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1.
R. A. Oktyabrsky A. A. Vrzhosek A. M. Lennikov T. A. Yasnygina S. V. Rasskazov E. Yu. Moskalenko T. A. Velivetskaya 《Russian Journal of Pacific Geology》2008,2(4):325-335
New geochemical data are presented on the magmatic rocks of the Late Jurassic Koksharovka alkaline-ultrabasic massif, which is associated with deposits of vermiculite, apatite, V-bearing titanomagnetite, and placer isoferroplatinum. The REE geochemistry and strontium, oxygen, and carbon isotopic composition of carbonatites and related ijolites and pyroxenites, together with geological observations, point to the magmatic origin of the Koksharovka carbonatites. The origin of associated magmatic rocks is discussed. Trace element modeling of partial melting of mantle sources was conducted to decipher the genesis of the melts of the Koksharovka carbonatites and host titanite-kaersutite pyroxenites. 相似文献
2.
Robert G. Eppinger Paul H. Briggs Cynthia Dusel-Bacon Stuart A. Giles Larry P. Gough Jane M.Hammarstrom Bernard E. Hubbard 《中国地球化学学报》2006,25(B08):232-232
The Bonnifield district hosts 26 tmmined volcanogenic massive sulfide (VMS) occurrences. Environmental geochemical samples of water and stream sediment were collected at several occurrences, concentrating on the two best-exposed and largest deposits, Red Mountain (RM) and Sheep Creek (SC). Limited samples were also collected at the poorly exposed WTF deposit. The deposits are Late Devonian to Early Mississippian, and are hosted by felsic metavolcanic and carbonaceous schist members of the Totatlanika Schist or Keevy Peak Fm. Spring and stream waters at RM and SC have pH values commonly 〈3.5 (as low as 2.4 at RM and 2.5 at SC), high conductivity (up to 11000 μS/cm), and very high (Is to 100s mg/L) dissolved contents of Al, Cd, Co, Cu, Fe, Ni, and Pb. Waters at RM are characterized by extremely high REE contents (summed REE median 3200 μg/L, n=33). At both RM and SC, pyrite oxidation and dissolution produce low pH waters that interact with and dissolve bedrock minerals, resulting in acidic, metal-laden, naturally degraded streams that are mostly devoid of aquatic life. Ferricrete is common. In contrast, WTF barely produces a surficial environmental footprint, mostly due to topography and relief. RM and SC are well exposed in the areas of relatively high relief, and both exhibit extensive areas of quartz-sericite-pyrite-alteration. While WTF shares many of the same deposit-and alteration characteristics, it is concealed by tundra in a large, nearly flat area. Surface water at WTF is absent and outcrops are sparse. Even though WTF is roughly the same size as Red Mountain (both around 3 million tonnes) and has similar base- and precious-metal grades, the surficial geochemical manifestation of WTF is minimal. However, exposure through mining of the altered, mineralized rock at WTF potentially could initiate the same processes of pyrite oxidation, acid generation, and mineral dissolution that are observed naturally at RM and SC. 相似文献
3.
华南地区晚二叠和晚三叠世煤中稀土元素特征研究 总被引:2,自引:0,他引:2
在华南地区贵州六盘水、江西乐平、露庆和湖北黄石矿区晚二叠和晚三叠世煤层的稀土元素ICP—MS分析数据的基础上,系统研究了研究区煤中稀土元素的含萤分布特征、赋存特征、配分模式以及地质控制因素。含量分布表明晚二叠世稀土元素含量总体高于晚三叠世;煤中稀土元素与灰分成正相关关系,部分煤样品由于有富稀土元素的重矿物组合的存在而出现稀土元素的异常高值;同一矿区、同一时代煤中稀土元素的配分模式具有一定的相似性,而不同地区同一时代和同一地区不同时代煤中稀土元素的配分模式具有较大差异;煤的沉积环境,煤中无机矿物组成以及海水的影响是控制煤中稀土元素含量和配分模式的主要地质因素。 相似文献
4.
Distribution of the rare-earth elements (REE) in dacite has been studied so as to get a better understanding of the migration
behavior of REE during alteration. Both unaltered and altered samples were collected in an unpolluted area of Guangxi Zhuang
Autonomous Region, southwest China. The REE concentrations were analyzed by ICP-MS. It is concluded that the REE were enriched
during dacite alteration in varying degrees. The chondrite-normalized REE patterns of altered samples approximately maintain
the characteristics of unaltered samples. However, if we normalize the REE concentrations of altered samples with unaltered
dacite, fractionation of REE will appear. The LREE are more enriched than HREE in all altered samples with the LREE possibly
precipitated as carbonate minerals. Both positive and negative Eu anomalies exist. Enrichment, immobility and depletion are
noticed for the element Lu. Heavy mineral alteration, difference in stability constant between carbonate LREE and HREE complexes,
downward migration of weathering fluid and microenvironment change may be responsible for the fractionation of REE in the
altered dacite. 相似文献
5.
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7.
E.V. Lazareva S.M. Zhmodik A.V. Prokopiev N.S. Karmanov A.I. Sergeenko 《Russian Geology and Geophysics》2018,59(10):1330-1347
Nodular monazite occurs in metamorphic rocks worldwide and has zonal REE patterns. This paper focuses on the composition of nodular monazite hosted by Permian black shales of the Kular Ridge in the Kular-Nera terrane. This monazite variety (called kularite in the Russian literature) reaches commercial amounts in placers of the area. The contents of Ce, Nd, and La in the analyzed monazite nodules show correlations at Ce/Nd = 14.39La + 0.0919 (in apfu) and Ce/Nd = 0.2318La + 0.1135 (in wt.%) and vary regularly from core to rim. All monazite compositions fall on this trend, but specific grains may plot in its different parts. Thermodynamic calculations indicate that monazite forms via an intermediate precursor (LnPO4·2H2O). The Ce:La:Nd changes in different grains record Eh-pH variations during nucleation and a gradual temperature increase during subsequent growth. The Ce:La:Nd ratio changes partly in grain rims as a result of oxidative dissolution. Judging by the tectonic setting, REE came to the Kular-Nera rocks from the weathered Tomtor Nb-REE deposit, being transported by the Paleo-Khatanga River with monazite nanoparticles bound to the surface of clay minerals. 相似文献
8.
西太平洋暖池近3万年来的沉积序列及其环境特征-WP92-3柱样的REE记录 总被引:1,自引:0,他引:1
WP92-3柱样采自西太平洋暖池核心区。利用稀土元素(REE)特征参数研究了该柱样的沉积物来源和地层序列划分,并对其所揭示的环境变化特征进行了探讨。研究认为:样品的REE分布模式揭示了该海域的沉积物源主要为海相自生沉积;基于REE指标的垂向深度变化特征可将该柱样划分为3个地层序列;∑REE,LREE/HREE和δCe几个指标对环境的温度变化以及地磁场的极性变换均有良好的响应,∑REE高值段基本对应于δ18O和SST所揭示的暖池低温期,而地磁场极性转变的时间正好对应着稀土指标(∑REE,LREE/HREE和δCe)快速大幅波动的层位。REE特征参数较好地记录了暖池区近3万年来的沉积和环境变化信息,是一组对气候环境演化具有潜在良好指示作用的地球化学指标。 相似文献
9.
山东招掖金矿带稀土元素地球化学特征初步研究 总被引:1,自引:0,他引:1
本文提出了解决本区某些地质问题的新信息。认为不同地质体具有大体相似的稀土元素配分模型,成岩成矿关系密切,具有继承性演化特点。各类花岗质岩石由胶东群变质岩经混合岩化作用形成。成矿热液富含[CO_3]~(2-)或[HCO_3]~-,金在黄铁矿和石英中富集,与∑REE、LREE的含量及∑Ce/∑Y、Ce/Yb、La/Yb比值呈正相关。上述参数可用作该类金矿床矿化富集规模和强度的评价标志。 相似文献
10.
岩浆分离结晶作用过程微量元素反演 总被引:1,自引:0,他引:1
介绍岩浆分离结晶作用中微量元素系统反演的基本原理和方法,反演计算中极小化问题的求解,反演所需要的优选模式参数估计方法,进行反演的计算机程序,利用模拟数据和实测数据检验了方法和程序的有效性. 相似文献