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1.
Radiocaesium isotopes, discharged into the North-east Irish Sea from the Sellafield (formerly Windscale) nuclear fuel reprocessing plant in Cumbria, have been employed as flow monitors to update and extend the record of coastal water movement from the Irish Sea to the Clyde Sea area and, further north, to Loch Etive. The temporal trends in radiocaesium levels have been used to determine the extent of water mixing en route and to define mean advection rates. Flow conditions from the Irish Sea have changed considerably since the mid-1970s, the residence time of northern Irish Sea waters being ~12 months during 1978–1980 inclusive. Average transport times of four and six months are estimated for the Sellafield to Clyde and Sellafield to Etive transects respectively. Sellafield 137Cs levels in seawater were diluted by factors of 27 and 50 respectively during current movement to the Clyde and Etive areas. The decrease in salinity-corrected 137Cs concentrations between the Clyde and Etive suggests that dilution by Atlantic water occurs, the latter mainly entering the Firth of Lorne from the west. The majority (~94%) of the radiocaesium supply to Loch Etive enters the Firth of Lorne via the portion of the coastal current circulating west of Islay, only ~6% arriving via the Sound of Jura. 相似文献
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This work deals with disposal of slurries generated during the cutting and polishing processes of slabs of decorative sedimentary
carbonate rocks in the north western Sicily. At present, they are used as fillers of dismantled quarries near the sawmills
and, as a final step of reclamation, are covered with earth layers. In spite of such inexpensive solution, there is lack of
knowledge about the composition of the waste. In order to assess if there is any threat for the environment and to suggest
indications for alternative solutions, such as recycling or inactivation processes, the slurries were analysed by XR diffraction,
simultaneous thermal analysis, ICP/MS, ionic chromatography, FTIR, UV-Vis, COD and TOC measurements, grain size analysis.
Results indicate that the slurries can threaten the groundwater, because of the high chemical oxygen demand; furthermore they
can modify the mechanism of groundwater recharge, because of their grain size distribution. Some laboratory tests show that,
even in very aggressive conditions, the solid pollutants persist in the waste and slowly release into water the products of
their degradation. The slurry therefore should be subjected to inactivation treatment before disposal or, alternatively, recycled
as secondary raw material for a suitable process. 相似文献
4.
G. Diego Gatta Nicola Rotiroti Martin Fisch Milen Kadiyski Thomas Armbruster 《Physics and Chemistry of Minerals》2008,35(9):521-533
The elastic and structural behaviour of the synthetic zeolite CsAlSi5O12 (a = 16.753(4), b = 13.797(3) and c = 5.0235(17) Å, space group Ama2, Z = 2) were investigated up to 8.5 GPa by in situ single-crystal X-ray diffraction with a diamond anvil cell under hydrostatic conditions. No phase-transition occurs within the P-range investigated. Fitting the volume data with a third-order Birch–Murnaghan equation-of-state gives: V 0 = 1,155(4) Å3, K T0 = 20(1) GPa and K′ = 6.5(7). The “axial moduli” were calculated with a third-order “linearized” BM-EoS, substituting the cube of the individual lattice parameter (a 3, b 3, c 3) for the volume. The refined axial-EoS parameters are: a 0 = 16.701(44) Å, K T0a = 14(2) GPa (βa = 0.024(3) GPa?1), K′ a = 6.2(8) for the a-axis; b 0 = 13.778(20) Å, K T0b = 21(3) GPa (βb = 0.016(2) GPa?1), K′ b = 10(2) for the b-axis; c 0 = 5.018(7) Å, K T0c = 33(3) GPa (βc = 0.010(1) GPa?1), K′ c = 3.2(8) for the c-axis (K T0a:K T0b:K T0c = 1:1.50:2.36). The HP-crystal structure evolution was studied on the basis of several structural refinements at different pressures: 0.0001 GPa (with crystal in DAC without any pressure medium), 1.58(3), 1.75(4), 1.94(6), 3.25(4), 4.69(5), 7.36(6), 8.45(5) and 0.0001 GPa (after decompression). The main deformation mechanisms at high-pressure are basically driven by tetrahedral tilting, the tetrahedra behaving as rigid-units. A change in the compressional mechanisms was observed at P ≤ 2 GPa. The P-induced structural rearrangement up to 8.5 GPa is completely reversible. The high thermo-elastic stability of CsAlSi5O12, the immobility of Cs at HT/HP-conditions, the preservation of crystallinity at least up to 8.5 GPa and 1,000°C in elastic regime and the extremely low leaching rate of Cs from CsAlSi5O12 allow to consider this open-framework silicate as functional material potentially usable for fixation and deposition of Cs radioisotopes. 相似文献
5.
Risk-based decision-making for drilling waste discharges using a fuzzy synthetic evaluation technique 总被引:5,自引:0,他引:5
Offshore petroleum drilling wastes contain toxic substances that are potentially harmful to the marine ecosystem. Despite environmentally benign characteristics, wastes associated with synthetic-based fluids still contain a certain amount of pollutants due to contamination with formation oil and the presence of trace heavy metals in barite, which may pose risk when discharged into the marine environment. A framework is presented here for a decision support system for the selection of the best drilling waste discharge option. Uncertainties in the quantification of risk, cost and technical feasibility are expressed by fuzzy numbers. An analytical hierarchy process with a technique called fuzzy synthetic evaluation is employed to determine the best management alternative (discharge scenario). 相似文献
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地面核磁共振模型约束反演含水层参数 总被引:1,自引:1,他引:0
导电模型的地面核磁共振感应电动势是含水量的非线性函数.引入模型约束的迭代反演方法求解该非线性问题的反演.在反演过程中,根据理论公式计算迭代过程中灵敏度矩阵,并采用平坦模型和光滑模型两种约束.对均匀半空间、层状导电模型和实际数据进行了反演模拟,结果表明,模型约束迭代反演方法能从地面核磁共振感应电动势获得含水层较为合理的含水量及分布,且该结果可以从作为初始模型的均匀含水量分布反演得到.对无噪音数据,平坦模型和光滑模型约束对反演的含水量分布影响不大;但当数据存在一定的噪音时,平坦模型约束将比光滑模型约束获得更为精确的含水层参数. 相似文献
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In Gaborone, as in other large cities in the developing world, individuals try to make a living by engaging in novel occupations
such as landfill scavenging. This paper reports on a research conducted in the Gaborone landfill, the largest in Botswana.
The study content-analyzed available literature from other countries. It also relied mainly on direct field observations.
The discussions on and answers to closed and interview schedules by stakeholders, affected- and- interested – persons, provided
the information on the threats and opportunities related to the landfill site and its informal management activities. This
on-going case study lends credence to the potential of scavenging in sustaining livelihoods among those who cannot secure
employment in the formal urban market. Scavenging tends to be useful although it may hazardous to the informal entrepreneurs.
Taking all the threats into consideration, the decommissioning and closure of the landfill seems inevitable, in spite of the
apparent short-term livelihood opportunities it provides to the informal sector. 相似文献