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1.
This study examines the depletion of ferromagnesian silicate minerals from a sequence of thin, distal, mainly rhyolitic tephra layers of Holocene age preserved in an acid peat bog (Kopouatai), North Island, New Zealand. The rate of such depletion has been fast, as indicated by the complete loss of biotite from one tephra layer (Kaharoa Tephra), in which it is normally dominant, in only ca. 770 yr. Chemical dissolution is advocated as the likely cause for the depletion, with amphiboles and other mineral grains commonly showing etch pits, microcaves, and other characteristic surface solution features. Theoretical thermodynamic and kinetic models show a marked increase in the rate of dissolution of all ferromagnesian minerals under conditions of low pH (< 4), but that where silica concentrations in solution are high the relative proportions of minerals remaining are unaffected. However, where concentrations of dissolved silica are low, as in most bog environments, the relative proportions of ferromagnesian minerals are affected as well as absolute amounts being decreased. Amphiboles are depleted relative to pyroxenes, consistent with kinetic studies. The results show that the identification and correlation of tephras on the basis of relative abundances of ferromagnesian minerals alone may be unreliable, and emphasise the need to use multiple criteria in such studies. 相似文献
2.
Summary Left in place pillars of abandoned mines are subject to weathering (e.g action of water, bacteria) that degrades their mechanical
strength and eventually leads to collapse. A simple weathering model is proposed, that is governed by two parameters: the
rate of progression of weathered front and the rate of degradation of the compressive strength with time. Both plane strain
and axisymmetric analyses are performed and closed form solutions of the variation with time of the bearing capacity of the
pillar are given. Experimental data of the tests conducted on gypsum and anhydrite specimens attacked by water are presented.
It is shown that in order to fit the experimental data a third parameter must be introduced. New closed form solutions are
given and the data are used for estimating the time to failure of abandoned gypsum mines in Northern Italy.
Authors’ address: Dr. Riccardo Castellanza, Research Assistant, Department of Structural Engineering, Milan University of
Technology (Politecnico), Piazza Leonardo da Vinci 32, 20133 Milan, Italy 相似文献
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In an assessment of the influence of internal rock moisture content on Schmidt hammer readings, rebound (R) values are found to decrease with increasing moisture content. For samples of basalt, sandstone and dolerite the maximum decrease in R‐values is found between oven dry values and saturated rock rebound values, the magnitude of which varies from 2 to 10 points on the R‐scale. A quartzite block has the greatest decline of 6 points at 60 per cent saturation. For certain rock types under differing site‐to‐site field moisture conditions the moisture effect can be a significant factor in the interpretation of the relative state of weathering from rebound values. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
7.
大兴安岭阿龙山地区流纹岩风化的地球化学特征 总被引:5,自引:1,他引:5
通过大兴安岭地区两个流纹岩风化剖面的研究发现,大兴安岭地区的岩石风化过程具有特殊性。风化过程分为两个阶段,即以化学风化为主导的基质风化阶段和以机械风化为主导的斑晶风化阶段,第二阶段显示出与正常风化剖面相反的风化趋势。低温和长冬使第二风化阶段延长,并呈现逆风化趋势。风化过程中Fe和Al始终处于流失状态。上述特征的产生是由原岩的结构及成分、气候因素和生态系统等多种因素作用的结果。 相似文献
8.
Pre-weighed blocks of a Jurassic Limestone were exposed on the ground surface in the coastal Namib Desert for a period of 2 years. The environment is both salty and foggy. Some of the blocks suffered extensive disintegration, and laboratory analyses (including geochemistry, XRD and SEM) indicate that the weathered samples have a high halite (sodium chloride) content. Cycles of wetting and drying associated with the frequent fog events of the area cause cycles of halite crystallization. Rocks exposed at the surface absorb salts from the surrounding desert surface and then disintegrate, contributing to planation of the landscape. 相似文献
9.
南宁、百色盆地红土风化壳的地球化学特征及其环境意义* 总被引:4,自引:0,他引:4
本文以广西南宁盆地那桐风化壳,及百色盆地江泽风地壳的大量土体化学分析数据为依据,进行了第四纪红土的确认、形成、分布和土壤肥力状况。以及通过地球化学强度、硅铁系数、硅铝系数等指标进行了两风化壳的对比研究。同时,还探讨了风化壳的发育过程及其与环境的关系。 相似文献
10.
系统研究了Ge-ARS-H2C2O4-V体系报道极谱催化波的影响因素,测定了Ge-ARS-H2C2O4三元配合物的配合比为1:2:1。实验初步证明了该体系催化波为具有吸附性质的平行催化波。本法检出限为0.14mg.mL^-1,相对标准偏差小于9.89%,标准回收率为93.70%-109.0%,0-50mg.mL^-1的锗具有良好的线性关系。 相似文献