A spectrophotometric measurement of soil cation exchange capacity based on cobaltihexamine chloride absorbance

Among numerous methods for cation exchange capacity (CEC) determination for soils and sediments, the cobaltihexamine chloride method is frequently used due to its ability to measure CEC at soil pH. After exchange with Co(NH₃)₆³⁺ ions, CEC is estimated via the measurement of the Co remaining in solution. The modified method proposed allows a more rapid determination of CEC based on the measurement of the absorbance at 472 nm of the cobaltihexamine chloride solution before and after exchange. This method has been applied to various soil's horizons from four sites, selected to cover a wide range of CEC and pH values. The model obtained allows one to calculate CEC from absorbance at 472 nm with 95% confidence intervals. As CEC is of relevant meaning in agronomical and environmental purposes, and more recently in ecotoxicological studies, this modified method can be proposed as a rapid test for CEC evaluation.     

Fuzzy logic model approaches to daily pan evaporation estimation in western Turkey / Estimation de l’évaporation journalière du bac dans l’Ouest de la Turquie par des modèles à base de logique floue

Abstract

Abstract Evaporation is one of the fundamental elements in the hydrological cycle, which affects the yield of river basins, the capacity of reservoirs, the consumptive use of water by crops and the yield of underground supplies. In general, there are two approaches in the evaporation estimation, namely, direct and indirect. The indirect methods such as the Penman and Priestley-Taylor methods are based on meteorological variables, whereas the direct methods include the class A pan evaporation measurement as well as others such as class GGI-3000 pan and class U pan. The major difficulty in using a class A pan for the direct measurements arises because of the subsequent application of coefficients based on the measurements from a small tank to large bodies of open water. Such difficulties can be accommodated by fuzzy logic reasoning and models as alternative approaches to classical evaporation estimation formulations were applied to Lake Egirdir in the western part of Turkey. This study has three objectives: to develop fuzzy models for daily pan evaporation estimation from measured meteorological data, to compare the fuzzy models with the widely-used Penman method, and finally to evaluate the potential of fuzzy models in such applications. Among the measured meteorological variables used to implement the models of daily pan evaporation prediction are the daily observations of air and water temperatures, sunshine hours, solar radiation, air pressure, relative humidity and wind speed. Comparison of the classical and fuzzy logic models shows a better agreement between the fuzzy model estimations and measurements of daily pan evaporation than the Penman method.     

Analysis of flood propagation changes in the Kienstock—Bratislava reach of the Danube River/Analyse des changements de propagation des crues dans le tronçon Kienstock—Bratislava du Fleuve Danube

Abstract

In the first part of this study, a flood wave transformation analysis for the largest historical floods in the Danube River reach Kienstock–Bratislava was carried out. For the simulation of the historical (1899 and 1954) flood propagation, the nonlinear river model NLN-Danube (calibrated on the recent river reach conditions) was used. It was shown that the simulated peak discharges were not changed significantly when compared to their historical counterparts. However, the simulated hydrographs exhibit a significant acceleration of the flood wave movement at discharges of between 5000 and 9000 m³ s^-1. In the second part, the travel time-water level relationships between Kienstock and Bratislava were analysed on a dataset of the flood peak water levels for the period 1991–2002. An empirical regression routing scheme for the Danube short-term water level forecast at Bratislava station was derived. This is based on the measured water level at Kienstock gauging station.     

Determination of Molybdenum, Antimony and Tungsten at sub μg g−1 Levels in Geological Materials by ID-FI-ICP-MS

We have developed a rapid and accurate method for the determination of Mo, Sb and W in geological samples using isotope dilution inductively coupled plasma-mass spectrometry with a flow injection system (ID-FI-ICP-MS). The chemical procedure requires HF digestion of the sample with a Mo-Sb-W mixed spike, subsequent evaporation and dissolution of Mo, Sb and W from Mg and Ca fluorides with HF. Recovery yields of Mo, Sb and W in the extraction were > 94% for samples of peridotite, basalt and andesite composition, with the exception of W in samples of peridotite composition for which recovery was 81%. No matrix effects were observed in the determination of the isotope ratios of Mo, Sb and W in solutions prepared from peridotite, basalt and andesite samples down to a dilution factor of 100. Detection limits of Mo, Sb and W in silicate materials were at the several ng g⁻¹ level. Analysis of the silicate reference materials PCC-1, DTS-1, BCR-1, BHVO-1, AGV-1 from the US Geological Survey and JP-1, JB-1, -2, -3, JA-1, -2, and -3 from the Geological Survey of Japan as well as the Smithsonian reference Allende powder yielded reliable Mo, Sb and W concentrations. The repeatability in the analysis of basalts and andesites was < 9%. This technique requires only 0.2 ml sample solution, and is therefore suitable for analyzing small and/or precious samples such as meteorites, mantle peridotites and their mineral separates.     

Modélisation directe et inverse de l'écoulement souterrain dans les milieux poreux

Résumé

Le présent article montre l'intérêt des simulations mathématiques dans la compréhension des aquifères complexes et hétérogènes. Le réservoir côtier du Maroc occidental est un exemple qui traduit une répartition spatiale des corps perméables et imperméables, d'où la nécessité d'approfondir la connaissance de son fonctionnement hydrogéologique en termes de modélisation numérique. Le modèle hydrodynamique proposé repose sur la résolution du problème direct et inverse. La simulation de l'écoulement (problème direct) en régime permanent a montré la persistance de grands écarts entre la piézométrie mesurée et calculée. Cette anomalie de calage est expliquée principalement par le caractère hétérogène et fissuré, incompatible avec la dérivation de l'équation de diffusivité qui présuppose un milieu continu et un régime laminaire plutôt que turbulent. Deux cartes principales ont été obtenues: (a) une carte des polygones de la conductivité hydraulique dont les valeurs varient entre 50 × 10^?4 et 80 × 10^?4 m/s; et (b) une carte des polygones de recharge avec des valeurs comprises entre 4.5 × 10^?9 et 5 × 10^?14 m/s. Le calage du modèle d'écoulement recherché dans la résolution du problème inverse consiste à identifier les paramètres de l'aquifère à partir de la piézométrie connue. Le code d'inversion PEST (Parameter ESTimation) a été utilisé pour créer des cartes montrant des polygones de la conductivité hydraulique et de la recharge avec des valeurs très similaires aux résultats du modèle conceptuel.     

Modelling Short‐Scale Variability and Uncertainty During Mineral Resource Estimation Using a Novel Fuzzy Estimation Technique

For mineral resource assessment, techniques based on fuzzy logic are attractive because they are capable of incorporating uncertainty associated with measured variables and can also quantify the uncertainty of the estimated grade, tonnage etc. The fuzzy grade estimation model is independent of the distribution of data, avoiding assumptions and constraints made during advanced geostatistical simulation, e.g., the turning bands method. Initially, fuzzy modelling classifies the data using all the component variables in the data set. We adopt a novel approach by taking into account the spatial irregularity of mineralisation patterns using the Gustafson–Kessel classification algorithm. The uncertainty at the point of estimation was derived through antecedent memberships in the input space (i.e., spatial coordinates) and transformed onto the output space (i.e., grades) through consequent membership at the point of estimation. Rather than probabilistic confidence intervals, this uncertainty was expressed in terms of fuzzy memberships, which indicated the occurrence of mixtures of different mineralogical phases at the point of estimation. Data from different sources (other than grades) could also be utilised during estimation. Application of the proposed technique on a real data set gave results that were comparable to those obtained from a turning bands simulation.     

Provisional Elemental Values for IAEA‐Sewage Sludge by Instrumental Neutron Activation Analysis

The International Atomic Energy Agency (IAEA) organised a proficiency test (PT), IAEA‐CU‐2010‐02, for the determination of elements in sewage sludge. The PT sample was analysed by semi‐absolute standardless k₀‐instrumental neutron activation analysis (k₀‐INAA). Results for seven elements (As, Co, Cr, Fe, Hg, Se, Zn) were submitted to the IAEA by our laboratory. All of our results were scored ‘acceptable’ by the ‘result evaluation criteria’ adopted by the IAEA. The same analytical methodology produced quantitative results for twenty‐six additional elements. In total, thirty‐six elements were determined with uncertainty varying from 4 to 11%. This paper presents the provisional mass fractions of twenty‐six additional elements (Ag, Al, Br, Ca, Ce, Cl, Dy, Eu, Ga, Hf, I, K, La, Mg, Mn, Na, Rb, Sb, Sc, Sm, Ta, Tb, Th, V, U, W) not reported by the IAEA. The analytical methodology was discussed with important sources of spectral, nuclear and fission‐product interferences. It was shown that the important components of uncertainties were the k₀ factor, Q₀ factor, detector efficiency, mass and counting statistics. The methodology was validated by analysing the IAEA‐S7 reference material.     

Development of a New Method of Extraction of Interstitial Water from Low‐Porosity Consolidated Sediments Recovered During Super‐Deep Drilling Projects

During the Integrated Ocean Drilling Program (IODP) Expedition 338, several methods were tested for the extraction of interstitial water in consolidated, low‐porosity deep‐sea sediments from Site C0002 in the Kumano Basin. On the basis of those tests, we propose a modified ground rock interstitial normative determination (GRIND) method of extraction of interstitial water. In separate runs of the new method, sediment samples were ground in a ball mill with either ultrapure water or a solution of HNO₃. The interstitial water was then extracted with a conventional squeezer. Sufficient solution was extracted by this method to analyse most major and a few minor components of interstitial water that were comparable to those previously reported for samples extracted by the conventional squeezing method. The new method requires much smaller amounts of sediment than that of the conventional method and will be useful for analysis of samples recovered during super‐deep drilling programmes.     

Coding random self-similar river networks and calculating geometric distances: 2. Application to runoff simulations / Codage de réseaux hydrographiques auto-similaires aléatoires et calcul de distances géométriques: 2. Application à la simulation de l'écoulement

Abstract

A preliminary method for coding random self-similar river networks and the corresponding distance calculations are proposed in a companion paper. The coding method is applied to generate random self-similar river networks, and the corresponding algorithm for calculating the geometric distances of the links is employed to determine the width function of the river networks, and thus evaluates the adaptability of the process. The width function-based geomorphological instantaneous unit hydrograph (WF-GIUH) model is then applied to estimate the runoff of the Po-bridge watershed in northern Taiwan. The results imply that the separately random self-similar generating algorithm can be used to simulate river networks during the rainfall–runoff process. It can also help analyse the variations of the river network when rainfall locations change and study the influence on hydrological responses (IUH) when the shape of river network changes.     

Further details on the applicability of Thellier paleointensity method: The effect of magnitude of laboratory field

Twenty years after Tanaka and Kono's pioneering contribution (Tanaka and Kono, 1984), we give some new details on the effect of applied field strength during Thellier paleointensity experiments. Special attention is paid to the relation of magnitude of laboratory field and Coe's quality factors (Coe et al., 1978). Full thermoremanent magnetizations were imparted on natural samples containing low-Ti titanomagnetites of pseudo-single domain structure in a 40-μT magnetic field from 600?°C to room temperature. The samples were subjected to the routine Thellier procedure using a wide range of applied laboratory fields. Results indicate that values of laboratory fields may be accurately reproduced within 2% of standard error. The quality factors, however, decrease when the magnitude of ‘ancient’ field does not match to applied laboratory fields. To cite this article: J. Morales et al., C. R. Geoscience 338 (2006).