八庙—青山金红石矿床化学成分与成矿关系

本矿床是我国金红石矿床重要的成因及工业类型，为具有特定化学成分的岩石在特定变质条件下形成的。本文通过对大量数据的处理，查明了化学成分与成矿的关系：高Ａｌ２Ｏ３、ＭｇＯ、Ｆｅ２Ｏ３＋ＦｅＯ、Ｋ２Ｏ、Ｐ２Ｏ５、Ｈ２Ｏ＋、ＭｎＯ，低ＳｉＯ２、ＣａＯ、Ｎａ２Ｏ、ＣＯ２、Ｓ等，利于钛富集；高ＴｉＯ２、ＭｇＯ、Ｐ２Ｏ５、Ｓ，低ＳｉＯ２、ＣａＯ、Ｋ２Ｏ、Ａｌ２Ｏ３、Ｆｅ２Ｏ３／ＦｅＯ，利于金红石形成；高Ｓｃ、Ｚｒ、Ｎｉ、Ｚｎ及Ｌａ／Ｙｂ，低Ｙ、Ｎｂ、Ｔｈ、Ｃｄ、Ｂａ、Ｂｅ、ΣＲＥＥ，利于金红石纯度提高。对研究矿床成因及寻找新的同类矿床等有重要意义     

天然含钒金红石加热、淬火及电子辐射改性实验研究

天然含钒金红石样品经过1273K加热、淬火和高能电子辐照处理后性质发生不同程度的变化。XRD谱峰显示处理前后样品没有发生物相变化，显微IR图谱证明原样、加热、淬火样品的表面有少量吸附水存在，而辐射样品的显微IR图谱上没有检测到吸附水的吸收峰。用XPS分析比较了处理前后样品表面主要元素Ti、O和V的价态及含量，结果表明，原样经过处理后表面钒和氧的原子百分含量增加，其中淬火样品表面吸附水和钒的含量相对于原样增加最为明显，光催化活性相应较高；加热样品表面的吸附水和钒的含量比原样稍有增加，光催化活性与原样相当；电子辐射样品表面钒的原子百分含量相对原样增加不明显，而对水的吸附能力相对原样较低，光催化效率也略低。     

中国金红石矿床成矿地质条件及成矿远景

中国金红石矿床成因类型不一,控矿因素各异。通过对地层、构造(包括大地构造环境及褶皱)等控矿因素,区域变质作用、岩浆作用、热液作用、风化及沉积作用等成矿地质条件及矿床分布等规律的归纳与研究,提出了陕西石泉-镇坪、陕西丹凤-西峡、河南南召-方城、湖北枣阳-河南新县、湖北英山-潜山、江苏徐州-东海、山东栖霞-荣城、山西代县-河北涞水、四川会东9个金红石成矿远景区。并圈定出山东省荣城曲家、安徽凤阳板桥、湖北郧西土门—涧池、湖北七里坪大悟仙山、山西代县义成沟—羊廷寺、河北涞源司各庄、河北丰宁黄土梁等7个找矿靶区。     

Nb–Ta fractionation induced by fluid‐rock interaction in subduction‐zones: constraints from UHP eclogite‐ and vein‐hosted rutile from the Dabie orogen,Central‐Eastern China

Niobium and Ta concentrations in ultrahigh‐pressure (UHP) eclogites and rutile from these eclogites and associated high pressure (HP) veins were used to study the behaviour of Nb–Ta during dehydration and fluid‐rock interaction. Samples were collected through a ～2 km profile at the Bixiling complex in the Dabie orogenic belt, Central‐Eastern China. All but one eclogite away from veins (EAVs) display nearly constant Nb/Ta ratios ranging from 16.1 to 19.2, with an average of 16.9 ± 0.8 (2 SE), similar to that of their gabbroic protolith from the Yangtze Block. Nb/Ta ratios of rutile from the EAVs range from 12.7 to 25.3 among different individual grains, with the average values close to those of the corresponding bulk rocks. These observations show that Nb and Ta were not significantly fractionated by prograde metamorphism up to eclogite facies when no significant fluid‐rock interaction occurs. In contrast, Nb/Ta ratios of rutile from eclogites close to veins (ECVs) are highly variable from 17.8 to 49.8, which are systematically higher (by up to 17) than those of rutile from the veins. These observations demonstrate that Nb and Ta were mobilized and fractionated during localized fluid flow and intensive fluid‐rock interaction. This is strongly supported by Nb/Ta zoning patterns in single rutile grains revealed by in situ LA‐ICP‐MS analysis. Ratios of Nb/Ta in the ECV‐hosted rutile decrease gradually from cores towards rims, whereas those in the EAV‐hosted rutile are nearly invariable. Furthermore, the vein rutile shows Nb/Ta zoning patterns that are complementary to those in rutile from their immediate hosts (ECVs), suggesting an internal origin for the vein‐forming fluids. The Nb/Ta ratios of such fluids evolved from low values at the early stage of subduction to higher values at later supercritical conditions with increased temperature and pressure. Quantitative modelling was conducted to constrain the compositional evolution of metamorphic fluids during dehydration and fluid‐rock interaction focusing on Nb–Ta distribution. The modelling results based on our proposed multistage fluid phase evolution path can essentially reproduce the natural observations reported in the present study.     

苏北榴辉岩的岩石性质及其金红石的嵌布特征

苏北榴辉岩主要产于由角闪岩相变质的长英质片麻岩，根据其赋存部位划分为3类：Ⅰ类榴辉岩，通常形成独立块体，有时夹薄层片麻岩、片岩，岩石呈块状、条带状、斑杂状、条纹状和片麻状等；Ⅱ类榴辉岩，与超基性岩相伴，矿石主要呈块状和斑杂状；Ⅲ类榴辉岩，与大理岩整合接触，岩石呈块状、片麻状。3类榴辉岩在变晶矿物组合中具有一定的差异。面积测量法统计结果表明：Ⅰ类榴辉岩的晶间金红石占12．49%，间粒金红石占85．69％，包体金红石占1．81％；Ⅱ类榴辉岩的晶间金红石占36．40％，间粒金红石占44．17%，包体金红石占19．43％．Ⅲ类榴辉岩的晶间余红石占27．49％．间粒会红石占53．43%，包体金红石占19．09％。     

On the origin of oriented rutile needles in garnet from UHP eclogites

Although oriented rutile needles in garnet have been reported from several ultrahigh‐pressure (UHP) rocks and considered to be important UHP indicators, their crystallographic features including growth habit and lattice correspondences with garnet host have never been properly characterized. This paper presents a detailed analytical electron microscopic (AEM) study on evenly distributed oriented rutile needles in garnet of two eclogitic rocks from Sulu. Some garnet in one UHP diamondiferous quartzofeldspathic rock from the Saxonian Erzgebirge, and in one high‐pressure (HP) felsic granulite from Bohemia also contain a few unevenly distributed oriented rutile needles. They have also been studied for the purpose of comparison. Despite different distribution patterns, AEM revealed that all rutile needles are oriented along the 〈111〉 directions of garnet with their lateral sides surrounded by the {110} planes of garnet, and that the growth directions of most needles are close to the normal of the {101} planes of rutile. No other specific crystallographic orientation relationships between rutile and garnet host were observed, and there is no pyroxene associated with rutile, as necessitated by the precipitation reaction of rutile in garnet as previously proposed. A simple solid‐state precipitation scenario for the formation of the rutile needles in garnet in these two eclogitic rocks is not justified. Three alternative mechanisms are considered for the formation of oriented rutile needles: (i) the rutile needles may be inherited from precursor minerals; (ii) the rutile needles may be formed by a dissolution–reprecipitation mechanism; and (iii) the rutile needles may be formed by cleaving and healing of garnet with rutile deposition. None of these mechanisms can fully explain the observations, although the first one is less likely and the third one is preferred. This study presents an example where the presence of oriented/aligned inclusions in minerals does not necessarily imply a precipitation origin.     

Rutile to Titanite Transformation in Eclogites and its Geochemical Consequences: An Example from the Sumdo Eclogite, Tibet

The formation of titanite coronae after rutile is common in retrograde high-to ultrahigh-pressure meta-mafic rocks, which provides a good opportunity to address the geochemical behavior of HFSE in crustal environments. In the Sumdo eclogite, titanite occurs either as a corona around rutile grains or as semi-continuous veins cross-cutting the major foliation, whereas rutile grains occur either as inclusions in garnet or omphacite or as a relict core surrounded by titanite. Textural relationships ...     

Rutile inclusions in garnet from a dissolution‐reprecipitation mechanism

Metamorphic garnet commonly contains needle‐like rutile inclusions as well as equant rutile inclusions that surround quartz inclusions and range in size from submicrometer to nanometer. Although the origin of these equant rutile inclusions, that is, exsolution or non‐exsolution, has important implications for petrological and tectonic processes, the crystallographic characteristics of these inclusions have rarely been studied because of the small sizes and analytical difficulties involved. Here, we report the crystallographic characteristics pertinent to the genetic origin of minute equant rutile inclusions in cloudy, nearly spherically shaped garnet domains with Ti‐depleted compositions surrounding quartz inclusions in ultrahigh‐pressure garnet from several diamondiferous Erzgebirge quartzofeldspathic gneissic rock samples. TEM analyses show that the equant rutile crystals in cloudy garnet domains are partially bounded by the low‐energy {100}_rt ± {110}_rt ± {101}_rt facets and have rather random crystallographic orientation relationships (CORs) with the garnet host, with preferential alignment of low‐energy lattice planes, for example, {100}_rt//{112}_grt, for some rutile crystals. Although the rather random CORs are unlikely to be attributed to solid‐state exsolution subjected to the stringent topotactic garnet lattice constraints, the characteristic subhedral {100}_rt ± {110}_rt ± {101}_rt crystal forms of rutile can be rationalized by a metasomatic dissolution‐reprecipitation mechanism via a fluid phase. In this scenario, the quartz+fluid inclusions in garnet were first subjected to decompression microcracking during rock exhumation, followed by dissolution of Ti‐bearing garnet matrix at the crack tips or along the crack surfaces and subsequent reprecipitation of rutile, apatite, gahnite, akdalaite, and Ti‐depleted garnet. The rapid coalescence between rutile and garnet crystals in fluid or direct attachment of rutile crystals onto the dissolving crack surfaces would then yield the rather random CORs as reported here. These results, along with previous work on rutile needles, indicate rather diverse genesis of rutile inclusions in various crystal forms, thus shedding light on the controversial exsolution origin for other inclusion suite/microstructure in minerals.     

藏南色如朗金红石矿床地质特征及控矿条件

藏南色如朗金红石矿床位于米拉山口断裂带东段北缘,矿床的赋矿岩石主要为绿片岩。由北向南圈定了3个矿体,矿体沿北东方向延伸,呈层状、似层状产出。矿石矿物以金红石为主,其他金属矿物有磁铁矿、赤铁矿、黄铁矿、黄铜矿、磁黄铁矿等。金红石主要为红褐色,少数为暗红褐色,呈自形-半自形柱状和他形粒状,粒径多为0.01~0.2mm,大者可达1~2mm。该矿床的形成主要受地层和变质作用控制,后期构造对矿床形态有一定的破坏作用。通过与中国典型金红石矿床地质特征对比,初步认为色如朗金红石矿床的成因类型为中低压变质型。     

热处理天然金红石的微结构研究

利用粉晶X射线衍射(XRD)、透射电镜(TEM)等分析手段对在氩气气氛中加热、退火的天然金红石样品的微结构进行了研究.研究表明样品在热处理后,晶格发生膨胀,并且在900 ℃和1000 ℃的样品中出现了钛铁矿物相.钛铁矿也是一种天然半导体矿物,沿与金红石(010)面网成大约31°夹角的方向生长,与金红石形成了二元复合半导体.紫外漫反射实验结果表明热处理后,金红石中出现的钛铁矿相有效地促进了光催化效果.