的流体，它们以气体、液体、熔融体等形式存在于地球内部不同深度处。这些流体的活动在地壳及岩石圈运动演化过程中扮演着十分重要的角色，其作用贯穿于地壳与岩石圈运动演化的全过程，地球表面形成的各种构造与流体作用的参与有着密切的联系。