邻菲啰啉在测定亚铁中的保护效果

样品在分解过程中 ,亚铁易被空气部分氧化 ,致使测试结果偏低 ,采用在HF H2 SO4溶矿过程中加入邻菲卟罗啉 ,与亚铁形成络合物 ,对保护亚铁具有较好的效果。拟定了在塑料坩埚中加邻菲卟罗啉、H2 SO4及HF ,中高温电热板溶矿 ,容量法测定样品中的亚铁 ,方法精密度为 0 .2 3% ,样品加标准回收率 98.8%～ 10 1.9%。此方法具有较好的应用效果     

Damage identification method using harmonic excitation force considering both modelling and measurement errors

A method of structural damage identification using harmonic excitation force is presented. It considers the effects of both measurement and modelling errors in the baseline finite element model. Damage that accompanies changes in structural parameters can be estimated for a damaged structure from the change between measured vibration responses and ones calculated from the analytical model of the intact structure. In practice, modelling errors exist in the analytical model due to material and geometric uncertainties and a reduction in the degrees of freedom as well as measurement errors, making identification difficult. To surmount these problems, bootstrap hypothesis testing, which enables statistical judgment without information about these errors, was introduced. The method was validated by numerical simulation using a three‐dimensional frame structure and real vibration data for a three‐storey steel frame structure. Copyright © 2005 John Wiley & Sons, Ltd.     

Ab initio infra-red spectra of iron-polycyclic aromatic hydrocarbon compounds: a model case

C₁₀H₆-Fe⁺ complexes were observed by Fourier transform mass spectrometry by Marty et al. (Chem. Phys. Lett. 256 (1996) 669). In this article, we present the infra-red (IR) spectra of the two isomers calculated by ab initio methods of quantum chemistry. In the past, the same approach has predicted successfully unexpected features of the IR spectra of polycyclic aromatic hydrocarbon (PAH) cations which were confirmed by measurements in matrices (J. Phys. Chem. 98 (1994) 9187). The C₁₀H₆-Fe⁺ systems are models for larger PAHs-Fe⁺ complexes, which are believed to play a key rôle in space chemistry.     

山东省区域地质构造演化探讨

山东省区域地质构造演化分为5个阶段.①陆核形成阶段形成太古宙高级区,地壳分异成稳定的花岗岩穹窿和活动的绿岩带,第一次克拉通化完成.②陆块发生形成阶段地壳向刚性发展,在华北陆核硅铝壳的基础上先后有3次张开、闭合裂谷作用,第二次克拉通化完成.这一阶段演化在鲁西地区主要表现为挤压作用,形成大量造山花岗岩;鲁东地区则以拉张作用为主,形成海槽,产生沉积.③秦昆洋形成演化阶段四堡期沿鲁东南部地壳拉张,在华北板块与扬子板块间形成秦昆洋.晋宁期秦昆洋关闭,华北板块与扬子板块对接碰撞,沿胶南造山带产生大量同碰撞花岗岩,同时产生超高压变质作用及形成丰富多彩的碰撞构造.晋宁运动最终形成统一的原始中国古陆,第三次克拉通化完成.④陆块发展阶段鲁西地区地壳频繁升降,形成广泛的海相及海陆交互相沉积;鲁东地区则以造山抬升为主,地层沉积较少.⑤滨太平洋发展阶段该阶段的主要特征是断块构造发育,形成盆岭构造格局,产生大陆边缘花岗岩,构造体系由古亚洲构造域转向滨太平洋构造域.     

The Fault Block''s Framework in Boli Basin and its Control Over the Deposition

Boli basin, between Yishu fracture belt and Dunmi fracture belt, is the biggest Mesozoic coal basin in the east of Heilongjiang Province. Now it is a fault - fold remnant basin. The basin' s shape is generally consistent with the whole distribution of the cover folds, an arc protruding southwards. The basement of the basin can be divided into three fault blocks or structural units. The formation and evoluation of the basin in Mesozoic was determined by the basement fault blocks' displacement features rusulted from by the movement of the edge faults and the main basement faults.     

Reliability assessment of serviceability performance of braced retaining walls using a neural network approach

In urban environments, one major concern with deep excavations in soft clay is the potentially large ground deformations in and around the excavation. Excessive movements can damage adjacent buildings and utilities. There are many uncertainties associated with the calculation of the ultimate or serviceability performance of a braced excavation system. These include the variabilities of the loadings, geotechnical soil properties, and engineering and geometrical properties of the wall. A risk‐based approach to serviceability performance failure is necessary to incorporate systematically the uncertainties associated with the various design parameters. This paper demonstrates the use of an integrated neural network–reliability method to assess the risk of serviceability failure through the calculation of the reliability index. By first performing a series of parametric studies using the finite element method and then approximating the non‐linear limit state surface (the boundary separating the safe and ‘failure’ domains) through a neural network model, the reliability index can be determined with the aid of a spreadsheet. Two illustrative examples are presented to show how the serviceability performance for braced excavation problems can be assessed using the reliability index. Copyright © 2005 John Wiley & Sons, Ltd.     

Quaternary fault segmentation and interaction in the epicentral area of the 1561 earthquake (Mw = 6.4), Vallo di Diano, southern Apennines, Italy

The main structural characteristics of the Caggiano and Polla faults, exposed in the epicentral area of the 1561 earthquake (Mw = 6.4), southern Italy, have been investigated in detail to assess their spatial and temporal properties, and to evaluate their seismogenic potential. These right stepping normal faults show an overlap of about 7 km and an across strike separation of about 4 km. The geometric relationships between the Caggiano and Polla faults, but also the displacement distribution along each fault, demonstrate that they have been strongly interacting throughout the Pleistocene. Nevertheless, geological evidence of Holocene tectonic activity was mainly recognized along the Caggiano Fault (faulted late glacial deposits) and in the southernmost part of the Polla Fault (faulted deposits of probably Late Pleistocene age). This suggests that the Caggiano Fault can be considered as the most tectonically active fault in the Vallo di Diano Fault System. By calculating Coulomb stress changes, we have constrained modes of mechanical interactions between the two faults in a scenario compatible with the 1561 earthquake. This approach allows us to argue that both the Caggiano and the Polla Faults are probably linked at depth, and part of the same seismogenic structure which may be potentially responsible for composite ruptures with magnitude ≥ 6.5.     

能量色散X射线荧光光谱法测定钼矿石中钼铅铁铜

建立了能量色散X射线荧光光谱法测定钼矿石中钼、铅、铁、铜的方法,讨论了粒度效应、矿物效应的影响因素,确定了采取粉末样品,用系列标准样品建立工作曲线,通过元素间相互校正消除基体效应,用内控标准样品考察了方法的精密度(RSD,n=11)为0.44%～15.4%。实际样品的测定结果和化学法相符,可满足日常分析工作需要。     

青海南部熔积岩的发现:对寻找VMS型矿床的重要启示

熔积岩指的是侵入、混合到未固结或弱固结的湿沉积物中的熔浆分解、原位形成的一类特殊岩石。正确地认识该类岩石,有利于增进人们对岩浆-水(沉积物)相互作用过程的理解,恢复古环境。在青海南部沱沱河地区发现了一套角砾为撕片状、锯齿状及浑圆状的安山岩,胶结物为铁硅质组合的特殊熔积岩。研究表明,该熔积岩的角砾为岩浆遇水后快速淬火、裂解的产物,铁硅质组合为海底喷气沉积形成的含铁建造;且安山岩与含铁建造发生混合时,含铁建造尚未固结。该套熔积岩的发现,改变了长期以来对开心岭铁矿为火山热液交代安山岩而形成的认识,对于在矿区寻找VMS型矿床、区域内寻找海底热水喷流沉积型矿床具有重要的启示意义。     

新疆阿尔泰蒙库铁矿床的成矿流体及成矿作用

蒙库大型铁矿床赋存于上志留统—下泥盆统康布铁堡组变质火山-沉积岩系中,容矿岩石为石榴子石矽卡岩、变粒岩、浅粒岩和大理岩。矿体总体顺层分布,空间上与矽卡岩密切相关。研究表明,矽卡岩期石榴子石以发育玻璃质熔融包裹体、流体熔融包裹体和流体包裹体为特征,晚期矽卡岩阶段矿物中发育液相包裹体,变质期矿物中主要发育液相包裹体和含子矿物包裹体。矽卡岩期熔融包裹体的均一温度为1100℃,早期矽卡岩阶段流体包裹体均一温度变化于193～499℃,在450℃、350℃和230℃出现峰值。中期矽卡岩阶段均一温度变化于236～550℃,峰值为350℃。区域变质期均一温度介于132～513℃,在350℃、230℃和190℃出现峰值。流体包裹体的盐度w(NaCleq)介于1.23%～60.31%,流体密度变化于0.60～1.16g/cm3。石榴子石、石英和方解石的δ18OSMOW变化于0.2‰～8.4‰,δ18OH2O介于-5.1‰～5.33‰,δD为-127‰～-81‰,表明矽卡岩期成矿流体主要是岩浆水,混合少量大气降水;变质期流体主要为大气降水,为混合变质水。方解石δ13CPDB变化于-6.1‰～-2.3‰,表明流体中碳来自深部或地幔。成矿时代为早泥盆世早期(略晚于404～400Ma),成矿作用与矽卡岩的退化变质作用有关。