雾化进样石墨炉原子吸收光谱法的研究 Ⅰ.直接雾化进样装置及其性能

介绍一种自行设计和加工的直接雾化石墨炉进样装置的结构、工作原理和操作方法。该装置由微机控制与石墨炉加热程序同步工作,可以实现自动控制和自动测量。对雾化进样石墨炉分析的仪器参数和实验条件进行了研究和选择。结果表明,该装置与石墨炉结合具有自动化程度高、重现性好、样品利用率高和分析速度快等特点。     

The Agulhas Ridge, South Atlantic: The Peculiar Structure of a Fracture Zone

The Agulhas Ridge is a prominent topographic feature that parallels the Agulhas-Falkland Fracture Zone (AFFZ). Seismic reflection and wide angle/refraction data have led to the classification of this feature as a transverse ridge. Changes in spreading rate and direction associated with ridge jumps, combined with asymmetric spreading within the Agulhas Basin, modified the stress field across the fracture zone. Moreover, passing the Agulhas Ridge’s location between 80 and 69 Ma, the Bouvet and Shona Hotspots may have supplied excess material to this part of the AFFZ thus altering the ridge’s structure. The low crustal velocities and overthickened crust of the northern Agulhas Ridge segment indicate a possible continental affinity that suggests it may be formed by a small continental sliver, which was severed off the Maurice Ewing Bank during the opening of the South Atlantic. In early Oligocene times the Agulhas Ridge was tectono-magmatically reactivated, as documented by the presence of basement highs disturbing and disrupting the sedimentary column in the Cape Basin. We consider the Discovery Hotspot, which distributes plume material southwards across the AAFZ, as a source for the magmatic material.     

The Vema Transverse Ridge (Central Atlantic)

Transverse ridges are elongate reliefs running parallel and adjacent to transform/fracture zones offsetting mid-ocean ridges. A major transverse ridge runs adjacent to the Vema transform (Central Atlantic), that offsets the Mid-Atlantic Ridge by 320 km. Multibeam morphobathymetric coverage of the entire Vema Transverse ridge shows it is an elongated (300 km), narrow (<30 km at the base) relief that constitutes a topographic anomaly rising up to 4 km above the predicted thermal contraction level. Morphology and lithology suggest that the Vema Transverse ridge is an uplifted sliver of oceanic lithosphere. Topographic and lithological asymmetry indicate that the transverse ridge was formed by flexure of a lithospheric sliver, uncoupled on its northern side by the transform fault. The transverse ridge can be subdivided in segments bound by topographic discontinuities that are probably fault-controlled, suggesting some differential uplift and/or tilting of the different segments. Two of the segments are capped by shallow water carbonate platforms, that formed about 3–4 m.y. ago, at which time the crust of the transverse ridge was close to sea level. Sampling by submersible and dredging indicates that a relatively undisturbed section of oceanic lithosphere is exposed on the northern slope of the transverse ridge. Preliminary studies of mantle-derived ultramafic rocks from this section suggest temporal variations in mantle composition. An inactive fracture zone scarp (Lema fracture zone) was mapped south of the Vema Transverse ridge. Based on morphology, a fossil RTI was identified about 80 km west of the presently active RTI, suggesting that a ridge jump might have occurred about 2.2 m.a. Most probable causes for the formation of the Vema Transverse ridge are vertical motions of lithospheric slivers due to small changes in the direction of spreading of the plates bordering the Vema Fracture Zone.     

塞曼石墨炉原子吸收法直接测定海水中的铜

本文选择酒石酸消除海水基体对铜信号的干扰,用塞曼石墨炉原子吸收法直接测定海水中的铜。从Cu的原子化曲线可知,加入酒石酸后,背景值减小,Cu原子吸收信号增强,且出现时间提前,表明酒石酸是有效的海水基体改进剂。用P.E.Z3030光谱仪测得双蒸水及海水中的元素Cu的特征质量(m。)分别为12.5pg及12.7pg;检测限分别为0.18μg/L和0.19μg/L,表明基体效应已消除,符合海洋监测要求。可用纯Cu标准溶液作校正曲线,以国家海洋局的两个标准海水样品中的Cu评定本法的准确度,相对偏差为0及-4.6%,与经典的经富集后的FAAS法的结果相比,相对偏差在3.0—6.5％范围内。用不同类型的光谱仪测定了30个海水样品,回收率在89—104％范围内。本法操作简便、快速。     

塞曼石墨炉原子吸收法直接测定海水中的铬

海水基体对Cr有增感作用。本文研究了抗坏血酸、柠檬酸三铵、酒石酸、乙酸铵等有机基体改进剂对消除基体干扰效果。前二者均有效地消除基体干扰,但1％抗坏血酸 1％柠檬酸三铵混合试剂的效果更好,它不仅可以消除基体干扰,还可降低背景及噪声,Cr的吸收峰也较平滑。本法准确,相对偏差在0.7—4.4％范围内。回收率在92—109％范围内。若海水Cr含量低于定量下限时,可采用多次进样法。     

烟台市污水处理深海排放工程设计方案研究与选择

沿海城市污水处理深海排放工程在我国起步较晚，烟台市污水处理深海排放工程我国目前规模最大的同类工程，且已进入施工阶段，本文详细阐述了该工程及水工设计方案，在我国城市污水２深海排放工程领域作了积极有益的探索。     

垦71区块井间地震资料处理研究与应用

由于避开了地表低降速带和风化层的影响,井间地震能够采集到高频地震信号,经过资料处理可以得到较高分辨率的速度和上行反射波成像剖面。2004～2005年,胜利油田在垦71 区块实施了8对井间地震资料采集。针对原始资料特点,研究了以层析成像、管波衰减、VSP-CDP技术和有限角度叠加成像等关键处理技术,较好地完成了该区块的井间地震资料处理。初步分析解释表明,井间地震可以识别低序级断层、小幅度构造和薄储层。     

DSQ型水管倾斜仪电压灵敏度的调整技巧

DSQ型水管倾斜仪是“九五”期间推出的数字化地震前兆仪器，本文介绍了一些如何调整换能器的电压灵敏度及调整中的技巧。     

ISO-834标准火灾作用后钢管混凝土的轴压刚度和抗弯刚度

火灾后钢管混凝土的轴压刚度和抗弯刚度是钢管混凝土结构变形性能和抗震分析的重要指标，也是火灾后钢管混凝土修复和加固的重要依据之一，本文利用数值方法计算了标准火灾作用后钢管混凝土轴压构件和纯弯构件荷载-变形关系曲线，分析了受火时间、材料强度、含钢率、截面尺寸等因素的影响规律，最后推导了标准火灾作用后钢管混凝土轴压刚度和抗弯刚度的简化计算公式，所得结果可供有关钢管混凝土结构工程设计时参考。     

河南郑州台数字化DSQ水管倾斜仪观测精度的评定

选取了河南郑州台数字化 DSQ型水管倾斜仪观测资料较好的 2 0 0 1年 10月 1日至 12月 31日的数据进行了分析处理 ,对该仪器的观测精度进行了评定。经计算 ,其北南向和东西向日飘移分别为 0 .0 0 0 7s和 0 .0 0 2 6 s,M2 的振幅因子为 0 .714 9和 0 .6 4 14 ,振幅因子中误差为 0 .0 0 5 5和0 .0 0 4 4。