‘We are managing!’ Uncertain paths to respectable adulthoods in Accra, Ghana

Studies have shown that the life experiences and future prospects of young people in many parts of the world today are more complex and less predictable than those of past generations. This has led to a recognition of the need to reconsider the conceptual frameworks applied in youth studies. Thus far, research within geography has mainly focused on young people’s paths to adulthood in the Global North or on particularly vulnerable children’s lives in the Global South. In this paper an approach based on the ‘social navigation’ of ‘vital conjunctures’ is adopted to explore the complex ways in which young people in Ghana navigate their way through life in a city marked by economic hardship and neo-liberal reform. The stories of three young people are presented to show the variety of life conditions, the complex social positions they occupy and their various and shifting future imaginations. The actions of these young people are steered by prevailing cultural ideals and social expectations of what a desirable and respectable future entails and by the actual space of possibility in the urban space they move through. It is argued that achieving respectable adulthoods in present-day Accra is a complicated and convoluted journey involving the careful management of social relationships.     

Computational study of tetrahedral Al–Si and octahedral Al–Mg ordering in phengite

 As part of a wider study of the nature and origins of cation order–disorder in micas, a variety of computational techniques have been used to investigate the nature of tetrahedral and octahedral ordering in phengite, K₂ ^[6](Al₃Mg)^[4](Si₇Al)O₂₀(OH)₄. Values of the atomic exchange interaction parameters J _n used to model the energies of order–disorder were calculated. Both tetrahedral Al–Si and octahedral Al–Mg ordering were studied and hence three types of interaction parameter were necessary: for T–T, O–O and T–O interactions (where T denotes tetrahedral sites and O denotes octahedral sites). Values for the T–T and O–O interactions were taken from results on other systems, whilst we calculated new values for the T–O interactions. We have demonstrated that modelling the octahedral and tetrahedral sheets alone and independently produces different results from modelling a whole T–O–T layer, hence justifying the inclusion of the T–O interactions. Simulations of a whole T–O–T layer of phengite indicated the presence of short-range order, but no long-range order was observed. Received: 8 August 2002 / Accepted: 14 February 2003 Acknowledgements The authors are grateful to EPSRC (EJP) and the Royal Society (CIS) for financial support. Monte Carlo simulations were performed on the Mineral Physics Group's Beowulf cluster and the University of Cambridge's High Performance Computing Facility.     

Geographies of energy transition: the case of high-performing commercial office space in the central business districts of Sydney and Melbourne,Australia

As a signatory to the Paris Climate Agreement, Australia committed to reduce emissions significantly by 2030. In a country highly urbanised and dependent on fossil fuels as its primary energy source, one key avenue for meeting these commitments is energy transition in the built environment. Australia has emerged as a leader in the design and construction of high-performance buildings in the premium commercial office sector. In this paper, we address a significant gap in understanding the diverse mechanisms through which building energy transition is being constituted in this sector, focusing on Sydney and Melbourne. In the absence of substantive publicly available data, we draw on mixed methods comprising a database developed around high-performing CBD office buildings and qualitative interviews with a range of sectoral stakeholders. We characterise the building stock in each city, and document five trends constituting energy transitions. We demonstrate that building energy transitions are not only shaped purposefully by dominant governance regimes but also by opportunistic responses to specific material and commercial conditions and legacies in each city. Thus the urban built environment affords significant opportunity for energy transitions, but pathways towards such transitions are necessarily multiple and ultimately shaped by material as well as institutional geographies.     

Phase transitions in perturbed stiff-fluid Friedmann-Robertson-Walker cosmological models

We consider one-soliton perturbations of a flat Friedmann-Robertson-Walker (FRW) cosmological model, with an ideal fluid with pressure equal to the energy density (stiff fluid), in the case where the “pole trajectory” parameter is negative, introducing thereby singularities along certain null hypersurfaces. Starting with a metric that approaches asymptotically the FR W background, we show that it is possible to construct an extension through these hypersurfaces such that the energy momentum tensor T_ab is finite and satisfies the energy conditions. The extension is only C₁, providing a sort of “shock front” with continuity in T_ab, that has an associated phase transition from null dust to stiff fluid, the transition being of the form described by CHANDRASEKHAR and XANTHOPOULOS.     

Latent heat effects of the major mantle phase transitions on low-angle subduction

Very low to zero shallow dip angles are observed at several moderately young subduction zones with an active trenchward moving overriding plate. We have investigated the effects of latent heat for this situation, where mantle material is pushed through the major mantle phase transitions during shallow low-angle subduction below the overriding plate. The significance of the buoyancy forces, arising from the latent heat effects, on the dynamics of the shallowly subducting slab is examined by numerical modeling. When a 32-Ma-old slab is overridden with 2.5 cm/yr by a continent, flat subduction occurs with a 4–5 cm/yr convergence rate. When latent heat is included in the model, forced downwellings cause a thermal anomaly and consequently thermal and phase buoyancy forces. Under these circumstances, the flat slab segment subducts horizontally about 350 km further and for about 11 Ma longer than in the case without latent heat, before it breaks through the 400-km phase transition. The style of subduction strongly depends on the mantle rheology: increasing the mantle viscosity by one order of magnitude can change the style of subduction from steep to shallow. Similarly, an overriding velocity of less than 1 cm/yr leads to steep subduction, which gradually changes to flat subduction when increasing the overriding velocity. However, these model parameters do not change the aforementioned effect of the latent heat, provided that low-angle subduction occurs. In all models latent heat resulted in a substantial increase of the flat slab length by 300–400 km. Varying the olivine–spinel transition Clapeyron slope γ from 1 to 6 MPa/K reveals a roughly linear relation between γ and the horizontal length of the slab. Based on these results, we conclude that buoyancy forces due to latent heat of phase transitions play an important role in low-angle subduction below an overriding plate.     

Electronic absorption spectra of Fe2+ ions in oxygen-based rock-forming minerals at temperatures between 297 and 600 K

 Polarized electronic single crystal spectra of natural Fe²⁺ ion-bearing oxygen-based minerals, in which ferrous ions enter octahedral sites of different symmetry and distortion (olivine, cordierite, ortho- and clinopyroxene, amphibole), eightfold sites in garnet (almandine) and clinopyroxene (M2), and tetrahedral sites in spinel, were studied at temperatures from 300 to ca. 600 K. In the minerals studied, the spin-allowed bands of Fe²⁺ display rather variable temperature behaviour. In most cases, due to the thermal expansion of the Fe²⁺-bearing polyhedra, bands shift to lower energies upon increasing temperature, though there are some exceptions to this rule: in cases of other than sixfold octahedral or close to octahedral coordination, in almandine and spinel the bands shift to higher energies, which can be explained by an increase in distortions of the Fe²⁺-bearing polyhedra. Splitting of the excited ⁵ E _g-level of Fe²⁺ ions usually, but not always, increases with temperature, reflecting thermally induced increase in distortion of the Fe²⁺-bearing sites in the minerals studied. Integral intensities of the bands in question do not always obey the general rule, according to which intensity should increase with temperature, when the 3d ^N-centred site is centrosymmetric, or should remain unchanged when the 3d ^N site lacks an inversion centre. The experimental results show that the response of the characteristics of absorption bands such as width, intensity and energy caused by dd transitions of Fe²⁺ in oxygen-based minerals to increasing temperature is not always uniform and is at variance with expectation. This temperature dependence cannot be used directly to solve band assignment problems, as earlier proposed in the literature. Received: 22 December 1999 / Accepted: 30 October 2000     

Public values for energy system change

In this paper we discuss the importance of framing the question of public acceptance of sustainable energy transitions in terms of values and a ‘whole-system’ lens. This assertion is based on findings arising from a major research project examining public values, attitudes and acceptability with regards to whole energy system change using a mixed-method (six deliberative workshops, n = 68, and a nationally representative survey, n = 2441), interdisciplinary approach. Through the research we identify a set of social values associated with desirable energy futures in the UK, where the values represent identifiable cultural resources people draw on to guide their preference formation about particular aspects of energy system change. As such, we characterise public perspectives as being underpinned by six value clusters relating to efficiency and wastefulness, environment and nature, security and stability, social justice and fairness, autonomy and power, and processes and change. We argue that this ‘value system’ provides a basis for understanding core reasons for public acceptance or rejection of different energy system aspects and processes. We conclude that a focus on values that underpin more specific preferences for energy system change brings insights that could provide a basis for improved dialogue, more robust decision-making, and for anticipating likely points of conflict in energy transitions.