全文获取类型
收费全文 | 631篇 |
免费 | 77篇 |
国内免费 | 239篇 |
专业分类
测绘学 | 4篇 |
大气科学 | 60篇 |
地球物理 | 60篇 |
地质学 | 677篇 |
海洋学 | 90篇 |
天文学 | 11篇 |
综合类 | 27篇 |
自然地理 | 18篇 |
出版年
2024年 | 1篇 |
2023年 | 7篇 |
2022年 | 17篇 |
2021年 | 11篇 |
2020年 | 15篇 |
2019年 | 20篇 |
2018年 | 17篇 |
2017年 | 14篇 |
2016年 | 23篇 |
2015年 | 20篇 |
2014年 | 37篇 |
2013年 | 33篇 |
2012年 | 31篇 |
2011年 | 32篇 |
2010年 | 27篇 |
2009年 | 49篇 |
2008年 | 44篇 |
2007年 | 53篇 |
2006年 | 51篇 |
2005年 | 42篇 |
2004年 | 35篇 |
2003年 | 27篇 |
2002年 | 34篇 |
2001年 | 29篇 |
2000年 | 27篇 |
1999年 | 42篇 |
1998年 | 24篇 |
1997年 | 25篇 |
1996年 | 34篇 |
1995年 | 25篇 |
1994年 | 27篇 |
1993年 | 17篇 |
1992年 | 13篇 |
1991年 | 10篇 |
1990年 | 8篇 |
1989年 | 9篇 |
1988年 | 4篇 |
1987年 | 2篇 |
1986年 | 6篇 |
1985年 | 1篇 |
1984年 | 2篇 |
1983年 | 1篇 |
1981年 | 1篇 |
排序方式: 共有947条查询结果,搜索用时 15 毫秒
1.
Quartz‐rich veins in metapelitic schists of the Sanandaj‐Sirjan belt, Hamadan region, Iran, commonly contain two Al2SiO5 polymorphs, and, more rarely, three coexisting Al2SiO5 polymorphs. In most andalusite and sillimanite schists, the types of polymorphs in veins correlate with Al2SiO5 polymorph(s) in the host rocks, although vein polymorphs are texturally and compositionally distinct from those in adjacent host rocks; e.g. vein andalusite is enriched in Fe2O3 relative to host rock andalusite. Low‐grade rocks contain andalusite + quartz veins, medium‐grade rocks contain andalusite + sillimanite + quartz ± plagioclase veins, and high‐grade rocks contain sillimanite + quartz + plagioclase veins/leucosomes. Although most andalusite and sillimanite‐bearing veins occur in host rocks that also contain Al2SiO5, kyanite‐quartz veins crosscut rocks that lack Al2SiO5 (e.g. staurolite schist, granite). A quartz vein containing andalusite + kyanite + sillimanite + staurolite + muscovite occurs in andalusite–sillimanite host rocks. Textural relationships in this vein indicate the crystallization sequence andalusite to kyanite to sillimanite. This crystallization sequence conflicts with the observation that kyanite‐quartz veins post‐date andalusite–sillimanite veins and at least one intrusive phase of a granite that produced a low‐pressure–high‐temperature contact aureole; these relationships imply a sequence of andalusite to sillimanite to kyanite. Varying crystallization sequences for rocks in a largely coherent metamorphic belt can be explained by P–T paths of different rocks passing near (slightly above, slightly below) the Al2SiO5 triple point, and by overprinting of multiple metamorphic events in a terrane that evolved from a continental arc to a collisional orogen. 相似文献
2.
This study explores garnet coronas around hedenbergite, which were formed by the reaction plagioclase + hedenbergite→garnet + quartz, to derive information about diffusion paths that allowed for material redistribution during reaction progress. Whereas quartz forms disconnected single grains along the garnet/hedenbergite boundaries, garnet forms ~20‐μm‐wide continuous polycrystalline rims along former plagioclase/hedenbergite phase boundaries. Individual garnet crystals are separated by low‐angle grain boundaries, which commonly form a direct link between the reaction interfaces of the plagioclase|garnet|hedenbergite succession. Compositional variations in garnet involve: (i) an overall asymmetric compositional zoning in Ca, Fe2+, Fe3+ and Al across the garnet layer; and (ii) micron‐scale compositional variations in the near‐grain boundary regions and along plagioclase/garnet phase boundaries. These compositional variations formed during garnet rim growth. Thereby, transfer of the chemical components occurred by a combination of fast‐path diffusion along grain boundaries within the garnet rim, slow diffusion through the interior of the garnet grains, and by fast diffusion along the garnet/plagioclase and the garnet/hedenbergite phase boundaries. Numerical simulation indicates that diffusion of Ca, Al and Fe2+ occurred about three to four, four and six to seven orders of magnitude faster along the grain boundaries than through the interior of the garnet grains. Fast‐path diffusion along grain boundaries contributed substantially to the bulk material transfer across the growing garnet rim. Despite the contribution of fast‐path diffusion, bulk diffusion through the garnet rim was too slow to allow for chemical equilibration of the phases involved in garnet rim formation even on a micrometre scale. Based on published garnet volume diffusion data the growth interval of a 20‐μm‐wide garnet rim is estimated at ~103–104 years at the inferred reaction conditions of 760 ± 50 °C at 7.6 kbar. Using the same parameterization of the growth law, 100‐μm‐ and 1‐mm‐thick garnet rims would grow within 105–106 and 106–107 years respectively. 相似文献
3.
江西省武功山地区浒坑钨矿床的Re-Os年龄及其地质意义 总被引:2,自引:0,他引:2
浒坑钨矿床是位于江西省中部武功山成矿带的大型石英脉型黑钨矿床。为了确定该矿床的成矿时代,笔者选取了浒坑含钨石英脉中与黑钨矿共生的辉钼矿进行了高精度Re-Os同位素定年,并获得5个辉钼矿样品的Re-Os等时线年龄和模式加权平均年龄分别为150.2±2.2Ma和149.82±0.92Ma。测年数据表明浒坑钨矿床的成矿时代为150Ma左右,是华南地区中生代大规模成岩成矿作用高峰期的产物。辉钼矿含铼较低,表明成矿物质可能来自壳源,与形成浒坑花岗岩体的燕山期重熔S型花岗岩岩浆活动有关。该矿床形成于燕山期岩石圈伸展减薄环境。 相似文献
4.
Mauro Lo Cascio Yan Liang Nobumichi Shimizu Paul C. Hess 《Contributions to Mineralogy and Petrology》2008,156(1):87-102
The grain-scale processes of peridotite melting were examined at 1,340°C and 1.5 GPa using reaction couples formed by juxtaposing
pre-synthesized clinopyroxenite against pre-synthesized orthopyroxenite or harzburgite in graphite and platinum-lined molybdenum
capsules. Reaction between the clinopyroxene and orthopyroxene-rich aggregates produces a melt-enriched, orthopyroxene-free,
olivine + clinopyroxene reactive boundary layer. Major and trace element abundance in clinopyroxene vary systematically across
the reactive boundary layer with compositional trends similar to the published clinopyroxene core-to-rim compositional variations
in the bulk lherzolite partial melting studies conducted at similar P–T conditions. The growth of the reactive boundary layer takes place at the expense of the orthopyroxenite or harzburgite and
is consistent with grain-scale processes that involve dissolution, precipitation, reprecipitation, and diffusive exchange
between the interstitial melt and surrounding crystals. An important consequence of dissolution–reprecipitation during crystal-melt
interaction is the dramatic decrease in diffusive reequilibration time between coexisting minerals and melt. This effect is
especially important for high charged, slow diffusing cations during peridotite melting and melt-rock reaction. Apparent clinopyroxene-melt
partition coefficients for REE, Sr, Y, Ti, and Zr, measured from reprecipitated clinopyroxene and coexisting melt in the reactive
boundary layer, approach their equilibrium values reported in the literature. Disequilibrium melting models based on volume
diffusion in solid limited mechanism are likely to significantly underestimate the rates at which major and trace elements
in residual minerals reequilibrate with their surrounding melt.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
5.
D. J. Cherniak 《Physics and Chemistry of Minerals》2008,35(4):179-187
Self-diffusion of Si under anhydrous conditions at 1 atm has been measured in natural zircon. The source of diffusant for
experiments was a mixture of ZrO2 and 30Si-enriched SiO2 in 1:1 molar proportions; experiments were run in crimped Pt capsules in 1-atm furnaces. 30Si profiles were measured with both Rutherford backscattering spectrometry (RBS) and nuclear reaction analysis with the resonant
nuclear reaction 30Si(p,γ)31P. For Si diffusion normal to c over the temperature range 1,350–1,550°C, we obtain an Arrhenius relation D = 5.8 exp(−702 ± 54 kJ mol−1/RT) m2 s−1 for the NRA measurements, which agrees within uncertainty with an Arrhenius relation determined from the RBS measurements
[62 exp(−738 ± 61 kJ mol−1/RT) m2 s−1]. Diffusion of Si parallel to c appears slightly faster, but agrees within experimental uncertainty at most temperatures
with diffusivities for Si normal to c. Diffusion of Si in zircon is similar to that of Ti, but about an order of magnitude faster than diffusion of Hf and two
orders of magnitude faster than diffusion of U and Th. Si diffusion is, however, many orders of magnitude slower than oxygen
diffusion under both dry and hydrothermal conditions, with the difference increasing with decreasing temperature because of
the larger activation energy for Si diffusion. If we consider Hf as a proxy for Zr, given its similar charge and size, we
can rank the diffusivities of the major constituents in zircon as follows: D
Zr < D
Si << D
O, dry < D
O, ‘wet’. 相似文献
6.
7.
本文以~3H—TdR掺入法观察911对小鼠脾淋巴细胞增殖反应的影响并用CTLL细胞检测了其对IL—2的作用。体外实验结果表明,911对小鼠脾淋巴细胞增殖反应有明显的增强作用,以0.5μg/ml的浓度效果最为明显,相对增殖指数RPI可达200%;体内实验则以5mg/kg体重ip,连续7d效果最好,相对增殖指数RPI可达176%;911用药组小鼠IL—2的产生量均高于对照组,以5mg/kg和10mg/kg效果最好。以上实验证明,这一多糖是一种有希望的新免疫调节药物。 相似文献
8.
尼罗罗非鱼对不同颜色定置网片的反应特性 总被引:6,自引:0,他引:6
本文初步研究了尼罗罗非鱼对红、黄、绿、蓝、青灰色定置网片反应特性,并探讨了该鱼对青灰色网片的适应特性。结果表明:绿色网片对罗非鱼的阻拦作用最大,青灰色网片次之,红、黄色网片再次,蓝色网片最小。罗非鱼对青灰色网片具明显的适应现象,它们完成整个适应过程所需的实验重复次数约为7次。 相似文献
9.
Supergene nickel deposits of New Caledonia that have been formed in the Neogene by weathering of obducted ultramafic rocks are controlled by fracture development. The relationship of tropical weathering and tectonic structures, faults and tension gashes, have been investigated in order to determine whether fractures play a passive role only, as previously thought; or alternatively, if brittle tectonics was acting together with alteration. Observation of time‐relationship, textures, and mineralogy of various fracture fills and fault gouges shows that active faulting has played a prominent role not only in facilitating drainage and providing room for synkinematic crystallization of supergene nickel silicate, but also in mobilizing already formed sparse nickel ore, producing the very high grade ore nicknamed “green gold”. 相似文献
10.
通过对取自MBR膜生物反应器中的活性污泥加入菲进行富集培养、驯化,分离、纯化出一株能以菲为唯一碳源和能源的短杆状革兰氏阴性菌J-1,细菌长2~5μm,宽1~3μm;研究了初始底物浓度、温度、pH对菌株J-1降解菲的影响,探讨了菌株J-1胞内酶对菲降解的底物抑制动力学。试验表明:菌株J-1在48h内能将不同浓度菲的水溶液中的菲完全降解;菲浓度增加,达到完全降解的时间延长。温度对细菌的降解能力影响较大,菌株J-1对菲降解的最佳温度为28℃。1.15mg·L-1的菲,28℃时48h内能完全降解,而相同时间内10℃时的降解率仅为36.65%。菌株J-1对pH的波动具有一定的适应性,pH在一定范围内(6.0~8.4)变化对菲降解的影响不大,降解反应的最佳pH为7.2。菌株J-1对菲的降解符合一级动力学反应方程。较高的底物浓度对酶促降解反应具有抑制作用,酶促反应的最大速率常数vm=1.17mg·L-1·h-1,米氏常数Km=61.70mg·L-1;底物抑制常数kS=49.60mg·L-1;最佳底物浓度[S]opt=55.32mg·L-1。 相似文献