Fluid-driven Hydrovolcanic Activity along Fracture Zones and near Seamounts: Evidence from Deep-sea Fe-rich Spherules,Central Indian Ocean Basin

An insight on occurrence of Fe-rich spherules from the Central Indian Ocean Basin (CIOB) provides an understanding of their distribution at a water depth of >5,000 m. In the present study, Fe-rich spherules are identified to occur in two different sediment types (i.e., siliceous and pelagic) and tectonic settings (i.e. near seamounts and fracture zones). These are single spheres or aggregates, of different sizes (63 to 390 μm) and show textural variability (smooth/quenched, brickwork, corkscrew, interlocking and dendritic). A comparative study based on physical morphology and chemical composition suggests a common mechanism of formation. The association of spherules with fracture zones (FZ) and seamounts signifies that morpho-tectonic features play an important role in fluid-driven hydrovolcanism. Based on the evidence and geologic conditions existing in the basin, we conclude that molten fuel-coolant interaction (MFCI) coupled with submarine hydrothermal exhalations could be an ideal mechanism for the formation of spherules and Fe-particles. The accretion of the spherules on the surface sediments could be a result of recent volcanic phenomena, while those occurring at different depths (280–355, and 460–475 cm-bsf) within the sediment core indicate two different episodes. The study provides a global implication in understanding fluid-driven magmatism in a deep-sea intraplate environment.     

Spherule textures in the Neoarchaean Wittenoom impact layer,Western Australia: consistency in diversity

The Wittenoom Formation (Hamersley Group, Western Australia) is a well-preserved Neoarchaean unit deposited in a deep shelf to upper slope setting. The upper part contains several laterally persistent marker beds, one of which is rich in well-preserved spherules of former silicate melt showing a diverse suite of internal textures. We quantified the relative abundances of these textures by point counting in spherule-rich samples selected from seven sites and found them to be surprisingly uniform for a lateral distance of?>?350 km. They also appear to be uniform at one site where the layer is thicker and contains multiple zones rich in spherules. Given this homogeneity and by comparison to experimentally produced textures and K/T impact spherules, we infer that: (i) the homogeneously diverse nature of the ejecta is most consistent with an impact origin; (ii) the spherules were partially crystallised at the time they were deposited and therefore classifiable as microkrystites; (iii) the original impact melt was roughly basaltic in composition; (iv) the spherules were generated by a single impact then deposited in multiple pulses; (v) the K/T impact model is not directly applicable to the Wittenoom spherule layer; and (vi) the Wittenoom spherule layer was not formed by the same impact as the Carawine layer.     

Spherules from the Late Cretaceous Phosphorite of the Fatehgarh Formation, Barmer Basin, India

A first report of discovery of spherules, glassy balls, highly magnetic fine dust and microbracciated matrix in the Fatehgarh Formation of Barmer Basin, Rajasthan, India is being presented in this paper. The Fatehgarh Formation is a mixed siliciclastic, carbonate and phosphorite formation of Cretaceous age in the Barmer Basin that comprises sediments of Middle Jurassic to Lower Eocene age. The phosphorite zone in the Fatehgarh Formation is 8 metre-thick zone that comprises phosphatic sandstone, bone bed, bedded phosphorite and phosphatic and non phosphatic gastropod beds. The spherules occur in a thin phosphatic-clay mud and silt band of bone bed, which also yielded a very rich and diverse microvertebrate assemblage with a dominant Late Cretaceous (Maastrichtian) form of Igdabatis along with forms comprising of Semionodontid, Lapisosteum and Enchodontid. The end Cretaceous is marked for a mass extinction of numerous species including dinosaurs. An extraterrestrial impact is interpreted as the reason for this mass extinction. Whether these spherules are related to the volcanic source or K/T Boundary impact ejecta found at Caribbean and Gulf of Mexico region needs detailed chemical and age characterization for which study is in progress.     

北方前寒武纪长城系常州沟组的宇宙尘

河北滦县、蓟县、北京十三陵三个地方的常州沟组宇宙尘是在人工重砂的重矿物中发现的,产在古老沉积岩地层中的砾岩和砂岩里,大部分是铁质宇宙尘,形态各异,表面构造多种多样,内部构造各有不同,具Fe—Ni金属,核与壳的化学元素分布不匀匀,化学成分与深海宇宙尘相似。     

南极碳质球粒陨石中两个富尖晶石球粒状难熔包体的岩石学和矿物化学特征

富尖晶石球粒状CAI(富Ca-Al难熔包体)是球粒陨石中一种特殊类型的CAI,在南极格罗夫山碳质球粒陨石GRV020025和GRV021579中共发现两个富尖晶石球粒状CAI———GRV020025-3RI8和GRV021579-3RI5。GRV020025-3RI8具有占统治地位的尖晶石,在球粒的最外边存在严重蚀变的不规则边,钙钛矿主要分布在靠近边的位置。与GRV020025-3RI8比较,GRV021579-3RI5的尖晶石中的钙钛矿消失,深绿辉石出现,薄薄的蚀变层位于尖晶石核和富钙辉石边之间。两个富尖晶石球粒状CAI的尖晶石均具有低含量FeO和ZnO的特征,而且GRV021579-3RI5具有较GRV020025-3RI8更高的TiO2含量。岩石学和矿物化学特征表明,GRV020025-3RI8和GRV021579-3RI5都经历过熔融结晶过程,它们的蚀变均发生在非氧化的含水或无水的环境中。     

Discovery of Cosmic Spherules from the Mesoproterozoic Strata and its Significance—in Case of the Ming Tombs Area, Beijing

This study covers cosmic spherules derived from the Mesoproterozoic Dahongyu Formation in the Ming Tombs area, Beijing. The cosmic spherules include iron oxide cosmic spherules, carbonaceous chondrites, and atomic iron “steely bead”-shaped cosmic spherules. The mineral assemblage of silicon carbide, forsterite, zircon, and glass spherules and fragments were picked from melt-silicified carbonate of the Mesoproterozoic Dahongyu Formation (ca. 1625 Ma). Cosmic spherule assemblages are solely discovered from sedimentary rocks in China. Platinum group elements (PGE) were determined for the first time in cosmic spherules and associated minerals. PGE comparative observation between meteorite and cosmic spherules is presented in this study. It is recognized that an extraterrestrial meteorite impact event might have occurred in the Dahongyu Stage. The main evidence is a large number of iron cosmic spherules in silicified oncolitic limestone, and associated cosmic silicon carbide, glass spherules, and fragments, as well as the presence of forsterite. The impact-volcanic crater is characteristic of a big black shale block dropped into the bended silicified limestone.     

Magnetic Susceptibility Screening of Anthropogenic Impact on the Danube River Sediments in Northwestern Bulgaria - Preliminary Results

Several events of anthropogenic impacts on the floodplain river sediments of the Danube along a section near the town of Oryakhovo (NW Bulgaria) have been detected using magnetic technique. In the field, magnetic susceptibility was measured using three susceptibility meters – MS2D, KT-5 and SM30. The differences in the surface susceptibility values measured with the different instruments are ascribed to the various penetration depths which depend on several parameters like sensor diameter, frequency and field strength. This is supported by the detailed laboratory study on penetration depth and sensitivity of the new SM30 susceptibility meter and the comparison with the already existing data for the other two sensors. Boundaries between different flooding events are clearly linked with significant variability of the measured susceptibility values corresponding to one and the same level. Sediment cores, taken at different distances from the water level, show the history of depositional events and corresponding degree of anthropogenic pollution. Identification of the magnetic phases responsible for the signal was carried out by means of thermomagnetic (T) curves. The main carrier is magnetite with Tc of 580°C or oxidized magnetite with Tc of 600°C. A second kink at about 300°C is better expressed for samples with lower susceptibilities. It may correspond to several minerals, e.g. maghemite, pyrrothite, titanomagnetite, as well as different mineral transformations of paramagnetic minerals (decomposition, dehydroxilation, etc. for example siderite, lepidocrocite). The samples showing strong magnetic enhancement are characterized by the predominance of magnetite. Optical microscopy on magnetic extracts shows the presence of small spherical particles, typical for the anthropogenic magnetic phases from high-temperature technological processes. Well expressed susceptibility variations along the cores suggest the presence of several stages of different degree of pollution, covering an estimated period of about 30 years.