The double solid reactant method: II. An application to the shallow groundwaters of the Porto Plain,Vulcano Island (Italy)

This paper presents an example of application of the double solid reactant method (DSRM) of Accornero and Marini (Environmental Geology, 2007a), an effective way for modeling the fate of several dissolved trace elements during water–rock interaction. The EQ3/6 software package was used for simulating the irreversible water–rock mass transfer accompanying the generation of the groundwaters of the Porto Plain shallow aquifer, starting from a degassed diluted crateric steam condensate. Reaction path modeling was performed in reaction progress mode and under closed-system conditions. The simulations assumed: (1) bulk dissolution (i.e., without any constraint on the kinetics of dissolution/precipitation reactions) of a single solid phase, a leucite-latitic glass, and (2) precipitation of amorphous silica, barite, alunite, jarosite, anhydrite, kaolinite, a solid mixture of smectites, fluorite, a solid mixture of hydroxides, illite-K, a solid mixture of saponites, a solid mixture of trigonal carbonates and a solid mixture of orthorhombic carbonates. Analytical concentrations of major chemical elements and several trace elements (Cr, Mn, Fe, Ni, Cu, Zn, As, Sr and Ba) in groundwaters were satisfactorily reproduced. In addition to these simulations, similar runs for a rhyolite, a latite and a trachyte permitted to calculate major oxide contents for the authigenic paragenesis which are comparable, to a first approximation, with the corresponding data measured for local altered rocks belonging to the silicic, advanced argillic and intermediate argillic alteration facies. The important role played by both the solid mixture of trigonal carbonates as sequestrator of Mn, Zn, Cu and Ni and the solid mixture of orthorhombic carbonates as scavenger of Sr and Ba is emphasized.

Characteristic analysis on oxygen isotopic tracer in the East China Sea and waters to east of the Ryūkyū-guntō

Samples of O isotopic tracer were mlleMed at Sections P₃,P₂₅,P_cM-t/2-E and P_CM-1/2.w in both the Fast China Sea and the area to the east of the Ryūkyū-gunto during October-November,1991.Analytical results of the δ¹⁸O are as follows: (1) In the Kuroshio area,the δ¹⁸O isolines are almost parallel to the 200 m isobath.The value of δ¹⁸O is negative and reaches minimum mt the main axis of the Kuroshio,and increases on both sides.(2) In the Taiwan Warm Current (TWC) area there is a high δ¹⁸O tongue extending to the northeast.(3) In the area near the coast,the distribution of δ¹⁸O isoline shows that the Changjiang River runoff diffuses seaward and the land-ocean isotopic effect from the nearshore to the offshore.(4) The values of δ¹⁸O are from -1.0×10^-3 to -0.5×10^-3 in the shelf.(5) There is a low mre of δ¹⁸O value(<-1.6×10^-3) at the 600 m layer in the Kuroshio area,which is quite in accord with the existence of a low salinity mre (S G 34.30) between the 600 and 800 m layers in the same area.Finally,the mrrelations of the δ¹⁸O with the salinity and temperature,the upwelling and so on are discussed.     

PLATEAU TYPE E(%)-pH CURVES OF INTERFACIAL EXCHANGE BETWEEN LIQUID AND SOLID IN SEAWATER

A study on the curves of the exchange ratio E(%)-pH on the liquid-solid interface of the systems Zn(II) with clay minerals (Kaolinite , illite and montmorillonite), Zn(II) with hydrous ferric oxides (amorphous ferric oxide, goethite and hematite). Zn(II) with hydrous manganese oxide (y-MnOOH, manganite and 5-MnO2) etc . in seawater resulted in the discovery of new plateau type exchange ratio ?%)-pH curves not yet reported in literature. The two factors that decide the growth , decline and the change of the " plateau type " curve are : (1) the inherent characteristics of systems , which can be explained by the exchange constants i(i=1 ,2 , 3 . etc .) of interfacial stepwise ion / coordination particle exchange between liquid and solid ; and (2)The theory of interfacial stepwise ion/coordination(the amount of solid exchange reagent)particle exchange in seawater was applied to explain the experimental results of the above study and a general formula was derived for the plateau type exchange ratio E(%)-pH c     

矿山固体废弃物对地质环境的影响分析

在山西省重点地区固体废弃物现状调查研究的基础上,通过试样试验,分析研究了固体废弃物对土壤、大气、水环境的污染,探讨了对固体废弃物的治理及利用,为研究矿山生态环境地质研究提供参考,同时积累工作经验。     

Decarbonation reaction of magnesite in subducting slabs at the lower mantle

High-pressure and temperature experiments (28–62 GPa, and 1,490–2,000 K, corresponding to approximately 770–1,500 km depth in the mantle) have been conducted on a MgCO₃ + SiO₂ mixture using a laser-heated diamond anvil cell combined with analytical transmission electron microscope observation of the product phases to constrain the fate of carbonates carried on the subducting basalt into the lower mantle. At these conditions, the decarbonation reaction MgCO₃ (magnesite) + SiO₂ (stishovite) → MgSiO₃ (perovskite) + CO₂ (solid) has been recognized. This indicates that above reaction takes place as a candidate for decarbonation of the carbonated subducting mid ocean ridge basalts in the Earth’s lower mantle.     

滇池农村固体废物和化肥流失治理试验研究

怎样合理处置农村固体废物和减少农田化肥流失一直是农村面源污染控制的难题之一。该研究将农村固体废物的处理与减少化肥施用措施有机结合，利用微生物复合发酵剂和农村固体废物生产活性肥料，开展了一系列农业种植试验和数据监测，在此基础上，提出了一套实用性强、效果好的控制农业固体废物和化肥流失污染的对策措施。     

镍铜硫化物矿石中磁黄铁矿固溶体的退火及其选矿意义

磁黄铁矿固治体从硫化物熔体结晶后，在缓慢冷却过程中经历了显著的退火。出治和出治体的租化是固治体退火的两种方式。叶片状的单斜磁黄铁矿和“火焰状”的镍黄铁矿原始出治相在降温过程中均可发生退火和租化。分布于磁黄铁矿等矿物粒间或包于磁黄铁矿粒内的粒状镍黄铁矿，不只是高温出治的直接产物，有一部分可能是由火焰状出治体租化而成的。磁黄铁矿中单斜变体的出治和租化可使矿石的磁性发生改变，镍黄铁矿出治体的租化使含镍矿物的粒度加大。因而，退火作用对矿石的选矿工艺性能有着显著影响。     

固体粒子的稳泡机理

固体粒子是良好的稳泡剂，其稳泡作用实质是在气－水界面产生吸附，形成固态膜，固态膜致密性强，机械强度高，表面粘度大。固体粒子的润湿性能，粒子大小及形状对固态膜的牢固程度有很大影响。     

地层模型的三维实体显示与剖切

本文介绍了地层模型的三维实体显示的原理与方法，同时又提出了沿任意方向垂直剖切地层模型的一种实用有效算法，它已用于交互式三维地层矿床显示系统ＧＤ－３ＤＷＳ，是三维地质解释的很好工具     

格子Boltzmann方法地震波场模拟

格子Ｂｏｌｔｚｍａｎｎ方法是细胞自动机在某些学科中的具体化和应用。它根据微观运动过程的某些基本特征建立简化的、时间和空间完全离散的动力学模型，这种模型的平行行为符合宏观的微分方程。