全文获取类型
收费全文 | 927篇 |
免费 | 146篇 |
国内免费 | 495篇 |
专业分类
测绘学 | 86篇 |
大气科学 | 38篇 |
地球物理 | 141篇 |
地质学 | 1047篇 |
海洋学 | 140篇 |
天文学 | 5篇 |
综合类 | 49篇 |
自然地理 | 62篇 |
出版年
2024年 | 4篇 |
2023年 | 26篇 |
2022年 | 39篇 |
2021年 | 48篇 |
2020年 | 58篇 |
2019年 | 50篇 |
2018年 | 26篇 |
2017年 | 38篇 |
2016年 | 54篇 |
2015年 | 64篇 |
2014年 | 57篇 |
2013年 | 78篇 |
2012年 | 57篇 |
2011年 | 76篇 |
2010年 | 83篇 |
2009年 | 82篇 |
2008年 | 70篇 |
2007年 | 66篇 |
2006年 | 61篇 |
2005年 | 57篇 |
2004年 | 40篇 |
2003年 | 52篇 |
2002年 | 49篇 |
2001年 | 44篇 |
2000年 | 38篇 |
1999年 | 35篇 |
1998年 | 32篇 |
1997年 | 25篇 |
1996年 | 33篇 |
1995年 | 19篇 |
1994年 | 22篇 |
1993年 | 22篇 |
1992年 | 13篇 |
1991年 | 18篇 |
1990年 | 8篇 |
1989年 | 6篇 |
1988年 | 8篇 |
1987年 | 2篇 |
1986年 | 1篇 |
1984年 | 3篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1980年 | 1篇 |
排序方式: 共有1568条查询结果,搜索用时 15 毫秒
1.
碱消解-高效液相色谱-电感耦合等离子体质谱法测定生物样品中的甲基汞和乙基汞 总被引:7,自引:2,他引:5
建立了碱消解-高效液相色谱-电感耦合等离子体质谱联用系统测定生物样品中甲基汞(MeHg)与乙基汞(EtHg)的分析方法。为提高灵敏度,选用微流量的PFA雾化器,在优化的检测条件下,MeHg及EtHg检出限可达到0.036μg/L和0.03μg/L;线性范围达到4个数量级,两条工作曲线线性相关系数为1。对1.78μg/L MeHg、1.65μg/L EtHg的混合标准溶液重复测定7次,色谱峰面积的相对标准偏差(RSD)分别为1.79%和1.44%。对标准物质BCR 464(金枪鱼)的分析结果表明,测定值与标准值基本吻合,但略低于标准值;甲基汞和乙基汞的加标回收率分别为85.9%和84.5%。高效液相色谱与质谱联用技术的高灵敏度和低检出限能够满足生物样品中汞形态定量分析的要求。 相似文献
2.
A strain of thermophilic fungus Aspergillus fumigatus was cultured with K-bearing minerals to determine if microbe-mineral interactions enhance the release of mineralic potassium. Experiments were carried out in two settings, one with the mineral grains and the fungal cells in direct contact, and the other employing a membrane (pore size 0.22 μm) to separate the two. Measurements over a period of 30 days showed that, irrespective of the experimental setup, the concentration of free K in the culture was drastically higher than those in any of the control experiments where no living organism was present. Moreover, the occurrence of mineral-cell physical contact enhanced potassium release by an additional factor of 3 to 4 in comparison to the separation experiments. For contact experiments, Electron Probe Microanalysis revealed the formation of mycelium-mineral aggregates, and Atomic Force Microscopy imaging further indicated the possible ingestion of mineral particles by the fungus cells. Contrasting to what was observed and expected in control experiments, the potassium solubilization rate showed a positive dependence upon pH when fungi and minerals were mixed directly, and exhibited no correlations with solution acidity if cell-rock contact was restrained. These results appear to suggest that A. fumigatus promoted potassium release by means of at least three likely routes, one through the complexation of soluble organic ligands, another appealing to the immobile biopolymers such as the insoluble components of secretion, and the third related to the mechanical forces in association with the direct physical contact between cells and mineral particles. 相似文献
3.
Two distinct series of slumps deform the upper part of the sedimentary sequence along the continental margin of the Levant.
One series is found along the base of the continental slope, where it overlies the disrupted eastern edge of the Messinian
evaporites. The second series of slumps transects the continental margin from the shelf break to the Levant Basin. It seemed
that the two series were triggered by two unrelated, though contemporaneous, processes. The shore-parallel slumps were initiated
by basinwards flow of the Messinian salt, that carried along the overlying Plio-Quaternary sediments. Seawater that percolated
along the detachment faults dissolved the underlying salt to form distinctly disrupted structures. The slope-normal slumps
are located on top of large canyons that cut into the pre-Messinian sedimentary rocks. A layer of salt is found in the canyons,
and the Plio-Quaternary sediments were deposited on that layer. The slumps are bounded by large, NW-trending faults where
post-Messinian faulted offset was measured. We presume that the flow of the salt in the canyons also drives the slope-normal
slumps. Thus thin-skinned halokynetic processes generated the composite post-Tortonian structural patterns of the Levant margin.
The Phoenician Structures are a prime example of the collapse of a distal continental margin due to the dissolution of a massive
salt layer. 相似文献
4.
Andrew R. Bowie Eric P. Achterberg Peter L. Croot Hein J.W. de Baar Patrick Laan James W. Moffett Simon Ussher Paul J. Worsfold 《Marine Chemistry》2006
The first large-scale international intercomparison of analytical methods for the determination of dissolved iron in seawater was carried out between October 2000 and December 2002. The exercise was conducted as a rigorously “blind” comparison of 7 analytical techniques by 24 international laboratories. The comparison was based on a large volume (700 L), filtered surface seawater sample collected from the South Atlantic Ocean (the “IRONAGES” sample), which was acidified, mixed and bottled at sea. Two 1-L sample bottles were sent to each participant. Integrity and blindness were achieved by having the experiment designed and carried out by a small team, and overseen by an independent data manager. Storage, homogeneity and time-series stability experiments conducted over 2.5 years showed that inter-bottle variability of the IRONAGES sample was good (< 7%), although there was a decrease in iron concentration in the bottles over time (0.8–0.5 nM) before a stable value was observed. This raises questions over the suitability of sample acidification and storage. 相似文献
5.
本文介绍了 Kohonen神经网络对输入数据进行聚类方法在卷烟配方中的应用 ,提出了从核心样本动态搜索 BP网络训练样本的新探索 ,摒弃了过去 BP算法中训练样本固定不变 ,互不相交的方法 ,实现了 BP网络和 Kohonen网络动态无缝集成。 相似文献
6.
K. Nagendra Prasad S. Triveni T. Schanz Late T. S. Nagaraj 《Marine Georesources & Geotechnology》2007,25(3):181-197
Despite the sophisticated methods employed to obtain high quality samples, they are prone to disturbance, due to stress release, let apart, due to sampling tools and techniques adopted. Critical reappraisal of different methods suggest that any method of sample quality assessment involving strength and deformation parameters would enable easier implementation and correct other engineering parameters for estimated sample disturbance. In this technical paper, sample disturbance index, using merely the slopes of compression paths, (representing mechanical response), in the pre- and post-yield stress regimes under odeometric loading conditions is proposed. This method is based on single oedometer test results on samples of unknown degrees of disturbance during sampling and handling. The unique feature of this approach is that the ideal rigid plastic material behavior is taken as reference. This eliminates the need for any additional experimental data or any calculations from the relationships formulated with any set of assumptions. 相似文献
7.
The seismic expression of a salt-filled channel which cuts across the Mid North Sea High in Quadrant 37 is described, with features interpreted as being produced by salt-edge dissolution forming both eastern and western margins of the channel. The apparent half-graben nature of the channel is shown to be only superficial, and due to complex faulting associated with, but not defining, its western margin. The shallower faulting here is a Mesozoic to early Tertiary growth fault related to local dissolution of Zechstein salt. The dissolution effect appears in turn to have been localized by the presence of a deeper fault that was already downthrown to the east in Zechstein times, when it seems to have limited the eastward progradation of Zechstein shelf carbonates and anhydrites, and had probably ceased to move significantly before the onset of the Late Cimmerian erosional phase. The origin of this arcuate fault is tentatively ascribed to subsidence around a granite batholith. Zechstein salt originally spread some distance to the east and west of the channel; it was dissolved from the edges inwards, mainly before the Late Cretaceous, giving rise to a thicker Mesozoic sequence on parts of the flanks of the channel than in the middle. Besides providing an interesting structural case history, the features described have implications regarding Zechstein sedimentation, reservoir potential, the tectonic history of the North Sea, and the nature of the Mid North Sea High itself. 相似文献
8.
离子色谱分析在黄土和粉尘研究中的应用 总被引:1,自引:0,他引:1
黄土中存在着大量的碱金属及碱土金属,以往的测试方法多为原子吸收和ICP—MS,离子色谱法在测试黄土样品的碱金属和碱土金属元素含量中应用不多。将黄土地质标准样品进行消解后用离子色谱进行测试,测试效果良好,重复测试的相对标准偏差小于5%,与推荐值的相对误差小于5%,准确度和精密度符舍相关的质量控制要求。本实验方法测试的离子含量都在仪器响应呈线性的最佳测试范围之内,标准曲线经回归后相关系数均达到0.9999。黄土样品的分析结果与粉尘气溶胶样品的离子分析结果对比表明,此方法对于探讨粉尘起源以及沙尘暴天气的研究具有重要意义。 相似文献
9.
天然气溶解过程中组分分馏模型及其应用 总被引:1,自引:0,他引:1
天然气不同组分在水中溶解度的差异,导致溶解相与残留游离相天然气组分组成不同,即发生组分的溶解分馏效应。溶解分馏效应在天然气水溶运移、溶解散失等过程中均有发生。揭示天然气组分的溶解分馏规律、建立定量分馏模型,有助于天然气气源对比和成藏过程示踪。以Henry定律为依据,对不同组分溶解特征分析,提出了溶解度分数的概念,并建立了溶解分馏模型。根据该模型和各组分的溶解度分数和天然气溶解量,可计算各组分的溶解分馏量,恢复天然气初始组成特征。计算表明,威远震旦系气藏初期的天然气组成为:CH4为72.70%,C2H6为0.09%,CO2为22.41%,N2为4.07%,干燥系数(C1/C1-5)为99.876%。溶解作用使天然气中CO2含量显著降低,烃类气体含量增加,而天然气干燥系数降低。结果有助于天然气成因判识和气源对比等。 相似文献
10.
DMS (dimethylsulfide), a breakdown product of cellular solutes of many species of macroalgae andphytoplankton plays an important role in regulating global climate and counteracting partly the "greenhouse" effect.In this paper, the advance and prospects of DMS study are reviewed and discussed with respectto DMS sample storage, measurement and importance in regulating global climate and the acidity ofrain and aerosol. 相似文献