碱消解-高效液相色谱-电感耦合等离子体质谱法测定生物样品中的甲基汞和乙基汞

建立了碱消解-高效液相色谱-电感耦合等离子体质谱联用系统测定生物样品中甲基汞(MeHg)与乙基汞(EtHg)的分析方法。为提高灵敏度,选用微流量的PFA雾化器,在优化的检测条件下,MeHg及EtHg检出限可达到0.036μg/L和0.03μg/L;线性范围达到4个数量级,两条工作曲线线性相关系数为1。对1.78μg/L MeHg、1.65μg/L EtHg的混合标准溶液重复测定7次,色谱峰面积的相对标准偏差(RSD)分别为1.79%和1.44%。对标准物质BCR 464(金枪鱼)的分析结果表明,测定值与标准值基本吻合,但略低于标准值;甲基汞和乙基汞的加标回收率分别为85.9%和84.5%。高效液相色谱与质谱联用技术的高灵敏度和低检出限能够满足生物样品中汞形态定量分析的要求。     

Problems of soil and groundwater pollution in the disposal of “marble” slurries in NW Sicily

This work deals with disposal of slurries generated during the cutting and polishing processes of slabs of decorative sedimentary carbonate rocks in the north western Sicily. At present, they are used as fillers of dismantled quarries near the sawmills and, as a final step of reclamation, are covered with earth layers. In spite of such inexpensive solution, there is lack of knowledge about the composition of the waste. In order to assess if there is any threat for the environment and to suggest indications for alternative solutions, such as recycling or inactivation processes, the slurries were analysed by XR diffraction, simultaneous thermal analysis, ICP/MS, ionic chromatography, FTIR, UV-Vis, COD and TOC measurements, grain size analysis. Results indicate that the slurries can threaten the groundwater, because of the high chemical oxygen demand; furthermore they can modify the mechanism of groundwater recharge, because of their grain size distribution. Some laboratory tests show that, even in very aggressive conditions, the solid pollutants persist in the waste and slowly release into water the products of their degradation. The slurry therefore should be subjected to inactivation treatment before disposal or, alternatively, recycled as secondary raw material for a suitable process.     

几丁糖酯原料药稳定性研究

该文建立高效凝胶渗透色谱法 (HPGPC) ,明胶比浊法 ,氧瓶燃烧法三种分析方法考察海洋硫酸多糖药物几丁糖酯的稳定性 ,采用这三种方法分别考察几丁糖酯原料药在高温、高湿、强光照射及加速条件下分子量及分布宽度、样品中硫酸根含量及样品含量的变化情况。结果表明 :三种方法均适用于几丁糖酯的稳定性考察 ,几丁糖酯在上述影响因素条件下稳定性良好     

Jason-1: Assessment of the System Performances

On 7 December 2001, Jason-1 was successfully launched by a Boeing Delta II rocket from the Vandenberg Air Force Base, California. The Jason-1 satellite will maintain the high accuracy altimeter service provided since 1992 by TOPEX/Poseidon (T/P), ensuring the continuity in observing and monitoring the Ocean Dynamics (intraseasonal to interannual changes, mean sea level, tides, etc.). Despite one-fourth the mass and power, the Jason-1 system has been designed to have basically the same performance as T/P, measuring sea surface topography at a centimetric level. This new CNES/NASA mission also provides near real-time data for sea state and ocean forecast. The first two months of the Jason-1 mission have been dedicated to the assessment of the overall system. The goals of this assessment phase were:

1. To assess the behavior of the spacecraft at the platform and payload levels (Jason-1 being the first program to call on the PROTEUS versatile multimission platform for Low and Medium Earth Orbit Missions developed in partnership between Alcatel Space and CNES);

2. To verify that platform performance requirements are met with respect to Jason-1 requirements;

3. To verify that payload instruments performance requirements evaluated at instrument level are met;

4. To assess the performance of the Jason-1 Ground System.

This article will display the main outputs of the assessment of the system. It will demonstrate that all the elements of the onboard and ground systems are within the specifications. Provision of data to the Jason-1 Science Working Team started at the end of March 2002. This is the goal of a six-month phase after closure of the initial assessment phase to derive the error budget of the system in terms of altimetry user products.     

大亚湾水域两种拟菱形藻的形态学鉴定及毒素分析

对2005年分离自广东大亚湾的两种潜在产毒拟菱形藻进行了形态学观察和毒性分析.通过透射电子显微镜(TEM)观察确认藻种为细弱拟菱形藻(Pseudo-nitzschia cuspidata)和多纹拟菱形藻(P.multistriata).采用高效液相色谱法(HPLC)对这两种藻的常规培养样进行软骨藻酸毒素检测,结果均未检测到软骨藻酸.鉴于以上两种拟菱形藻存在着潜在产毒特性,不同培养条件的诱导实验尚需继续.     

An Electronic Chart Display and Information System

This article introduces the most advanced form of electronic chart display and information systems (ECDIS) which complies with the performance standards for ECDIS established by the International Maritime Organization (IMO) and International Hydrographic Organization (IHO). It also describes the key features and the important functions of ECDIS, which we developed. This system is different from the productions developed by C-map, Seven-cs, offshore, and others. It is more suitable for China Marine Safety Administration Bureau to manage the navigation marks real-time. Using this system charts were located and accessed rapidly, and displayed smoothly. This article also discusses in ECDIS application system how to dynamically access and desert charts data in a limited memory (limited computer memory and resource). We constructed a tridimensional structure to manage a large amount of charts data. Vertically, according to the scale range, all charts were divided into eight levels, and a data structure called as “Multiple Scale Quad-tree” was constructed. And horizontally, a grid (every unit has a fixed size) was given to a certain scale level. We call this data structure a “Regular Page.” We explore the implementation of such a structure on the worldwide charts management utilizing quad-trees. Then we discuss the future development of ECDIS and its application system in marine agencies in China.     

川西南周公山及邻区下二叠统碳酸盐岩成岩作用对储集性的影响

川西南周公山及邻区下二叠统的中-低孔、中-低渗碳酸盐岩储层的储集空间以次生成因的溶孔、溶洞和构造裂缝为主.研究认为,多世代方解石胶结、化学充填作用以及埋藏期的压实(溶)作用是孔隙很难得到保存的主要原因;同生-准同生期的混合水云化作用和表生期、埋藏期的流体溶蚀作用则产生了大量的次生溶孔、洞,使储层的孔渗性得到明显的改善;构造破裂作用可以产生新的储集空间,还影响各储集体之间及单一储集体内部空隙的连通.成岩相分为混合水云化-溶蚀-破裂相、溶蚀-胶结相和胶结-压实-压溶相.各种成岩作用的叠加形成了现今下二叠统油气储层的分布格局.     

Performance of Mortar and Chemical Grout Injection into Surrounding Soil When Slurry Pipe-jacking Method is Used

Small-diameter shallow tunnels are often being built by using the slurry pipe-jacking method. This system involves the pushing or thrusting of a drivage machine and concrete pipes into the ground. Chemical grout injection into the surrounding soil around the tunnel is carried out after the drivage and pushing processes are finished. The purpose of the chemical grout injection is to maintain permanent stability of the surrounding soil. However, the behavior of the chemical grouting material in the surrounding soil around the tunnel and the amount of optimum injection is not clearly understood. From these points of view, this paper discusses the performance of the chemical grouting material, when it is injected into the surrounding soil around the tunnel, by means of 2-D Eulerian–Lagrangian seepage analysis. Moreover, the effectiveness of the chemical grout injection was evaluated by using the non-linear finite element method. This investigation show when the range of the grouted zone is designed; it is necessary that the relationship between Young’s modulus of the soil/grouted zone and the confining stress be taken into consideration in order to establish effective, economical and safe chemical grout injection system. Understanding the performance of the seepage/dispersion behavior of the chemical grout and the characteristics of soil/ grouted zone is also important.     

Monitoring of Over Cutting Area and Lubrication Distribution in a Large Slurry Pipe Jacking Operation

Slurry pipe jacking was firmly established as a special method for the non-disruptive construction of the underground pipelines of sewage systems. Pipe jacking, in its traditional form, has occasionally been used for short railways, roads, rivers, and other projects. Basically the system involves the pushing or thrusting of concrete pipes into the ground by a number of jacks. In slurry pipe jacking, during the pushing process, mud slurry and lubricant are injected into the face and the over cutting area that is between the concrete pipes and the surrounding soil. Next, the slurry fills voids and the soil stabilizes due to the created slurry cake around the pipes. Fillings also reduce the jacking force or thrust during operation. When the drivage and pushing processes are finished, a mortar injection into the over cutting area is carried out in order to maintain permanent stability of the surrounding soil and the over cutting area. Successful lubrication around the pipes is extremely important in a large diameter slurry pipe jacking operation. Control of lubrication and gaps between pipes and soil can prevent hazards such as surface settlement and increases in thrust. Also, to find voids around the pipes after the jacking process, in order to inject mortar for permanent stabilizing, an investigation around the pipes is necessary. To meet these aims, this paper is concerned with the utilization of known methods such as the GPR (Ground Penetrating Radar) system and borehole camera to maintain control of the over cutting area and lubricant distribution around the pipes during a site investigation. From this point of view, experiments were carried out during a tunnel construction using one of the largest cases of slurry pipe jacking in Fujisawa city, Japan. The advantages and disadvantages of each system were clarified during the tests.