有咸水区深层淡水可持续利用研究

天津市东丽区第四系Ⅱ组深层淡水在长期较强开采状态下未发生水位持续下降及大面积深层淡水成化污染,十余年来地层沉降基本消失.该地多年来中更新统淡水及上更新统、全新统咸水水位具有同步不等幅的动态,证明它们之间联系密切,地层中渗透系数小于10-3m/d的历次海侵沉积层及压实的粘土层具有半透膜特性,咸水越流补给第Ⅱ承压含水组的是淡水.适量加大Ⅱ组淡水开采强度,使其产生越流系统,稳定后不会再加大地面沉降.最终使全新统地下水下入渗水位降低,夺取潜水蒸发的水量.在有咸水分布区,地表入渗水是尚没有引起足够重视的可持续利用地下淡水的补给来源.     

Semi-analytical solutions to one-dimensional consolidation for unsaturated soils with symmetric semi-permeable drainage boundary

This paper presents semi-analytical solutions to Fredlund and Hasan’s one-dimensional consolidation for unsaturated soils under symmetric semi-permeable drainage boundary conditions. Two variables are introduced to transform two coupled governing equations of pore-air and pore-water pressures into an equivalent set of partial differential equations, which are easily solved by the Laplace transform. Then, the pore-air and pore-water pressures, and soil settlement are obtained in the Laplace domain. Crump’s method is adopted to perform the inverse Laplace transform in order to obtain semi-analytical solutions in time domain. It is shown that the present solution is more applicable to various types of drainage boundary conditions, and in a good agreement with existing solutions from the literature. Furthermore, several numerical examples are provided to investigate the consolidation behavior of an unsaturated single-layer soil with traditional drainage boundary (single or double), and single-sided and double-sided semi-permeable drainage boundaries. Finally, it illustrates the changes in pore-air and pore-water pressures and soil settlement with time at different values of symmetric semi-permeable drainage boundary conditions parameters. In addition, parametric studies are conducted by the variations of pore-air and pore-water pressures at different ratios of air-water permeability coefficient and the depth.     

An explicit one-dimensional consolidation solution with semi-permeable drainage boundary for unsaturated soil

Existing solutions for analyzing one-dimensional (1-D) consolidation of unsaturated soil are only derived to cater to two extreme drainage conditions (fully drained and undrained). This study presents a new explicit solution for 1-D consolidation of unsaturated soil with semi-permeable drainage boundary. Based on the assumptions of two independent stress variables and the governing equations proposed by Fredlund, the eigenfunction expansion method is adopted to develop an explicit analytical solution to calculate excess pore-water and pore-air pressures in an unsaturated soil when it is subjected to external loads. The developed general solutions are expressed in terms of depth, z, and time, t. For the semi-permeable drainage boundary, eigenvalues and eigenfunctions in the space domain are developed. The technique of Laplace transform is used to solve the coupled ordinary differential equations in the time domain. The newly derived explicit solution is verified with the existing semi-analytical method in the literature, and an excellent agreement is obtained. Compared with the semi-analytical solution, the newly derived analytical solution is more straightforward and explicit so that this solution is relatively easier to be implemented into a computer program to carry out a preliminary assessment of 1-D consolidation of unsaturated soil.     

利用非金属矿物原料研制半渗透陶瓷隔板

利用五种非金属矿物原料,按照科学的制造工艺,研制成功了高压半渗透隔板仪的核心部件——半渗透陶瓷隔板,广泛用于油气勘探和开发中测定流体分布和孔隙大小。其主要技术指标为:突破压力(过气)1—2兆帕(MPa),过水压力0.001—0.05兆帕,抗拉强度141kg/cm~2,抗压强度1310kg/cm~2,产品合格率达75％以上,其中达到国际先进水平的占32％。     

地下水中半透膜采样方法的室内模拟实验研究

利用含有三油酸甘油酯的半透膜装置进行室内模拟实验,得出有机氯农药在水相和半透膜之间分配的平衡时间和富集系数．平衡时间除δ—BHC为234h和p,p′-DDE、o,p—DDT为70h外,其余组分均为594h;α—BHC、六氯苯、β—BHC、γ—BHC、δ—BHC、七氯、艾氏剂、七氯环氧、p,p′—DDE、狄氏剂、异狄氏剂、p,p′—DDD、o,p—DDT、p,p′-DDT富集系数分别为：0．061,0．071,0．098,0．066,0．033,0．014,0．007,0．062,0．108,0．052,0．029,0．032,0．061ml／h。七氯、艾氏剂、o,p—DDT、p,p′-DDE以及p,p′-DDT组分在膜中的平衡浓度远小于它们在水中浓度,不适于用此种方法进行富集;异狱氏剂和p,p′-DDD组分在膜中的平衡浓度与水中的浓度相当．也不适于用此种方法;α—BHC、六氯苯、γ-BHC、δ-BHC、七氯环氧和狄氏剂的在膜中最大的富集浓度为2倍左右;β-BHC在膜中最大的富集浓度为4倍左右体现了对这些组分的浓缩作用．适合用这种方法进行富集。     

半透水边界下分数阶黏弹性饱和土一维固结特性分析

为描述饱和土体的流变特性,引入分数阶导数Kelvin-Voigt黏弹性模型,采用解析方法对半透水边界下的分数阶黏弹性饱和土一维固结特性进行了研究。分别对骤加恒载下饱和土一维固结微分方程和分数阶Kelvin-Voigt黏弹性本构方程进行Laplace变换,并联立求解得到了双边半透水边界条件下分数阶黏弹性饱和土在Laplace变换域内的解析表达式。通过Crump方法实现Laplace数值反演,得到时间域内的半解析解。将所得到的解分别退化为分数阶黏弹性饱和土一维固结半解析解和双边半透水黏弹性饱和土一维固结半解析解,结果与已有文献半解析解相同,验证了提出的双边半透水边界条件下分数阶黏弹性饱和土一维固结解的可靠性。通过算例考察了半透水边界条件和分数阶黏弹性饱和土参数对一维固结特性的影响。研究表明,双边半透水边界下分数阶黏弹性饱和土一维固结发展过程与半透水边界条件、分数阶次和黏滞系数有关,且土体的压缩模量对饱和土一维固结最终沉降量有显著影响。     

利用半透膜渗透装置富集-超声萃取分析表层沉积物间隙水PCBs的方法

本文建立了半透膜渗透装置(semi-permeable membrane device,SPMD)富集-超声萃取-凝胶渗透色谱净化-气相色谱法测定沉积物间隙水中多氯联苯(PCBs)的方法。比较了有机溶剂透析法与超声萃取法从膜袋内提取PCBs的回收率,发现超声萃取法在节省时间和溶剂方面有明显优势。应用凝胶渗透色谱分离与净化SPMD提取物,收集11—17min的流出液能达到最佳分离效果。基于此方法测定了大连湾沉积物间隙水中自由溶解态PCBs的含量(C_(W-SPMD)),同时又分析了沉积物中PCBs的总量(C_(SED))、间隙水中PCBs的含量(有机碳含量校正法,C_(W-SED))和间隙水中PCBs的总含量(离心法,C_(PW))。结果表明,C_(PW)值显著高于C_(W-SED)和C_(W-SPMD)值。因此,考虑到生物可利用性,无论采用沉积物中或者间隙水中的PCBs总量进行污染物生态风险评价均会造成风险被高估,建议采用间隙水中可溶解态含量。     

海水pCO2流通式光度测定方法研究

将膜分离技术与流动注射分析相结合 ,采用聚四氟乙烯疏水性微孔膜 ,使样品流与接受液流进行物理分离。通过测定含有显色剂的接受液流吸光度的变化来测定 p CO2 ,初步建立海水中p CO2 流通式光度测定方法。该方法的相对标准偏差小于 1.2 %,与气相色谱法相比 ,无显著性差异。整个实验仅需 11min,样品用量不到 10 m L,操作简便、快速。     

地下水中有机氯农药的半透膜采样方法野外实验

利用含有甘油三油酸酯的半透膜装置进行室内模拟实验和野外验证实验，旨在开发一种可以模拟生物过程的监测地下水的方法。得出了有机氯农药在水相和半透膜之间分配的平衡时间和富集系数，平衡时间除δ-BHC为234h和p，p’-DDE、o，p-DDT为70h外，其余组分均为594h；α—BHC、六氯苯、β—BHC、γ—BHC、δ-BHC、七氯、艾氏剂、七氯环氧、p，p’-DDE、狄氏剂、异狄氏剂、p，p’-DDD、o，p’-DDT,p，p，-DDT富集系数分别为：0．061、0．071、0．098、0．066、0．033、0．014、0．007、0．062、0．108、0．052、0．029、0．032、0．061 mL／h。七氯、艾氏剂、o，p—DDT、p，p’-DDE以及p，p’-DDT组分在膜中的平衡浓度远小于它们在水中浓度，不适于用此种半透膜取样器进行富集；在凉水河岸边的野外实验结果也验证了半透膜装置监测地下水有机氯农药的可行性，但其个别组分的结果出现异常，需要在该地区进一步开展工作进行研究。     

An evaluation of the osmotic method of controlling suction∗

Experimental techniques of testing the mechanical properties of unsaturated soils are complex and difficult to conduct. As a consequence, complete sets of parameters that characterise the behaviour of unsaturated soils remain scarce and necessary. In this context, it has been found useful to gather the information obtained after some years of practice of the osmotic technique of controlling suction. As compared to the more documented axis-translation technique, the osmotic technique has its own advantages and drawbacks that are discussed in this paper, together with some potential future developments.

The osmotic method has been developed by soil scientists in the 1960s and adapted to geotechnical testing in the early 1970s. This paper presents the osmotic technique and comments on its advantages (including suction condition close to reality and higher suctions easily attained) and drawbacks (including some concern with the membrane resistance and some membrane effects in the suction/concentration calibration). Various applications to geotechnical testing are presented such as the determination of the water retention curve, oedometer and triaxial testing procedures and the determination of the permeability of unsaturated soils. Recent developments, that include the extension of the method up to high suctions (10 MPa) are also described, together with some recent and novel applications such as data from high controlled suction oedometer compression test and the determination of the oil/water retention properties of oil reservoir chalks.