One zone modeling of irregular variability of stellar convective envelope

One zone modeling of the irregular variability of red super-giants is intended with regard to the nonlinear coupling of finite amplitude pulsation with convection. The nonlocal mixing length is employed for the evaluation of the convective flux, the turbulent pressure and the turbulent power of temperature fluctuations. The radial pulsation and the Boussinesq convection are assumed for simplicity. The one zone is defined as the layer having the entropy maximum and the minimum at the bottom and at the top, respectively. The quasi-adiabatic approximation is consistent with this definition in fixing the zone to the same mass range. The spatial derivatives are evaluated under the assumption of homologous changes with the equilibrium homologous parameters. Then, a set of 6 simultaneous first order nonlinear ordinary differential equations are obtained as the one zone representation of the irregular variability of the convective envelope.     

岩体三维节点偶对分析及其应用

本文讨论了节点偶对分析的三维扩展。节点偶对分析是针对摩擦滑动节理单元的约束边界进行的序列矢量判定。在三维节理单元的分析中,几何约束和相应的力学判据极为复杂,采用节点偶对等效结合力方法才能迎刃而解。文中对三维转向节理模型的分析得到合理的结果,它表明本文所提出的方法可成功地应用于节理岩体的有限元分析。     

Asymmetrically zoned reaction rims: assessment of grain boundary diffusivities and growth rates related to natural diffusion-controlled mineral reactions

This study explores garnet coronas around hedenbergite, which were formed by the reaction plagioclase + hedenbergite→garnet + quartz, to derive information about diffusion paths that allowed for material redistribution during reaction progress. Whereas quartz forms disconnected single grains along the garnet/hedenbergite boundaries, garnet forms ～20‐μm‐wide continuous polycrystalline rims along former plagioclase/hedenbergite phase boundaries. Individual garnet crystals are separated by low‐angle grain boundaries, which commonly form a direct link between the reaction interfaces of the plagioclase|garnet|hedenbergite succession. Compositional variations in garnet involve: (i) an overall asymmetric compositional zoning in Ca, Fe²⁺, Fe³⁺ and Al across the garnet layer; and (ii) micron‐scale compositional variations in the near‐grain boundary regions and along plagioclase/garnet phase boundaries. These compositional variations formed during garnet rim growth. Thereby, transfer of the chemical components occurred by a combination of fast‐path diffusion along grain boundaries within the garnet rim, slow diffusion through the interior of the garnet grains, and by fast diffusion along the garnet/plagioclase and the garnet/hedenbergite phase boundaries. Numerical simulation indicates that diffusion of Ca, Al and Fe²⁺ occurred about three to four, four and six to seven orders of magnitude faster along the grain boundaries than through the interior of the garnet grains. Fast‐path diffusion along grain boundaries contributed substantially to the bulk material transfer across the growing garnet rim. Despite the contribution of fast‐path diffusion, bulk diffusion through the garnet rim was too slow to allow for chemical equilibration of the phases involved in garnet rim formation even on a micrometre scale. Based on published garnet volume diffusion data the growth interval of a 20‐μm‐wide garnet rim is estimated at ～10³–10⁴ years at the inferred reaction conditions of 760 ± 50 °C at 7.6 kbar. Using the same parameterization of the growth law, 100‐μm‐ and 1‐mm‐thick garnet rims would grow within 10⁵–10⁶ and 10⁶–10⁷ years respectively.     

An experimental study of the grain-scale processes of peridotite melting: implications for major and trace element distribution during equilibrium and disequilibrium melting

The grain-scale processes of peridotite melting were examined at 1,340°C and 1.5 GPa using reaction couples formed by juxtaposing pre-synthesized clinopyroxenite against pre-synthesized orthopyroxenite or harzburgite in graphite and platinum-lined molybdenum capsules. Reaction between the clinopyroxene and orthopyroxene-rich aggregates produces a melt-enriched, orthopyroxene-free, olivine + clinopyroxene reactive boundary layer. Major and trace element abundance in clinopyroxene vary systematically across the reactive boundary layer with compositional trends similar to the published clinopyroxene core-to-rim compositional variations in the bulk lherzolite partial melting studies conducted at similar P–T conditions. The growth of the reactive boundary layer takes place at the expense of the orthopyroxenite or harzburgite and is consistent with grain-scale processes that involve dissolution, precipitation, reprecipitation, and diffusive exchange between the interstitial melt and surrounding crystals. An important consequence of dissolution–reprecipitation during crystal-melt interaction is the dramatic decrease in diffusive reequilibration time between coexisting minerals and melt. This effect is especially important for high charged, slow diffusing cations during peridotite melting and melt-rock reaction. Apparent clinopyroxene-melt partition coefficients for REE, Sr, Y, Ti, and Zr, measured from reprecipitated clinopyroxene and coexisting melt in the reactive boundary layer, approach their equilibrium values reported in the literature. Disequilibrium melting models based on volume diffusion in solid limited mechanism are likely to significantly underestimate the rates at which major and trace elements in residual minerals reequilibrate with their surrounding melt. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Si diffusion in zircon

Self-diffusion of Si under anhydrous conditions at 1 atm has been measured in natural zircon. The source of diffusant for experiments was a mixture of ZrO₂ and ³⁰Si-enriched SiO₂ in 1:1 molar proportions; experiments were run in crimped Pt capsules in 1-atm furnaces. ³⁰Si profiles were measured with both Rutherford backscattering spectrometry (RBS) and nuclear reaction analysis with the resonant nuclear reaction ³⁰Si(p,γ)³¹P. For Si diffusion normal to c over the temperature range 1,350–1,550°C, we obtain an Arrhenius relation D = 5.8 exp(−702 ± 54 kJ mol⁻¹/RT) m² s⁻¹ for the NRA measurements, which agrees within uncertainty with an Arrhenius relation determined from the RBS measurements [62 exp(−738 ± 61 kJ mol⁻¹/RT) m² s⁻¹]. Diffusion of Si parallel to c appears slightly faster, but agrees within experimental uncertainty at most temperatures with diffusivities for Si normal to c. Diffusion of Si in zircon is similar to that of Ti, but about an order of magnitude faster than diffusion of Hf and two orders of magnitude faster than diffusion of U and Th. Si diffusion is, however, many orders of magnitude slower than oxygen diffusion under both dry and hydrothermal conditions, with the difference increasing with decreasing temperature because of the larger activation energy for Si diffusion. If we consider Hf as a proxy for Zr, given its similar charge and size, we can rank the diffusivities of the major constituents in zircon as follows: D _Zr < D _Si << D _{O, dry} < D _{O, ‘wet’}.     

塔里木西部地区古生代断裂活动的方式和机制

基于系统的地震剖面解释及其与塔中地区的对比,本文探讨了塔里木西部地区古生代断裂活动的方式和机制。玛东断裂带是一条宽阔的北东向盖层滑脱型褶皱冲断带,前展式向东南扩展,冲断作用发生在奥陶纪末。巴东断裂(吐土休克Ⅱ号断裂)为北西向基底卷入型冲断带,奥陶纪末和中二叠世末发生冲断。巴西断裂和塔参2井南断裂是海西期的正断层。塔里木古板块古生代的发育受邻侧的造山带演化制约,近东西向和北东向断裂奥陶纪末的冲断是继承基底构造发育的。塔中地区的近北西向断裂是晚寒武世的新生断裂,加里东运动可分为两幕:奥陶纪末的冲断(艾比湖运动)和晚志留-中泥盆世的冲断-走滑,后者向西明显减弱。塔里木西部的部分北西向断裂(如康西断裂)可归入塔中北西向断裂系。北东向的玛东断裂带是其西的向北(东)冲断的吐木休克断裂带与其东的向南偏东冲断的塔中8-1井——塔中5井断裂带之间的调节断层。     

钱二块铀矿床采铀注液结垢趋势的理论分析与预测

用离子系数矩阵法对钱二块铀矿床地浸采铀试验注液中存在的独立离子反应进行了确定,由溶度积规则及反应平衡原理,借助Matlab编程,估算出了钱二块铀矿床地浸采铀试验注液可能会生成的沉淀物种类及数量,为防治结垢提供了一定的理论依据.     

海藻硫酸多糖911对小鼠脾淋巴细胞增殖反应及对细胞产生IL—2作用的影响

本文以~3H—TdR掺入法观察911对小鼠脾淋巴细胞增殖反应的影响并用CTLL细胞检测了其对IL—2的作用。体外实验结果表明,911对小鼠脾淋巴细胞增殖反应有明显的增强作用,以0.5μg/ml的浓度效果最为明显,相对增殖指数RPI可达200％;体内实验则以5mg/kg体重ip,连续7d效果最好,相对增殖指数RPI可达176％;911用药组小鼠IL—2的产生量均高于对照组,以5mg/kg和10mg/kg效果最好。以上实验证明,这一多糖是一种有希望的新免疫调节药物。     

A novel technique in analyzing non-linear wave-wave interaction

During wave growth non-linear wave–wave interactions cause transfer of some wave energy from lower to higher wave periods as the spectrum grows. Wavelet bicoherence, which is a new technique in the analysis of wind–wave and wave–wave interactions, is used to analyze non-linear wave–wave interactions. A selected record of wind wave that contains the maximum wave height observed during 6 h of wave generation is divided into five segments and wavelet bicoherence is computed for the whole record, and for all divided segments. The study shows that the non-linear wave–wave interaction occurs at different bicoherence levels and these levels are different from one segment to another due to the non-stationarity feature of the examined data set.     

Variability in oceanographic and ecological processes in the Canadian Arctic Archipelago

This paper brings together unpublished historical data sets and published literature to review the role of climatic, oceanographic and ecological processes in the marine ecosystem of the eastern Canadian Archipelago. Physical data include characteristics of the water masses, circulation patterns, sea ice conditions, and climatic records from 1950s onward. Biological data include unpublished data sets on nutrients, primary and secondary production, and sedimentation, which were collected during the 1980–1990s in the eastern Canadian Archipelago. These results show high year-to-year variability in nutrient inventories and ratios, the magnitude of the ice algae and phytoplankton bloom, the timing of ice algae sedimentation in the spring, and the composition of the zooplankton community. The significance of this high interannual variability and its effect on pelagic–benthic coupling processes is discussed in the context of climatic and oceanographic forcing, with emphasis on recent (past decade) Arctic changes. An estimate of total primary production in the Archipelago is also presented, along with published production estimates for other Arctic shelves, showing that the Archipelago may support up to 32% of the total primary production of Arctic shelves. The high year-to-year variability in production and carbon transfer pathways (e.g. pelagic versus benthic) in the Archipelago suggest that the system might be resilient to the increased variability in climatic conditions occurring in the past decade. However, this increased variability combined with directional change in climatic and oceanographic conditions might also modify the existing balance of ecological processes. For example, shifts in the timing of events appear to have already occurred in the past decade, with potential cascading effects throughout the ecosystem.