Proterozoic fluvial styles: response to changes in accommodation space (Rivieradal sandstones, eastern North Greenland)

Fluvial styles recorded by the uppermost part of the Neoproterozoic ‘Rivieradal sandstones' succession of eastern North Greenland reflect variations in rate of generated accommodation space and possibly climatic changes. Three facies associations, arranged in two genetic sequences, are recognised within the succession. The lower sequence initially records little available accommodation space. A high degree of reworking results in sheet-like, high-energy, bed-load-dominated, braided river deposits lacking recurrent facies patterns. As accommodation space increases upwards through the sequence, reduction in reworking is recorded by the development of fining- and thickening-upward muddy fluvial cycles. Evidence of desiccation or prolonged periods of drought are absent within the deposits and climate was probably relatively humid. Channel deposits in the lower sequence reflect mixed-load, braided fluvial systems with stable channel banks and floodplains, and the gradient appears to have been low to moderate. These features are generally considered favourable for the establishment of meandering river systems, but channels, nevertheless, retained an overall braided character and their deposits show no evidence of meandering. Despite indications of a climatic setting without significant periods of drought sediments indicate that large fluctuations in discharge occurred within the mixed-load streams and this is suggested to be the main cause for the absence of meandering. The swift and rather dramatic response of the fluvial systems to changes in precipitation, probably resulted from rapid runoff rates caused by the absence of vegetation. The upper sequence shows an initial return to shallow, sandy braided river deposition recording little available accommodation space. A subsequent increase in the rate of generated accommodation space is indicated by the presence of alternating sheet sandstones and sand-streaked mudstones with abundant desiccation cracks. The sheet sandstones show evidence of high-energy, unconfined ephemeral fluvial flash-flood deposition, while the mudstones are interpreted to represent muddy floodplain deposits. The change in fluvial style, combined with the widespread evidence of desiccation, suggest an evolution towards a more semi-arid climate in the upper sequence. This climatic change could account for the reduced clastic input seen in the overlying marine succession which culminated in carbonate platform deposition. The present study suggests that even under conditions considered favourable for the formation of meandering streams, these will rarely occur in Proterozoic deposits due to the lacking influence of vegetation. Although meandering deposits cannot be ruled out as having formed in pre-vegetational times, the conditions for their formation appear to have been even more restricted than previously realised.     

Controls on spatial and temporal distribution of Precambrian eolianites

Inversely graded stratification, generated by the migration of wind ripples, and adhesion structures permit unequivocal identification of Precambrian eolianites. These criteria, in combination with scale of cross-beds, angle of inclination of foresets, geometry of depositional units, and associated non-eolian facies, are used to discriminate between Precambrian dune/draa, dune-plinth, sand-sheet, and interdune deposits that formed in inland and coastal settings. Based on an analysis of published literature, fundamental conclusions can be drawn on the spatial and temporal distribution of Precambrian eolianites. The oldest reported eolianites are from the ca. 2.1 Ga Deweras Group in Zimbabwe and Hurwitz Group in Canada and numerous examples of eolianites are reported from the 1.8 Ga and younger rock record. Lack of Archean and early Paleoproterozoic eolianites and their widespread development after 1.8 Ga are examined with respect to: absence of vegetation, crustal growth and tectonic setting, relative sea-level fluctuations, unfavorable atmospheric and/or climatic change, and non-recognition. The lack of pre-2.2 Ga eolianites may be related to reworking by braided rivers combing across non-vegetated floodplains, reworking of coastal eolianites during transgression or their non-recognition in the Early Precambrian record. The temporal concentration of eolianites at 1.8 Ga may best be related to the early stages of breakup and the assembly phases of supercontinents.     

Preservation of pre-vegetational mixed fluvio–aeolian deposits in a humid climatic setting: an example from the Middle Proterozoic Eriksfjord Formation, Southwest Greenland

Sedimentological studies of a 30 m thick coastal cliff section within the Middle Proterozoic Eriksfjord Formation in western South Greenland reveals three distinct types of fluvial sand sheet deposits that reflect perennial streams (Type I), semi-perennial streams (Type II), and ephemeral flash floods (Type III). Perennial river sand sheets are characterised by co-sets of medium-scale trough cross-beds, interbedded with isolated medium- and large-scale, high-angle, tabular cross-beds. Indications of desiccation or subaerial exposure are absent. Semi-perennial fluvial sand sheets consist predominantly of low-angle cross-beds, interbedded with isolated sets of high-angle tabular cross-beds with common reactivation surfaces. Horizontal lamination and climbing ripple lamination form subordinate structures. Associated with the sand sheets are adhesion structures and 0.05–0.4 m thick sets of wind ripple-lamination indicating periods of subaerial exposure and aeolian reworking. High-energy ephemeral flash flood sand sheets consist almost exclusively of planar-parallel lamination and climbing ripple lamination with some isolated sets of low-angle cross-bedding. Scouring and internal truncation surfaces are common. The three types of sand sheets are considered to reflect deposition under changing climatic conditions, varying from humid to arid or semi-arid. Aeolian deposits are preserved within the sand sheets showing characteristics of dominantly perennial flow punctuated by shorter periods of desiccation (Type II), while sand sheets showing features typical of arid and or semi-arid flow conditions (Type III) contain no preserved aeolian deposits. This selective preservation is interpreted to be a result of the combined effect of groundwater table level and fluvial style which in turn are inferred to have been controlled by the climatic regime. The deposits show that during pre-vegetational times the preservation of aeolian deposits, under certain conditions, may be more optimal in fluvial systems formed in a humid climate than in fluvial systems formed under semi-arid or arid circumstances. The occurrence of aeolian deposits within a Precambrian succession of fluvial deposits therefore, need not be an indication of the most arid environmental conditions.     

Precambrian tidal and glacial clastic deposits: implications for Precambrian Earth–Moon dynamics and palaeoclimate

Over the past decade the study of Precambrian clastic tidal rhythmites — stacked laminae of sandstone, siltstone and mudstone that display periodic variations in thickness reflecting a strong tidal influence on sedimentation — has provided accurate palaeotidal and palaeorotational data. Palaeotidal records obtained from tidal rhythmites may be systematically abbreviated, however, and derived periods and frequencies can be misleading. The validity of such values, including past length of day, can be assessed by testing for internal self-consistency through application of the laws of celestial mechanics. Such a test supports the estimated length of day of h derived from the late Neoproterozoic (620 Ma) Elatina–Reynella rhythmites in South Australia, and the indicated mean rate of lunar retreat of cm/year since 620 Ma. The validity of estimated lengths of day obtained from other Precambrian tidal rhythmites remain unverified because the data sets contain only one primary value directly determined from the rhythmites. The Elatina–Reynella data militate against significant Earth expansion at least since 620 Ma, and suggest that the free nutation or ‘tipping' of the Earth's fluid core has undergone a resonance with the Earth's annual forced nutation since the Neoproterozoic. Glaciogenic deposits are readily distinguishable from ejecta resulting from impacts with Earth-crossing bodies. Palaeomagnetic data, based on the geocentric axial dipole model for the geomagnetic field, indicate that Neoproterozoic and Palaeoproterozoic glaciation and cold climate near sea level occurred in low palaeolatitudes. This enigmatic finding may imply global glaciation or an increased obliquity of the ecliptic, and is relevant to modelling the effect of ice sheet formation on the Earth's obliquity history by obliquity–oblateness feedback mechanisms. Through multidisciplinary studies, clastic sedimentology and geophysics together can make substantial contributions to understanding Precambrian Earth–Moon dynamics and global palaeoenvironments.     

Elemental mercury concentrations and formation rates in the Scheldt estuary and the North Sea

Concentrations of Hg⁰ in surface waters and atmosphere of the Scheldt estuary and the North Sea are presented and their relationship with biological processes is discussed. Hg⁰ concentrations in the Scheldt estuary range from 0.1 to 0.38 pmol·l⁻¹ in the winter and from 0.24 to 0.65 pmol·l⁻¹ in the summer and show a positive relationship with phytoplankton pigments. In the North Sea Hg⁰ concentrations range from 0.06 to 0.8 pmol·l⁻¹ and are higher in coastal stations. Transfer velocities across the air–sea interface were calculated using a classical shear turbulence model. Volatilization fluxes of Hg⁰ were calculated for the Scheldt estuary and the North Sea. For the Scheldt estuary the fluxes range from 226–284 pmol·m⁻²·d⁻¹ in winter and 500–701 pmol·m⁻²·d⁻¹ in summer and for the North Sea the fluxes range from 59–1110 pmol·m⁻²·d⁻¹ for an average windspeed of 8.1 m·s⁻¹. These fluxes are comparable to the wet and dry depositional fluxes to the North Sea. Hg⁰ formation rates necessary to balance the volatilization fluxes vary from 0.2 to 4% d⁻¹.     

超声心动图联合64排CT心血管造影在法洛四联症诊断中的应用研究

目的:通过对比单纯超声心动图和超声心动图联合64排CT心血管造影对肺动脉狭窄部位的诊断准确性,对肺动脉主干、左、右肺动脉内径、右心室流出道内径以及患儿肺血管发育情况的预测准确率,并通过相关性分析说明超声心动图和64排CT心血管造影两种方法对左右心室各指标测量结果的密切相关性,从而阐明联合应用两种方法在提高法洛四联症心血管成像诊断准确率中的重要意义。方法:分别采用超声心动图和超声心动图联合64排CT心血管造影诊断肺动脉狭窄部位以及评价患儿肺血管发育情况,并与手术后实际诊断结果比较;采用超声心动图和超声心动图联合64排CT心血管造影测量肺动脉主干、左、右肺动脉内径以及右心室流出道内径,并与手术后实际测得结果比较;相关性分析说明超声心动图和64排CT心血管造影两种方法对左右心室各指标测量结果的相关情况。结果:超声心动图联合64排CT心血管造影诊断肺动脉狭窄部位的准确率为91.5%,明显高于单纯超声心动图的准确率68.1%(P<0.05);联合诊断组所测得Me Goon指数、Nakata指数、肺动脉主干、左、右肺动脉内径以及右心室流出道内径与手术组实测结果间无明显统计学差异(P>0.05),而超声心动图与手术实测结果相比有明显统计学差异(P<0.05);超声心动图和64排CT心血管造影对左右心室各指标测量结果均呈现密切相关性(r>0.7,P<0.05)。结论:单纯超声心动图和64排CT心血管造影在诊断法洛四联症病变方面呈现密切相关性,但超声心动图联合64排CT心血管造影对法洛四联症(TOF)病变情况的诊断准确率明显高于单纯超声心动图,为临床上法洛四联症心血管成像提供了新的思路。      

Lithic types in ignimbrites as a guide to the evolution of a caldera complex, Taupo volcanic centre, New Zealand

Taupo volcanic centre is one of two active rhyolite centres in the Taupo Volcanic Zone (TVZ), and has been sporadically active over the past ca. 300 ka. At least four large-scale ignimbrites have erupted from the centre, including the well documented 26.5 ka Oruanui ignimbrite and 1.8 ka Taupo ignimbrite. Because stratigraphy of earlier ignimbrites and their sources are masked by later volcanism, disrupted by regional tectonics and obscured by poor exposure, indirect methods must be applied in order to determine their source regions. In this paper detailed componentry, density and petrology of lithic fragments from three ignimbrites (Rangatira Point, Oruanui, Taupo) are used to reveal aspects of the sub-Taupo caldera geology, including the evolution of the Taupo volcanic centre, to assist in ignimbrite correlation and to evaluate structures within the Taupo caldera complex. Lithic fragments identify a complex subsurface geology. The Rangatira Point ignimbrite sampled dominantly rhyolite lavas, plus a variety of welded ignimbrites, rare high-silica dacites and a single dolerite. Most lithic fragments in the Oruanui ignimbrite are andesite with minor rhyolite, welded ignimbrite, dacite and rounded greywacke, while in the Taupo ignimbrite, rhyolite is again the dominant lithic component with subordinate welded ignimbrites, andesite, and greywacke. The densities of lithic fragments indicate similar ranges of values for all lava types, and thus density is a poor indicator of lithology. Care must, therefore, be taken before interpreting subcrustal stratigraphy using density as the sole criterion. The petrography and geochemistry of lithic types are more specific, and the variation can be used to identify sources for the ignimbrites. Both pumice chemistry and rhyolite lithic fragments from the Rangatira Point ignimbrite are comparable to domes exposed at the southern end of the Western Dome Complex and, combined with limited outcrop information, suggest the most likely source for this unit is in the northern part of the Taupo caldera complex. The dominance of andesite lithic fragments in the Oruanui ignimbrite suggests a major andesite cone existed beneath the source area, and the different lithic suites between Oruanui and Taupo ignimbrites suggest these ignimbrites came, at least in part, from mutually exclusive collapse structures. We believe that the Oruanui caldera is sited principally in the northwestern part of present-day Lake Taupo and the Taupo caldera in the northeastern part. Identification of abundant ignimbrite lithics in the Taupo ignimbrite, which are considered to represent an intracaldera facies of an earlier ignimbrite, that is not exposed at the surface, suggest there was a further (pre-Oruanui) ignimbrite caldera in the Taupo ignimbrite eruptive vent region.     

Measuring N–NH4 in marine, estuarine and fresh waters: An adaptation of the ammonia diffusion method for samples with low ammonium concentrations

We present a method for measuring ¹⁵N–NH₄⁺ in marine, estuarine and fresh waters. The advantage of this method is that it is broadly applicable to all types of water and it allows measurements in samples with lower ammonium concentrations than has previously been possible. The procedure is a modification of the ammonia diffusion method and uses large sample volumes (often 4 l) to obtain sufficient N for isotope ratio mass spectrometric analysis. Large volume samples have not previously been used with the diffusion procedure because isotopic fractionation occurs due to incomplete recovery of ammonium. However, the method we present accounts for this fractionation and allows precise correction of measured δ¹⁵N values.     

Possible indicators of microbial mat deposits in shales and sandstones: examples from the Mid-Proterozoic Belt Supergroup, Montana, U.S.A.

It has been suspected for some time that microbial mats probably colonized sediment surfaces in many terrigenous clastic sedimentary environments during the Proterozoic. However, domination of mat morphology by depositional processes, post-depositional compaction, and poor potential for cellular preservation of mat-building organisms make their positive identification a formidable challenge. Within terrigenous clastics of the Mid-Proterozoic Belt Supergroup, a variety of sedimentary structures and textural features have been observed that can be interpreted as the result of microbial colonization of sediment surfaces. Among these are: (a) domal buildups resembling stromatolites in carbonates; (b) cohesive behaviour of laminae during soft-sediment deformation, erosion, and transport; (c) wavy–crinkly character of laminae; (d) bed surfaces with pustular–wrinkled appearance; (e) rippled patches on otherwise smooth surfaces; (f) laminae with mica enrichment and/or randomly oriented micas; (g) irregular, curved–wrinkled impressions on bedding planes; (h) uparched laminae near mud-cracks resembling growth ridges of polygonal stromatolites; and (i) lamina-specific distribution of certain early diagenetic minerals (dolomite, ferroan carbonates, pyrite). Although in none of the described examples can it irrefutably be proven that they are microbial mat deposits, the observed features are consistent with such an interpretation and should be considered indicators of possible microbial mat presence in other Proterozoic sequences.