Palaeoenvironmental significance of Late Permian palaeosols in the South‐Eastern Iberian Ranges,Spain

The Late Permian (Wuchiapingian) Alcotas Formation in the SE Iberian Ranges consists of one red alluvial succession where abundant soil profiles developed. Detailed petrographical and sedimentological studies in seven sections of the Alcotas Formation allow six different types of palaeosols, with distinctive characteristics and different palaeogeographical distribution, to be distinguished throughout the South‐eastern Iberian Basin. These characteristics are, in turn, related to topographic, climatic and tectonic controls. The vertical distribution of the palaeosols is used to differentiate the formation in three parts from bottom to top showing both drastic and gradual vertical upwards palaeoenvironmental changes in the sections. Reconstruction of palaeoenvironmental conditions based on palaeosols provides evidence for understanding the events that occurred during the Late Permian, some few millions of years before the well‐known Permian‐Triassic global crisis.     

Pedogenic factors affecting magnetic susceptibility of the last interglacial palaeosol S1 in the Chinese Loess Plateau

The magnetic susceptibility has been used as a quantitative or semi‐quantitative proxy for reconstructing the summer monsoon intensity in the Chinese Loess Plateau based on extensive studies on climatic or/and environmental mechanisms producing the magnetic susceptibility signatures. However, the precise nature of the link between past climates and the susceptibility signatures has remained uncertain primarily due to lack of our understanding in the ?nalizing and preserving processes of the signatures. This paper attempts to examine the reliability or acceptability of this summer monsoon proxy from non‐magnetic perspectives of soil‐forming processes. We chose nine sections along two transects: one across the western part of the Chinese Loess Plateau and another across the eastern part. Several conclusions can be drawn from our analytical data. First, clay translocation within the S1 palaeosol pro?les, as indicated by ?eld‐observed clay coatings on ped faces in Bt and Bk horizons and demonstrated by laboratory‐analysed clay contents, must have moved some of the magnetic minerals downward so that the susceptibility re?ects only the post‐translocation distribution of the magnetic‐susceptibility‐producing minerals. Second, the best‐developed palaeosol S1S3 at most of the sections studied is not expressed by the magnetic susceptibility because this palaeosol developed in underlying coarse loess (L2) and coarse textures tend to lower the susceptibility. Third, carbonate concentration is normally negatively correlated with the magnetic susceptibility or simply suppresses the magnetic susceptibility peak when the susceptibility enhancement exceeds the carbonate dilution effect. To conclude, extreme caution must be observed when using magnetic susceptibility signatures to retrieve high‐resolution records of the last interglacial palaeoclimate in the Chinese Loess Plateau. Copyright © 2004 John Wiley & Sons, Ltd.     

Morphology and distribution of fossil soils in the Permo-Pennsylvanian Wichita and Bowie Groups, north-central Texas, USA: implications for western equatorial Pangean palaeoclimate during icehouse–greenhouse transition

Analysis of stacked Permo‐Pennsylvanian palaeosols from north‐central Texas documents the influence of palaeolandscape position on pedogenesis in aggradational depositional settings. Palaeosols of the Eastern shelf of the Midland basin exhibit stratigraphic trends in the distribution of soil horizons, structure, rooting density, clay mineralogy and colour that record long‐term changes in soil‐forming conditions driven by both local processes and regional climate. Palaeosols similar to modern histosols, ultisols, vertisols, inceptisols and entisols, all bearing morphological, mineralogical and chemical characteristics consistent with a tropical, humid climate, represent the Late Pennsylvanian suite of palaeosol orders. Palaeosols similar to modern alfisols, vertisols, inceptisols, aridisols and entisols preserve characteristics indicative of a drier and seasonal tropical climate throughout the Lower Permian strata. The changes in palaeosol morphology are interpreted as being a result of an overall climatic trend from relatively humid and tropical, moist conditions characterized by high rainfall in the Late Pennsylvanian to progressively drier, semi‐arid to arid tropical climate characterized by seasonal rainfall in Early Permian time. Based on known Late Palaeozoic palaeogeography and current hypotheses for atmospheric circulation over western equatorial Pangea, the Pennsylvanian palaeosols in this study may be recording a climate that is the result of an orographic control over regional‐scale atmospheric circulation. The trend towards a drier climate interpreted from the Permian palaeosols may be recording the breakdown of this pre‐existing orographic effect and the onset of a monsoonal atmospheric circulation system over this region.     

Contrasting geochemical signatures on land from the Middle and Late Permian extinction events

The end of the Palaeozoic is marked by two mass‐extinction events during the Middle Permian (Capitanian) and the Late Permian (Changhsingian). Given similarities between the two events in geochemical signatures, such as large magnitude negative δ¹³C anomalies, sedimentological signatures such as claystone breccias, and the approximate contemporaneous emplacement of large igneous provinces, many authors have sought a common causal mechanism. Here, a new high‐resolution continental record of the Capitanian event from Portal Mountain, Antarctica, is compared with previously published Changhsingian records of geochemical signatures of weathering intensity and palaeoclimatic change. Geochemical means of discriminating sedimentary provenance (Ti/Al, U/Th and La/Ce ratios) all indicate a common provenance for the Portal Mountain sediments and associated palaeosols, so changes spanning the Capitanian extinction represent changes in weathering intensity rather than sediment source. Proxies for weathering intensity chemical index of alteration, ?W and rare earth element accumulation all decline across the Capitanian extinction event at Portal Mountain, which is in contrast to the increased weathering recorded globally at the Late Permian extinction. Furthermore, palaeoclimatic proxies are consistent with unchanging or cooler climatic conditions throughout the Capitanian event, which contrasts with Changhsingian records that all indicate a significant syn‐extinction and post‐extinction series of greenhouse warming events. Although both the Capitanian and Changhsingian event records indicate significant redox shifts, palaeosol geochemistry of the Changhsingian event indicates more reducing conditions, whereas the new Capitanian record of reduced trace metal abundances (Cr, Cu, Ni and Ce) indicates more oxidizing conditions. Taken together, the differences in weathering intensity, redox and the lack of evidence for significant climatic change in the new record suggest that the Capitanian mass extinction was not triggered by dyke injection of coal‐beds, as in the Changhsingian extinction, and may instead have been triggered directly by the Emeishan large igneous province or by the interaction of Emeishan basalts with platform carbonates.     

Stable isotopes of pedogenic carbonates from the Somma–Vesuvius area,southern Italy,over the past 18 kyr: palaeoclimatic implications

Stable isotopes were measured in the carbonate and organic matter of palaeosols in the Somma–Vesuvius area, southern Italy in order to test whether they are suitable proxy records for climatic and ecological changes in this area during the past 18000 yr. The ages of the soils span from ca. 18 to ca. 3 kyr BP. Surprisingly, the Last Glacial to Holocene climate transition was not accompanied by significant change in δ¹⁸O of pedogenic carbonate. This could be explained by changes in evaporation rate and in isotope fractionation between water and precipitated carbonate with temperature, which counterbalanced the expected change in isotope composition of meteoric water. Because of the rise in temperature and humidity and the progressive increase in tree cover during the Holocene, the Holocene soil carbonates closely reflect the isotopic composition of meteoric water. A cooling of about 2°C after the Avellino eruption (3.8 ka) accounts for a sudden decrease of about 1‰ in δ¹⁸O of pedogenic carbonate recorded after this eruption. The δ¹³C values of organic matter and pedogenic carbonate covary, indicating an effective isotope equilibrium between the organic matter, as the source of CO₂, and the pedogenic carbonate. Carbon isotopes suggest prevailing C₃ vegetation and negligible mixing with volcanogenic or atmospheric CO₂. Copyright © 2000 John Wiley & Sons, Ltd.     

Modelling palaeosol preservation in aeolian dunes

In some of the world's desert and desert‐marginal areas (e.g. Simpson/Strzelecki, Australia) dunefields preserve well‐developed palaeosols, whereas in other regions with broadly similar climatic regimes and topography (e.g. southwest Kalahari), the dunes are characterized by very poorly developed internal stratigraphy. It has been postulated that dunes such as those in the Kalahari may never have had conditions conducive to soil formation, or that soils once formed but any evidence of palaeosols has been lost due to reworking. This study develops and applies a one‐dimensional numerical model to simulate dune development, soil formation and soil preservation. Variables in the model allowed experimentation on the influence of sediment supply, the time taken for soil to form, and the additional resistance to erosion offered by the soil. Reduced sediment supply plays a vital role in landscape development during periods of initial pedogenesis. Although re‐exhumed palaeosols influence sediment supply, the effect is minimal. Although under almost all parameterized conditions more than half (and up to 80‐90%) of those soils initially formed are lost due to reworking, evidence of their past formation remains in the large majority of profiles, and the dominant factor in controlling the preservation of palaeosols is the frequency of their formation. The implication is that where dunes are found without palaeosols, the most likely (albeit not certain) inference is that they have never formed. Counter‐intuitively, the limited sediment supply means their additional resistance to erosion becomes almost inconsequential to their preservation, at least until the unit approaches complete invulnerability. Short chronostratigraphic hiatuses around palaeosols are normal, and although long gaps can occur, they are extremely infrequent. Where such gaps are observed in field studies, external forcing factors (e.g. climatic or environmental changes) are implied, as they are highly unlikely to result from stochastic net preservation. Copyright © 2014 John Wiley & Sons, Ltd.     

大别山北麓竹竿河黄土—古土壤的磁组构特征及其古环境意义

大别山北麓竹竿河黄土—古土壤样品的磁组构特征显示,研究剖面0～1480cm层段的平均Pj、F值小于1.02,而底部Pj、F大于1.02。F—L、Pj—q组合关系图反映磁化率椭球体为压扁状,磁面理较磁线理发育。磁化率椭球体主轴方位显示0～1480cm层段样品的椭球体轴向分布分散,长轴的倾角大于60°,短轴的倾角小于15°,而底部的分布聚集,长轴的倾角一般小于10°,短轴的倾角大于80°,上述特征综合揭示了0～1480cm层段属于典型风成沉积而底部属于典型水成沉积。磁化率椭球体最大主轴的偏角暗示风成沉积的主导风向为NW—SE方向,而水成沉积的古流向为SW—NE方向,与现代竹竿河水系的方向基本一致。磁化率各向异性最大轴方向的优选方向可能与大别山抬升等构造运动有关。     

A test of models of fluvial architecture and palaeosol development: Camp Rice Formation (Upper Pliocene-Lower Pleistocene), southern Rio Grande rift, New Mexico, USA

Numerical, experimental and theoretical models of fluvial architecture and palaeosol development are tested with outcrops of Upper Pliocene-Lower Pleistocene sediment in the southern Rio Grande rift, New Mexico. The sediment was deposited and subsequently exhumed in the Jornada del Muerto basin, a westward-tilted half graben whose footwall corresponds to the Rincon Hills and San Diego Mountain fault blocks. The axial river, the ancestral Rio Grande, shared time between the Jornada del Muerto basin and the adjacent Corralitos basin. The ancestral Rio Grande entered the Jornada del Muerto basin via a gap between the footwall blocks, periodically flowing southward towards San Diego Mountain, or making a broad northward sweep into the northern fluvial salient towards the Rincon Hills fault block and unfaulted northern edge of the basin. Ten logged sections up to 35 m thick are correlated using the top of the formation (La Mesa surface), a 1·59 Ma pumice conglomerate, and a ground-water carbonate/opal bed. Additionally, one of the sections is dated by reversal magnetostratigraphy. Consistent with the model of Bridge & Leeder (1979 ) and Bridge & Mackey (1993a ), differential tilting of the Jornada del Muerto half graben resulted in sections directly adjacent to the faults that consist almost exclusively of multistorey channel sands/sandstones, whereas more distal sections contain a greater proportion of crevasse-splay fine sand and overbank mudstone and calcic palaeosols. Along the axis of the northern fluvial salient, a northward decrease in channel/floodplain ratio, a decrease in channel recurrence interval from 171 kyr to 685 kyr, and an increase in the maturity of calcic palaeosols are consistent with southward tilt of the unfaulted northern edge of the basin. An upsection decrease in sediment accumulation rate in the northern fluvial salient from 0·036 mm/ yr to 0·017 mm/ yr corresponds to an increase in the ratio of channel/floodplain facies and in the number of multistorey channel sands/sandstones, and is consistent with the model of Bridge & Leeder (1979 ) in which avulsion frequency is independent of sediment accumulation rate. Stage II and III calcic palaeosols indicate 10³−10⁵ year of landscape stability and soil formation between periods of floodplain deposition in response not only to basin tilting but also because the ancestral Rio Grande had multiple paths within the Jornada del Muerto basin and shared time between the Corralitos and Jornada del Muerto basins.     

Diagenetic overprinting of the sphaerosiderite palaeoclimate proxy: are records of pedogenic groundwater δ18O values preserved?

Meteoric sphaerosiderite lines (MSLs), defined by invariant δ¹⁸O and variable δ¹³C values, are obtained from ancient wetland palaeosol sphaerosiderites (millimetre‐scale FeCO₃ nodules), and are a stable isotope proxy record of terrestrial meteoric isotopic compositions. The palaeoclimatic utility of sphaerosiderite has been well tested; however, diagenetically altered horizons that do not yield simple MSLs have been encountered. Well‐preserved sphaerosiderites typically exhibit smooth exteriors, spherulitic crystalline microstructures and relatively pure (> 95 mol% FeCO₃) compositions. Diagenetically altered sphaerosiderites typically exhibit corroded margins, replacement textures and increased crystal lattice substitution of Ca²⁺, Mg²⁺ and Mn²⁺ for Fe²⁺. Examples of diagenetically altered Cretaceous sphaerosiderite‐bearing palaeosols from the Dakota Formation (Kansas), the Swan River Formation (Saskatchewan) and the Success S2 Formation (Saskatchewan) were examined in this study to determine the extent to which original, early diagenetic δ¹⁸O and δ¹³C values are preserved. All three units contain poikilotopic calcite cements with significantly different δ¹⁸O and δ¹³C values from the co‐occurring sphaerosiderites. The complete isolation of all carbonate phases is necessary to ensure that inadvertent physical mixing does not affect the isotopic analyses. The Dakota and Swan River samples ultimately yield distinct MSLs for the sphaerosiderites, and MCLs (meteoric calcite lines) for the calcite cements. The Success S2 sample yields a covariant δ¹⁸O vs. δ¹³C trend resulting from precipitation in pore fluids that were mixtures between meteoric and modified marine phreatic waters. The calcite cements in the Success S2 Formation yield meteoric δ¹⁸O and δ¹³C values. A stable isotope mass balance model was used to produce hyperbolic fluid mixing trends between meteoric and modified marine end‐member compositions. Modelled hyperbolic fluid mixing curves for the Success S2 Formation suggest precipitation from fluids that were < 25% sea water.