碱消解-高效液相色谱-电感耦合等离子体质谱法测定生物样品中的甲基汞和乙基汞

建立了碱消解-高效液相色谱-电感耦合等离子体质谱联用系统测定生物样品中甲基汞(MeHg)与乙基汞(EtHg)的分析方法。为提高灵敏度,选用微流量的PFA雾化器,在优化的检测条件下,MeHg及EtHg检出限可达到0.036μg/L和0.03μg/L;线性范围达到4个数量级,两条工作曲线线性相关系数为1。对1.78μg/L MeHg、1.65μg/L EtHg的混合标准溶液重复测定7次,色谱峰面积的相对标准偏差(RSD)分别为1.79%和1.44%。对标准物质BCR 464(金枪鱼)的分析结果表明,测定值与标准值基本吻合,但略低于标准值;甲基汞和乙基汞的加标回收率分别为85.9%和84.5%。高效液相色谱与质谱联用技术的高灵敏度和低检出限能够满足生物样品中汞形态定量分析的要求。     

Efficiency analysis of open trench for impact pile driving through a single-variable method

Abstract

The ground vibrations during pile driving operation have a drastic potential to undermine the surrounding structures both in land and reclaimed land. Particularly, reclaimed land necessitates ample application of pile driving due to the weak land condition. To prevent the structural damage, attenuation of the ground vibrations to an allowable level through active isolation of circular open trench is the scope of this study. In this research, finite element simulations of continuous impact pile driving process from the ground surface was executed with particular attention to the pile-soil interaction, and thereby, the efficiency of open trench application in attenuation of the unsafe distance of different structures was surveyed using the vibration sensitivity degree. Regarding the crucial parameters of an open trench (depth, width, and location), it was concluded that a sufficient high depth can attenuate the unsafe distance up to 68%, the trench width variations are less effective, and an average pile-trench distance is the most efficient option. The excavation volume was also concluded as another crucial parameter in open trench design which takes all three parameters into account. The trench depth equal to the pile’s maximum critical depth of vibration was inferred for an optimum design.     

A community-wide intercomparison exercise for the determination of dissolved iron in seawater

The first large-scale international intercomparison of analytical methods for the determination of dissolved iron in seawater was carried out between October 2000 and December 2002. The exercise was conducted as a rigorously “blind” comparison of 7 analytical techniques by 24 international laboratories. The comparison was based on a large volume (700 L), filtered surface seawater sample collected from the South Atlantic Ocean (the “IRONAGES” sample), which was acidified, mixed and bottled at sea. Two 1-L sample bottles were sent to each participant. Integrity and blindness were achieved by having the experiment designed and carried out by a small team, and overseen by an independent data manager. Storage, homogeneity and time-series stability experiments conducted over 2.5 years showed that inter-bottle variability of the IRONAGES sample was good (< 7%), although there was a decrease in iron concentration in the bottles over time (0.8–0.5 nM) before a stable value was observed. This raises questions over the suitability of sample acidification and storage.     

Kohonen网络与BP网络的集成应用研究

本文介绍了 Kohonen神经网络对输入数据进行聚类方法在卷烟配方中的应用 ,提出了从核心样本动态搜索 BP网络训练样本的新探索 ,摒弃了过去 BP算法中训练样本固定不变 ,互不相交的方法 ,实现了 BP网络和 Kohonen网络动态无缝集成。     

Sample Disturbance in Soft and Sensitive Clays: Analysis and Assessment

Despite the sophisticated methods employed to obtain high quality samples, they are prone to disturbance, due to stress release, let apart, due to sampling tools and techniques adopted. Critical reappraisal of different methods suggest that any method of sample quality assessment involving strength and deformation parameters would enable easier implementation and correct other engineering parameters for estimated sample disturbance. In this technical paper, sample disturbance index, using merely the slopes of compression paths, (representing mechanical response), in the pre- and post-yield stress regimes under odeometric loading conditions is proposed. This method is based on single oedometer test results on samples of unknown degrees of disturbance during sampling and handling. The unique feature of this approach is that the ideal rigid plastic material behavior is taken as reference. This eliminates the need for any additional experimental data or any calculations from the relationships formulated with any set of assumptions.     

离子色谱分析在黄土和粉尘研究中的应用

黄土中存在着大量的碱金属及碱土金属，以往的测试方法多为原子吸收和ICP—MS，离子色谱法在测试黄土样品的碱金属和碱土金属元素含量中应用不多。将黄土地质标准样品进行消解后用离子色谱进行测试，测试效果良好，重复测试的相对标准偏差小于5％，与推荐值的相对误差小于5％，准确度和精密度符舍相关的质量控制要求。本实验方法测试的离子含量都在仪器响应呈线性的最佳测试范围之内，标准曲线经回归后相关系数均达到0．9999。黄土样品的分析结果与粉尘气溶胶样品的离子分析结果对比表明，此方法对于探讨粉尘起源以及沙尘暴天气的研究具有重要意义。     

Optimum Sample Size to Detect Perturbation Effects: The Importance of Statistical Power Analysis – A Critique

Abstract. The current article describes statistical power analysis as an efficient strategy for the estimation of the optimum sample size. The principle aim is constructively to criticise and enrich the results presented by Mouillot et al. (1999) , who estimate the optimum sample size for evaluating possible perturbations. The authors did not make any reference to statistical power analysis, even though their objective clearly went beyond a simple stock evaluation to assess management strategies in a particular marine ecosystem. Surprisingly, they proposed (a priori) an ANOVA design to test a hypothesis considering both space and temporal scales. However, the authors did not cover important topics related with power analysis and the precautionary principle, both used into environment impact assessment programmes for marine ecosystems. Based on their results and on statistical power analysis, it is demonstrated that the variability (dispersion statistics), a key factor they used to estimate the sample size, is less relevant than the magnitude of perturbation (effect size). Therefore, a greater effort must be devoted to estimate the effect size of a particular phenomenon rather than a desired variability.     

A Numerical Model for Natural Backfill of Pipeline Trenches Subjected to Unidirectional／Oscillatory Flows

A numerical model for the self-burial of a pipeline trench is developed. Morphological evolutions of a pipeline trench under steady-current or oscillatory-flow conditions are simulated with/without a pipeline inside the trench. The oscillatory flow in this study represents the action of waves. The two-dimensional Reynolds-averaged continuity and Navier-Stokes equations with the standard k-e turbulence closure, as well as the sediment transport equations, are solved with the finite difference method in a eurvilirrear coordinate system. Both bed and suspended loads of sediment transport are included in the morphological model. Because of the lack of experimental data on the backfilling of pipeline trenches, the numericalmodel is firstly verified against three closely-relevant experiments available in literature. A detailed measurement of the channel migration phenomenon under steady currents is employed for the assessment of the integral performance of themodel. The two experimental results from U-tube tests are used to validate the model‘s ability in predicting oscillatory flows. Different time-marching schemes are employed for the morphological computation under unidirectional and oscillatory conditions. It is found that vortex motions within the trench play an important role in the trench development.     

Influence of dimethylsulfide produced by marine algae on the global climate

DMS (dimethylsulfide), a breakdown product of cellular solutes of many species of macroalgae andphytoplankton plays an important role in regulating global climate and counteracting partly the "greenhouse" effect.In this paper, the advance and prospects of DMS study are reviewed and discussed with respectto DMS sample storage, measurement and importance in regulating global climate and the acidity ofrain and aerosol.     

地震学定量预报指标的一种提取方法——对比筛选法

鉴于目前地震学综合定量预报指标的缺乏和预报工作的急需,尝试使用“对比筛选法(简称CSM方法)”进行地震学定量预报指标的提取试验。较之以往作法的进展在于:1.同时使用“有震”和“无震”两类样本对比筛选;2.对不同地区的地震学参数进行了归一化处理。这样做的显著优点是:1.可以较有效地提取“有震异常”和“正常变化”指标;2.提取的异常和预报指标具有定量化和普适性特点。 试验研究使用大华北地震区资料,研究对象取中强地震。经内符和外推检验,证明该方法提取的异常和预报指标有效性和实用性较高。