吉林中部晚三叠世和早侏罗世两期铝质A型花岗岩的厘定及对吉黑东部构造格局的制约

高精度同位素年代学和岩石学、元素地球化学研究结果表明,吉林省中部地区存在晚三叠世和早侏罗世两期铝质A型花岗岩。其中三道河正长花岗岩的锆石LA ICPMS年龄为(216±3) Ma,形成于晚三叠世,受控于华北板块和其北侧板块在晚二叠世—早三叠世沿西拉木伦河—长春—延吉缝合带碰撞拼合后的岩石圈伸展作用,标志古亚洲洋构造域的演化结束。天桥岗碱长花岗岩的锆石SHRIMP和TIMS年龄分别为(182±3) Ma和(188±4) Ma,全岩Rb Sr等时线年龄为(185±4) Ma,形成于早侏罗世,可能是与佳木斯板块和松嫩—张广才岭板块在早侏罗世早期沿嘉荫—牡丹江缝合带碰撞拼合有关的伸展作用的产物。这次板块碰撞作用很有可能标志着东北地区东部此时已经开始进入滨太平洋构造域的演化阶段。更详细的研究显示,两期A型花岗岩岩浆都来源于年轻的基性玄武质下地壳的部分熔融,岩浆经历了分离结晶作用。     

Zircon U-Pb geochronology and geochemistry of syenogranites in western Niubiziliang,northwestern Qaidam,Qinghai

The study presents the results of U-Pb dating of zircons and whole-rock geochemical analyses of a syenogranite located in the western Niubiziliang area,China with the aim of determining its formation time,petrogenesis and the regional tectonic setting. Zircons within the syenogranite are euhedral-subhedral and display rhythmic growth zoning,indicating a magmatic origin. Zircon U-Pb data obtained by LA-ICP-MS indicate the syenogranite formed in the Late Permian (260.7±1.5 Ma). The w(SiO_2) of syenogranites is 70.82%--73.59%,w(Al_2O_3) is 13.49%--14.82%,and w(Na_2O + K_2O) is 7.85%--8.52%,and yield K_2O/Na_2O ratios of 1.06--1.26. Therefore,the syenogranites belong to the high-K calc-alkaline and metaluminous (A/CNK 1,A/NK 1) series which display I-type granites similarly. The syenogranites also show the geochemical characteristics of volcanic arc rocks,being enriched in large-ion lithophile elements (LILEs; K,Rb) and light rare-earth elements (LREEs; La,Ce,Sm,Nd),but depleted in high field strength elements( HFSEs; Ta,Nb,P,Ti). On the whole,trace element ratios are close to the mean of the Earth's crust,indicating a lowercrust magma source. The low Sr (161--214) ×10~(-6) and Yb (1.08--1.80)×10~(-6) concentrations indicate that plagioclase and hornblende are residual mineral phases in the source. The regional geology and whole-rock geochemistry suggest that the formation of the syenogranites was related to subduction of the Zongwulong Ocean crust,and the north margin of Qaidam Block during the Late Permian was in an active continental margin tectonic setting.     

辽东凤凰山正长花岗岩SHRIMP U-Pb年龄、地球化学特征与陆内伸展作用

【研究目的】 辽宁丹东地区发育着一期A型花岗岩,因其特殊的成因演化,特定的构造背景及其重要的地球动力学意义而备受关注。【研究方法】 本文通过对辽宁丹东凤凰山岩体SHRIMP锆石U-Pb年代学、岩石地球化学特征的分析,探讨了该岩体形成时代、岩石成因及地球动力学背景。【研究结果】 辽东凤凰山黑云母正长花岗岩锆石U-Pb年龄分别为（122.3±1.7）Ma、（125.0±1.7）Ma、 （122±2）Ma,代表岩浆结晶年龄,凤凰山正长花岗岩侵位时代属于早白垩世。地球化学分析结果显示,SiO₂含量为65.65%～73.62%,K₂O为3.52%～5.76%,Na₂O为3.64%～4.26%,Al₂O₃为13.4%～15.49%,A/CNK值1.02～1.46,属铝过饱和型。碱度率AR在2.71～5.13,基本在铝质A型花岗岩AR值范围内,FeO_t/MgO比值为4.69～18.05,表现为A型花岗岩的A1和A2过渡类型。Rb/Nb比值为6.02～8.64,明显高于大陆壳的Rb/Nb比值2.2～4.7,说明陆壳物质对岩体成岩影响较大,从而导致Rb的含量增加。相对富集大离子亲石元素Rb、Th, Zr、Hf,亏损Sr、P、Ba、Ti、Nb。稀土总量较高,轻重稀土之间的分馏不明显,Eu具明显的负异常。【结论】 综上,凤凰山正长花岗岩可能产生于陆内剪切相关的伸展环境,应为自中侏罗世开始由板块俯冲引起的东亚大陆边缘构造过程的响应。     

Zircon U-Pb geochronology,geochemistry and petrogenesis of syenogranite from Angeer Yinwula area in Inner Mongolia

The study presents the results of U-Pb dating of zircons and whole-rock geochemical analyses of syenogranite in Angeer Yinwula area, China, with the aim of determining its formation time, petrogenesis and regional setting. Zircon U-Pb data obtained by LA-ICP-MS indicate that the syenogranite formed in the Early Cretaceous(136.1±0.9 Ma). Geochemically, the rock is characterized by high SiO_2(76.63%--77.58%) and Na_2O+K_2O(8.00%--8.32%), low MgO(0.02%--0.04%) and TFe_2O_3(0.51%--0.84%), and is enriched in LREEs and LILEs, depleted in HREEs and HFSEs. It belongs to high-K calc-alkaline, metaluminous-weakly peraluminous, exhibiting an affinity to I-type granite. All these characteristics implied that the syenogranite in this region derived from crust-mantle mixed source. Overall, the regional geology, geochronology and geochemical features suggest that the formation of the syenogranite was related to the subduction of the Paleo-Pacific Ocean.     

Geochemical characteristics and evaluation of Nb and Ta deposits in Nianzishan area of Heilongjiang Province

In order to improve the geochemical research degree of Nb and Ta deposits in Nianzishan area, the authors conducted 1:10 000 soil geochemical survey to comprehensively analyze the characteristics of geochemical element content, single element exception and comprehensive anomaly in the study area. The results show that Nb, Ta and other elements in Nizishan area belong to high background field and are unevenly distributed in the soil, which may result in the local enrichment of ore deposits. By R-type clustering analysis, these 18 elements were divided into three groups of precious and non-ferrous metal elements, rare and rare earth elements, and dispersed elements, which reflects the clustering and combination characteristics of normal granite elements, indicating that Nb and Ta minerals are closely related to granite bodies. In the study area, 521 single element anomalies and 12 composite anomalies were identified. Among these anomalies, three composite anomalies, Nian-2012-Ht-2, Nian -2012-Ht-7 and Nian -2012-Ht-11, were the key anomalies with great metallogenic potential. Three low-grade Nb and Ta ore bodies and 11 Nb and Ta mineralized bodies were found in the Early Cretaceous alkaline granite and syenogranite after trenching and drilling engineering verification.     

黑龙江宝清地区早古生代花岗岩锆石U-Pb年龄及岩石地球化学特征

对黑龙江宝清地区七一林场正长花岗岩岩体、干涸沟口二长花岗岩进行了详细的地球化学分析和U-Pb锆石测年,结果表明,正长花岗岩与二长花岗岩的形成年龄分别为523.3±2.4Ma和523.3±2.3Ma,属于早寒武世。地球化学的研究显示,岩石具有准铝质-过铝质钙碱性碱性和高分异I型花岗岩的特点,高硅、高铝、富碱。属于轻稀土元素富集、重稀土元素亏损型;δEu=0.38~1.73,平均值为1.05,根据Eu的正负异常,将宝清地区的花岗岩分为2类,正Eu异常型花岗岩和负Eu异常型花岗岩。富集大离子亲石元素(LILE)Rb、K,亏损高场强元素(HFSE)Nb、Ta、P、Ti。结合区域构造背景与年代学特征,在早古代以前佳木斯-兴凯地块可能属于同一个大陆——冈瓦纳大陆,在泛非运动主峰期之后,由于陆块的碰撞,形成大量的早古生代花岗质岩石。     

黑龙江多宝山地区大岔子正长花岗岩锆石U-Pb年龄及其地质意义

为查明出露于黑龙江多宝山地区大岔子正长花岗岩体的时代和形成的地质背景,对其进行了锆石SHRIMP U-Pb同位素地质年代学研究.结果显示该锆石具有明显环带结构,Th/U比值为0.41~0.99,是典型的岩浆型锆石.大岔子正长花岗岩锆石共分析了11个测点,206Pb/238U加权平均年龄为345±3 Ma（n=11,SMWD=0.99）.该年龄代表了正长花岗岩的结晶年龄,表明正长花岗岩形成时代为早石炭世.对正长花岗岩的主量元素及微量元素的分析表明,该花岗岩属于富钾钙碱性花岗岩类,成因类型属于A型花岗岩.     

南极中山站地区正长花岗岩及花岗伟晶岩脉的~(40)Ar/~(39)Ar同位素年龄测定

本文详细报道了用 4 0 Ar/3 9Ar定年法测定的二个黑云母样品的数据结果。样品来自拉斯曼丘陵米洛岛北部中国南极中山站附近。一个取自正长花岗岩 ,另一个取自侵入正长花岗岩的花岗伟晶岩脉。正长花岗岩的 4 0 Ar/3 9Ar坪年龄为 494.4± 1 .4Ma,花岗伟晶岩脉的 4 0 Ar/3 9Ar坪年龄为 485 .8± 0 .6 Ma。两者为区域泛非热事件晚期阶段的产物。     

Geochemistry and geodynamic significance of the rare-earth mineralized Paleoproterozoic Longwangzhuang granite on the southern margin of the North China Craton

The Longwangzhuang granite pluton occurs on the southern margin of the North China Craton and consists mainly of biotite syenogranite with aegirine granite being locally distributed.The granites are characterized by high silicon and alkaline contents(SiO2=72.17%-76.82%,K2O+Na2O=8.28%-10.22%,K2O/Na2O>>1),AI(agpaitic index) =0.84-0.95,DI=95-97,ASI(aluminum saturation index)=0.96-1.13,and very high Fe* number(FeO*/(FeO*+Mg)=0.90-0.99),thus the granites are assigned to the metaluminous to weakly peraluminous,alkalic to calc-alkalic ferroan A-type granites.The granites are rich in large ion lithophile elements(LILE),especially high in REE concentrations(REE+Y=854×10-6-1572×10-6);whereas the enrichment of high strength field elements(Nb,Ta,Zr,Hf) is obviously less than that of LILEs,exhibiting mild depletions on trace element spider plots;and the rocks are significantly depleted in Ba,Sr,Ti,and Pb.The low εNd(t) values(-4.5--7.2) and high model ages(2.3-2.5 Ga) of the granites as well as the low εHf(t) values(-1.11--5.26) and high Hf model ages(THf1= 2.1-2.3 Ga,THf2=2.4-2.6 Ga) of zircons from the biotite syenogranite suggest that the granites were probably derived from an enriched mantle source.The zircons from the biotite syenogranite are mainly colorless transparent crystals exhibiting well-developed oscillatory zoning on the cathodoluminescence images with a LA-ICPMS zircon U-Pb age of 1602.1±6.6 Ma(MSWD=0.48).Petrochemical,trace elements,as well as Nd and Hf isotopic compositions of the rocks demonstrate that the granites were formed in a within-plate extensional tectonic regime possibly related to the breakup of the Columbia supercontinent.The granites were most likely formed through extreme fractional crystallization of alkali basaltic magma resulted from partial melting of the mantle,which was fertilized by recycling crustal rocks triggered by the delamination of lithospheric mantle and lower crust following the ～1.8 Ga collision and amalgamation of the North China Craton which is part of the Columbia supercontinent.However,contamination of neo-Archean to Paleoproterozoic crustal rocks during the ascent and emplacement of the magma could not be excluded.Being the youngest known anorogenic magmatism on the southern margin of the North China Craton related to Columbia breakup,it might represent the break off of the North China Craton from Columbia supercontinent at the end of Paleoproterozoic.     

太行山南段丰峪蚀变正长花岗岩LA-ICP-MS锆石U-Pb年龄及构造意义

在华北克拉通中东部的太行山南段丰峪一带,发现一处不整合于长城系大河组之下的蚀变正长花岗岩体。岩石类型为黑云母正长花岗岩,钾化、绢云母化蚀变明显。岩体低硅(SiO_2=67.46%～68.89%)、富碱(K_2O+Na_2O=8.09～9.62,K_2O/Na_2O远大于1),铝指数A/CNK=1.20～1.57,属过铝质、钙碱性A型花岗岩。岩石富集大离子亲石元素,显著亏损Nb、Ba、Ta、Sr、P、Ti元素,稀土元素含量高(192～774μg/g,平均483μg/g)。用LA-ICPMS技术测得锆石的207Pb/206Pb年龄为(1790±22)Ma(n=22,MSWD=0.80),这是迄今为止太行山南段长城系底界直接的控制年龄。岩石主、微量元素地球化学以及同位素年代学表明,丰峪蚀变正长花岗岩形成于板内伸展构造环境,为熊耳期三叉裂谷东北一支的存在提供了重要的岩浆岩石学证据,其所处的太行山区与熊耳群火山岩所处的豫西地区均为熊耳期三叉裂谷的组成部分,进而为太行山区与豫西地区的长城系对比提供了重要支撑。