银纳米杆高温熔化断裂弛豫性能的原子级模拟研究

采用分子动力学模拟方法,研究了不同长度银纳米杆在不同温度弛豫过程中的结构演变过程.结果表明:银纳米杆存在一与杆长相关的临界熔断温度,该临界熔断温度随杆长增加而显著降低.当温度大于熔点而小于临界熔断温度时,体系形成一个高度无序的球形团簇,而温度大于临界熔断温度时,体系则熔断成两个球形团簇.并给出了银纳米杆的产生该熔断现象的机理.     

Solvothermal Synthesis of CdSxSe1-x Nanorods by Polymer Gel-Controlled Growth Strategy

Alloyed ternary CdSxSe1-x nanorods have been synthesized by the thermal treatment of Cd2 -dispersed polyethylene glycol 2 000 gel (PEG 2000) with ethylenediamine solution of sulfur and selenium in a sealed system at 180 ℃ for 24 h, in which the ratio of S to Se in the nanorods was controlled by adjusting the relative amounts of the starting materials. Based on the results of experiments, it is found that the CdSxSe1-x nanorods were also synthesized with several sulfur sources by the method. X-ray diffraction (XRD) shows that the alloyed ternary CdSxSe1-x nanorods are highly crystalline, and no other phase was observed in these nanorods.