A modified numerical model for moisture-salt transport in unsaturated sandy soil under evaporation

Soil salinization, caused by salt migration and accumulation underneath the soil surface, will corrode structures. To analyze the moisture-salt migration and salt precipitation in soil under evaporation conditions, a mathematical model consisting of a series of theoretical equations is briefly presented. The filling effect of precipitated salts on tortuosity factor and evaporation rate are taken into account in relevant equations. Besides, a transition equation to link the solute transport equation before and after salt precipitation is proposed. Meanwhile, a new relative humidity equation deduced from Pitzer ions model is used to modify the vapor transport flux equation. The results show that the calculated values are in good agreement with the published experimental data, especially for the simulation of volume water content and evaporation rate of Toyoura sand, which confirm the reliability and applicability of the proposed model.     

First evidence of IMF control of Jovian magnetospheric boundary locations: Cassini and Galileo magnetic field measurements compared

The Cassini spacecraft, en route to Saturn, passed close to Jupiter while the Galileo spacecraft was completing its 28th and 29th orbits of Jupiter, thus offering a unique opportunity for direct study of the solar wind-Jovian interaction. Here evidence is given of response of the Jovian magnetopause and bow shock positions to changes of the north-south component of the solar wind magnetic field, a phenomenon long known to occur in equivalent circumstances at Earth. The period analyzed starts with the passage over Cassini of an interplanetary shock far upstream of Jupiter. The shock's arrival at Galileo on the dusk-flank of the magnetosphere caused Galileo to exit into the solar wind. Using inter-spacecraft timing based on the time delay established from the shock arrival at each spacecraft, we point out that Galileo's position with respect to the Jovian bow shock appears to correlate with changes in the disturbed north-south reversing field seen behind the shock. We specifically rule out the alternative of changes in the shape of the bow shock with rotations of the interplanetary magnetic field as the cause.     

Stochastic modelling of groundwater flow and solute transport in aquifers

This paper presents an introductory overview of recently developed stochastic theories for tackling spatial variability problems in predicting groundwater flow and solute transport. Advantages and limitations of the theories are discussed. Lastly, strategies based on the stochastic approaches to predict solute transport in aquifers are recommended.     

Zircon U–Pb age, trace element and Hf isotope composition of Kongling terrane in the Yangtze Craton: refining the timing of Palaeoproterozoic high-grade metamorphism

U–Pb age, trace element and Hf isotope compositions of zircon were analysed for a metasedimentary rock and two amphibolites from the Kongling terrane in the northern part of the Yangtze Craton. The zircon shows distinct morphological and chemical characteristics. Most zircon in an amphibolite shows oscillatory zoning, high Th/U and ¹⁷⁶Lu/¹⁷⁷Hf ratios, high formation temperature, high trace element contents, clear negative Eu anomaly, as well as HREE-enriched patterns, suggesting that it is igneous. The zircon yields a weighted mean ²⁰⁷Pb/²⁰⁶Pb age of 2857 ± 8 Ma, representing the age of the magmatic protolith. The zircon in the other two samples is metamorphic. It has low Th/U ratios, low trace element concentrations, variable HREE contents (33.8 ≥ Lu_N≥2213; 14.7 ≤ Lu_N/Sm_N ≤ 354) and ¹⁷⁶Lu/¹⁷⁷Hf ratios (0.000030–0.001168). The data indicate that the zircon formed in the presence of garnet and under upper amphibolite facies conditions. The metamorphic zircon yields a weighted mean ²⁰⁷Pb/²⁰⁶Pb age of 2010 ± 13 Ma. These results combined with previously obtained Palaeoproterozoic metamorphic ages suggest a c. 2.0 Ga Palaeoproterozoic collisional event in the Yangtze Craton, which may result from the assembly of the supercontinent Columbia. The zircon in two samples yields weighted mean two-stage Hf model ( T _DM2) ages of 3217 ± 110 and 2943 ± 50 Ma, respectively, indicating that their protoliths were mainly derived from Archean crust.     

Anthropogenic trace metals in an ice core at Vestfonna,Svalbard, Norway

1　IntroductionAnicecoreobtainedfrom polarglaciersoricesheetsisoneofthemostimportantarchivestoreconstructpaleoclimaticandpaleoatmosphericcondition .Informationonpale o environmentcanbeextractedfromicecoresaschemicaland/orphysicalsignals.Amongthechemicalsignals,heavymetalsarenotedassignalsofterrestrialenvironmentalchangeandanthropogenicpollution (e.g .Murozumietal.1 969;NgandPatterson 1 981 ;Hongetal.1 994) .SinceconcentrationsofmostofthemetalsinpolarsnowincentralGreen landareatorbelowthepptl…     

青海省沙柳河南区有色金属矿成矿物质来源及矿床成矿模式探讨

本文简述了沙柳河南区有色金属矿床的基本特征。通过对成矿热液及成矿物质的来源与性质的研究,认为该矿床的成因类型为火山沉积—接触交代改造叠加型,进而探讨了该矿床的成矿模式。     

Ab initio infra-red spectra of iron-polycyclic aromatic hydrocarbon compounds: a model case

C₁₀H₆-Fe⁺ complexes were observed by Fourier transform mass spectrometry by Marty et al. (Chem. Phys. Lett. 256 (1996) 669). In this article, we present the infra-red (IR) spectra of the two isomers calculated by ab initio methods of quantum chemistry. In the past, the same approach has predicted successfully unexpected features of the IR spectra of polycyclic aromatic hydrocarbon (PAH) cations which were confirmed by measurements in matrices (J. Phys. Chem. 98 (1994) 9187). The C₁₀H₆-Fe⁺ systems are models for larger PAHs-Fe⁺ complexes, which are believed to play a key rôle in space chemistry.     

A Simulating Experiment in the Process of Soil Erosion on Bare Land in Mt. Tanakami

In order to understand the process of surface erosion and acquire basic data of conditions on hillslope without vege tation, a sprinkling experiment is conducted on a bare slope in Mt. Tanakami in the central part of Japan. Based on the mea surements of runoff, mean soil erosion depth, and sediment yield, etc. , the results suggest the following characteristics in the process of surface erosion in the experimental area. (1) The occurrence of sediment discharge is interrupted; (2) Surface runoff is a saturated overland flow; (3) The mean soil erosion depth is thick compared with other areas in Mt. Tanakami;(4) Sediment discharge process is detachment- limited.     

Accumulation of Zn,Cu and Cd by crabs and barnacles

The crab Carcinus maenas (L.) and the barnacle Elminius modestus Darwin were exposed to a range of dissolved concentrations of Zn, Cu and Cd for 21 days in artificial seawater. Accumulation of Zn and Cu by crabs has been interpreted in terms of the presence of a regulation mechanism to maintain constant body concentrations (83·2 ± 19·4 μg Zn g^?1 dry wt.; 39·8 ± 9·8 μg Cu g^?1 dry wt.) under varying external dissolved metal levels, until a threshold dissolved metal concentration (c. 400 μg Zn l^?1; c. 170 μg Cu l^?1) beyond which net accumulation of metal begins. Cadium appears to be accumulated by C. maenas at all exposures with no evidence for regulation of body cadmium concentrations. Exposure of E. modestus to Zn, Cu or Cd caused net accumulation of the respective metal in the bodies of the barnacles, with no evidence for regulation of body metal concentrations.     

运输系统的区域效应研究

运输系统改进—运距缩短—产业布局调整这一空间过程对不同的区域可能具有完全不同的意义。本文通过对一个两区域—两部门经济模型的研究得出结论:当较落后的资源产区与经济中心之间的距离由于运输系统的改进而缩短时,资源产区的经济结构向单一化转变,初级产品的生产和输出在经济建设中逐渐占主导地位,加工工业逐渐萎缩,地方经济发展受到阻碍,而且这种变化是在距离的某一特定值处突然出现的,带有跃变的性质。这一研究结果表明,对区域运输系统的任何改进措施都应该慎而行之,以免造成与本来目标相悖的区域效应。