内蒙阿右旗铁板井镍矿矿床特征及成因探讨

铁板井绦矿床赋存于辉橄岩体中,辉橄岩体具有全岩矿化的特点,岩体及镍矿体的形成经历了三种不同的成矿过程:首先是岩浆深源液态重力分异作用,而后发生岩浆深源熔离-贯入(成岩、成矿)作用,形成岩体和镍矿体,最后在岩浆期后热液作用的叠加下完成整个成矿过程.该矿床是典型的主要由岩浆熔离作用形成的岩浆矿床.     

<Superscript>40</Superscript>Ar-<Superscript>39</Superscript>Ar dating of lamprophyre dykes in the Baimazhai nickel deposit,Yunnan Province,China, and its geological significance

The Baimazhai nickel deposit, Yunnan Province, China, is located in the southern part of the Sanjiang （Tri-river） alkali-rich intrusive rock belt （Sanjiang ARIR）. In this paper was conducted ^40Ar-^39Ar dating of two phlogopites in lamprophyres which are, as dikes, widely distributed in the orefield, and two plateau ages were acquired, i.e., 32.46±0.62 Ma and 32.01±0.60 Ma, respectively （averaging 32.23±0.60 Ma）. The ages are obviously younger than those of the ore-hosted complex and mineralization of the Baimazhai nickel deposit. In combination with the characteristics, it is indicated that lamprophyres in the orefield and those in the Sanjiang ARIR are similar in tectonic setting, mineral assemblage and geochemistry. It is considered that lamprophyres in the orefield are the important component of the Sanjiang ARIR, and the lamprophyres and ore-hosted complex in the orefield represent the products of two times of different magmatic activity from different mantle sources. On the other hand, the age of lamprophyres in the orefield is older than that of the strike-slip shearing of the Ailaoshan-Honghe fault belt, suggesting that the strike-slip shearing of the Ailaoshan-Honghe fault belt is not the factor leading to magmatic activity of lamprophyres in the orefield, while it is more possible that magmatic activity of the Sanjiang ARIR promoted strike-slip shearing of the fault belt.     

Syntectonic Mobility of Supergene Nickel Ores of New Caledonia (Southwest Pacific). Evidence from Garnierite Veins and Faulted Regolith

Supergene nickel deposits of New Caledonia that have been formed in the Neogene by weathering of obducted ultramafic rocks are controlled by fracture development. The relationship of tropical weathering and tectonic structures, faults and tension gashes, have been investigated in order to determine whether fractures play a passive role only, as previously thought; or alternatively, if brittle tectonics was acting together with alteration. Observation of time‐relationship, textures, and mineralogy of various fracture fills and fault gouges shows that active faulting has played a prominent role not only in facilitating drainage and providing room for synkinematic crystallization of supergene nickel silicate, but also in mobilizing already formed sparse nickel ore, producing the very high grade ore nicknamed “green gold”.     

Interpreting tracer breakthrough tailing in a conduit-dominated karstic aquifer

Breakthrough tailing has been observed during dye-tracing recovery tests in the Norville aquifer system (chalk), France. Karst-conduit flow and transport parameters were assessed using two different interpretative methods: the linear graphical method and the Chatwin method (implemented in the Qtracer2 program). The linear graphical method was used to model the observed tailing effects, which was explained by a second smaller delayed breakthrough curve. By comparing the results of tracer-test interpretation for the two methods, it was possible to relate the area of this second curve to the importance of turbulent flow in spring discharge. The more turbulent the flow, the less important the contribution of the second breakthrough curve and the tailing effect. The observed tailing could possibly be controlled by hydrodynamics to a greater extent than usually expected, the tailing effects being mostly attributed to diffusion phenomena. Tailing effects were expected to increase with discharge and the piezometric level, which would have resulted in overpressure in conduits, fissure flooding, etc. Instead, breakthrough tailing tended to disappear with increasing aquifer discharge, which would support the hypothesis of there being mostly hydrodynamic-controlled tailing effects instead of matrix- or fissure-diffusion.An erratum to this article can be found at     

重油凝胶色谱制备样品中痕量镍的分析研究

研究表明微波密闭消解法对重油凝肢色谱制各样品的前处理，不造成易挥发有机金属化合物的损失，对样品无污染。采用消解前定容，配合石墨炉二次进样富集样品，可以测定样品中低至10^—9级的镍。方法应用于镍在渣油中随相对分子质量分布分析中，标准样品对照数据吻合好，相对标准偏差(RSD，n＝11)为8％。     

无水氯化镍及芳烃基二膦酸四乙酯的制备

1，4—二溴苯，4，4’—二溴联苯、4，4’—二溴三联和亚磷酸三乙酯在催化剂无氯化镍催化下，干燥氮气保护．反应得到相应的有机二磷酸四乙酯。     

镍钼在黑色岩系中富集成因的实验研究

对湘西和黔北早寒武世含Ｎｉ、Ｍｏ等多金属黑色岩系进行了淋滤实验。实验分别模拟了普通雨水、富ＣＯ２气雨水及酸性雨水三种不同淋滤条件。实验表明，黑色岩系中Ｍｏ、Ｎｉ、Ｖ等元素是比较容易被淋滤出的，尤其是在酸性雨水条件下，它们的带出强度最大。本实验为镍钼富集层的成因及寻找类似的矿床提供了依据。＊据（１９６２）。图３实验样品在不同雨水淋滤条件下各个元素带出强度的比较Ｆｉｇ．３Ｃｏｍｐａｒｉｓｏｎｏｆｔｈｅｉｎｔｅｎｓｉｔｙｏｆｔｈａｔｔｈｅｖａｒｉｏｕｓｅｌｅｍｅｎｔｉｎｓａｍｐｌｅｓｉｓｌｅａｃｋｅｄｏｕｔｂｙｄｉｆｆｅｒｅｎｔｒａｉｎｗａｔｅｒｓ从图３上可以看出，不同元素的带出强度有着明显的差别。例如带出强度最大的钼与其最小的铝可以相差４～５个数量级。现代空气雨水与饱含ＣＯ２气的雨水对样品淋滤强度的图形基本相似，也就是它们对各种元素的带出强度是相似的。而酸性度很大的雨水则明显地增强了多数元素的带出强度。值得注意的是钼在上述实验的任何条件下都能被强烈的带出，这是因为在表生条件的氧化作用下，Ｍｏ４＋可氧化为Ｍｏ６＋，形成溶解度较高的钼酸或钼酸盐，在溶液中搬运或呈胶体形式迁移，而在还原条件下，在有机质及铁硫化物大量存?     

2-[2-(6-氯苯并噻唑)偶氮]-5-二乙氨基苯甲酸与镍的显色反应

研究了2-[2-(6-氯苯并噻唑)偶氮]-5-二乙氨基苯甲酸(6-Cl-BTAEB)与Ni2+的显色反应。结果表明:在pH4.5～7.6的HAc-NaAc缓冲溶液中及十二烷基硫酸钠存在下,试剂与Ni2+形成稳定的蓝紫色配合物,组成为n(Ni2+)∶n(6-Cl-BTAEB)=1∶2,最大吸收波长650nm,表观摩尔吸光系数为1.59×105L·mol-1·cm-1,Ni2+浓度在0～400μg/L内符合比尔定律。用铝合金和合金钢中的微量镍验证该分析方法,所得结果与推荐值相符,6次测定的RSD<2%。     

Nickel speciation in Sebertia acuminata,a plant growing on a lateritic soil of New Caledonia

Nickel speciation in a nickel hyperaccumulating plant (Sebertia acuminata) and its associated soil of southern New Caledonia was studied using various analytical methods. The soil is formed of iron oxides (goethite, hematite), which contain almost all the nickel. The available nickel is probably linked to the organic matter in the litter. Sebertia acuminata, acts as a nickel pump, and concentrates the metal in its leaves. It partitions nickel and silica; nickel is concentrated in the cells (probably in the vacuoles) as organometallic complexes, whereas silica forms the framework of the cells, and the phytolithes. A thorough study of these plants seems essential in order to define the soil–plant relations, and to propose appropriate ways for ecological restoration. To cite this article: N. Perrier et al., C. R. Geoscience 336 (2004).     

广西南丹地区有色金属尾砂型人工矿床地质特征及其资源化

广西南丹地区尾矿分布于大厂、车河、芒场等矿区。尾砂来自以锡石为主的多金属矿床，尾砂中除Sn，Pb，Zn，Ag，Sb的质量分数达到工业指标外，Au亦达到综合利用指标。通过试验证明，对尾矿中的细微粒锡石可采用风力分级选矿、磁选和化学选矿等方法回收；尾砂中的非金属资源可作为填充材料、水泥原料利用，使尾砂型人工矿床充分的资源化。