全文获取类型
收费全文 | 1039篇 |
免费 | 161篇 |
国内免费 | 419篇 |
专业分类
测绘学 | 18篇 |
大气科学 | 107篇 |
地球物理 | 196篇 |
地质学 | 1038篇 |
海洋学 | 160篇 |
天文学 | 4篇 |
综合类 | 44篇 |
自然地理 | 52篇 |
出版年
2024年 | 8篇 |
2023年 | 21篇 |
2022年 | 32篇 |
2021年 | 48篇 |
2020年 | 38篇 |
2019年 | 45篇 |
2018年 | 48篇 |
2017年 | 40篇 |
2016年 | 32篇 |
2015年 | 43篇 |
2014年 | 82篇 |
2013年 | 67篇 |
2012年 | 51篇 |
2011年 | 74篇 |
2010年 | 67篇 |
2009年 | 67篇 |
2008年 | 94篇 |
2007年 | 80篇 |
2006年 | 72篇 |
2005年 | 73篇 |
2004年 | 63篇 |
2003年 | 73篇 |
2002年 | 44篇 |
2001年 | 49篇 |
2000年 | 38篇 |
1999年 | 38篇 |
1998年 | 33篇 |
1997年 | 27篇 |
1996年 | 41篇 |
1995年 | 17篇 |
1994年 | 27篇 |
1993年 | 17篇 |
1992年 | 17篇 |
1991年 | 9篇 |
1990年 | 7篇 |
1989年 | 4篇 |
1988年 | 5篇 |
1987年 | 8篇 |
1986年 | 9篇 |
1985年 | 4篇 |
1984年 | 2篇 |
1983年 | 3篇 |
1982年 | 2篇 |
排序方式: 共有1619条查询结果,搜索用时 31 毫秒
1.
《Planetary and Space Science》2002,50(9):871-876
C10H6-Fe+ complexes were observed by Fourier transform mass spectrometry by Marty et al. (Chem. Phys. Lett. 256 (1996) 669). In this article, we present the infra-red (IR) spectra of the two isomers calculated by ab initio methods of quantum chemistry. In the past, the same approach has predicted successfully unexpected features of the IR spectra of polycyclic aromatic hydrocarbon (PAH) cations which were confirmed by measurements in matrices (J. Phys. Chem. 98 (1994) 9187). The C10H6-Fe+ systems are models for larger PAHs-Fe+ complexes, which are believed to play a key rôle in space chemistry. 相似文献
2.
素土桩挤密地基由桩间挤密土和回填素土夯实的桩体组成,它是一种人工“复合地基”。其作用是通过素土桩挤密法提高地基土的密实度,从而对湿陷性黄土达到消除浅部或深部的部分或全部湿陷性的作用,并改善地基承载能力,减少地基变形。本文通过现场单桩、群桩单元体轻便触探、小环刀深层取样、开剖取样等方法对场地地基土挤密前、后干重度和压实系数进行了对比分析,判定用素土桩挤密法处理陇东湿陷性黄土地基的可行性。 相似文献
3.
4.
5.
研究了2003年10月采于珠江口5个站位的沉积物剖面酸挥发性硫化物(AVS)和同时提取的重金属(SEM:Pb,Zn,Cu,Cd,Ni)。其中,站位1、2位于中滩,其沉积物的AVS含量变化范围较小,为0.25—4.06μmol.g-1;站位3、4位于西滩,其沉积物的AVS含量变化范围较大,为0—26.09μmol.g-1。中滩和西滩沉积物的AVS含量均随深度增加。西滩表层沉积物的AVS含量接近于零,这可能与该水域较强的底层流和沉积物的再悬浮作用有关。站位5位于珠江口外侧,其表层沉积物的AVS含量相对较高,且垂向变化较小,可能是还原性沉积物间歇性再悬浮后重新沉积的结果。站位1、2和5沉积物中同时提取的重金属含量大体在0.95±0.2μmol.g-1范围内,随深度增加略呈下降趋势;而西滩沉积物重金属含量相对较高,为1.43—2.42μmol.g-1,且在一定深度范围内随深度增加呈明显下降的趋势,表明珠江口西滩沉积物中的重金属污染有加重的趋势。对AVS/SEM摩尔比值和单个金属的毒性效应研究显示,珠江口内尤其是西滩的表层沉积物存在重金属污染,对其中生活的底栖生物具有潜在的毒性效应。 相似文献
6.
考虑到平台所在海区台风出现的频次及其诱发之风、浪、潮、流极端海况联合出现的概率特性,本文推导出Poisson—Logistic二元复合极值模式,并以平台甲板标高进行实例计算。新模式增加了概率模型的物理内涵,解决了Logistic模型阈值选取的任意性。对海洋工程极端海况荷载组合预测具有广泛的应用前景。 相似文献
7.
Photoinduced toxicity single and binary mixtures of four polycyclic aromatic hydrocarbons to the marine diatom Skeletonema costatum 总被引:1,自引:0,他引:1
Diatom Skeletonema costatum Cleve is one of the main predominant phytoplankton species in the Changjiang Estuary in China. In order to provide some basic information for future assessment of the potential risk on phytoplankton communities in this estuary caused by polycyclic aromatic hydrocarbons(PAHs), this alga was selected as a representative to investigate the photoinduced toxicity of PAHs, in single and mixture. Four PAHs including three-ring phenanthrene and anthracene, four-ring fluoranthene and pyrene were tested in the laboratory. The single toxicity of each PAH on this microalga was compared with and without the simulated solar UV radiation. The results showed that this microalga was sensitive to PAH's photoinduced toxicity. Ratios of the 72 h median effect concentration obtained for fluorescent and UV light tests were about 8.4 for phenanthrene, 13.0 for anthracene, 6.5 for fluoranthene, and 5.7 for pyrene, indicating that UV light enhanced the PAH toxicity to this alga significantly. Under the fluorescent radiation (lacking UV), the dose-response curves based on chemical concentrations revealed that the order of toxic strength was fluoranthene greater than pyrene greater than anthracene greater than phenanthrene; while under the UV radiation (476 μW/cm2 for UVA, 6.5 μW/cm2 for UVB) it became fluoranthene approximately equaling anthracene greater than pyrene greater than phenanthrene, indicating that the UV light also changed its relative toxicity to this alga. The photoinduced toxicity of PAHs to the marine diatom S. costatum might be a synergistic effect of photosensitization reactions (e.g., generation of single-state oxygen) and photomodification (photooxidation and/or photolysis).The combined effects of six binary mixtures on the marine diatom S. costatum were investigated using the additive-index method. Four binary-mixtures (phenanthrene plus anthracene; phenanthrene plus pyrene; anthracene plus fluoranthene; anthracene plus pyrene) were found to be synergistic joint action mode, while two binary-mixtures (phenanthrene plus fluoranthene; fluoranthene plus pyrene) displayed antagonist, revealing a complex pattern of possible interactions. The combined action mode of PAHs might be related to various factors such as the mixture compounds, mixture ratios and test conditions, etc. 相似文献
8.
Abbondanzi F Campisi T Focanti M Guerra R Iacondini A 《Marine environmental research》2005,59(5):419-434
A study was conducted to determine polycyclic aromatic hydrocarbons (PAHs) distribution and microbial population changes in brackish sediments from an Italian lagoon included in the Ramsar List of Wetlands of International Importance. The presence and level of PAH-degrading bacteria were estimated by the most probable number (MPN) enumeration technique, whereas degradation capability towards target compounds was checked against loss of spiked PAHs (Phenanthrene, Anthracene and Fluoranthene) in MPN tubes after incubation in optimal conditions. Chemical analyses and microbiological counts suggested a potential for PAHs biodegradation by natural occurring populations of sediment microorganisms, thus indicating an "optimal range" in sediment PAHs concentrations, outside of which the natural selection of the indigenous microflora did not occur. The MPN procedure here described, provided an effective and reliable way to simultaneously determine microbial population densities and subsequent confirmation of the biodegradation capability of sediment indigenous microflora when exposed to laboratory and environmental concentrations of PAHs. 相似文献
9.
对虾养殖水质与饵料的关系研究 总被引:3,自引:0,他引:3
本文报道投喂不同厂家生产的对虾配合饵料致使水质因子变化的比较试验。结果表明:对虾养殖水体的pH、溶解氧及氨氮含量的变化和饵料的质量有直接关系,且影响到对虾的生存。而养殖水体的盐度、温度的变化和饵料的相关性不甚明显。文中还对配合饵料影响养殖水质因子变化的机理作了初步探讨。 相似文献
10.
本文研究了虾蟹海产品香味的前体物质在加热前后的变化。实验结果表明:对虾和蟹肌肉中的糖原和不饱和脂肪酸在加热前后含量下降,糖原是Maillard反应的基础物质.不饱和脂肪酸是虾蟹肌肉香味中羰基化合物的前体物质。虾蟹肌肉中主要积累的核苷酸成分AMP在加热后减少,而肌肉提取物中的游离氨基酸和结合氨基酸,特别是疏水氨基酸含量均增加。 相似文献