大洋粘土制备白炭黑后的铝回收实验研究

为了回收大洋粘土制备白炭黑后残液中的Al3 ,并获得氧化铝超细粉体,实验选用NH3.H2O为沉淀剂,在常温下采用沉淀法使残液中Al3 以氢氧化铝形式沉淀并去除其它杂质离子,然后将得到的沉淀在1200℃灼烧,保温1h。利用IR和XRD测试了产物的物相组成和结构,证实实验可以获得纯度较高的α-Al2O3;而SEM和粒度分析结果显示产物粒度细小,部分颗粒可以达到纳米级;BET结果显示Al2O3的比表面积可达32m2/g。根据氧化铝结构和性能等优选的实验条件为大洋粘土的进一步开发利用提供了参考依据。     

利用高铝粉煤灰制备莫来石微晶玻璃的实验研究

以高铝粉煤灰为主要原料,采用粉末烧结法制备出莫来石微晶玻璃。X射线衍射分析显示,经1350~1550℃热处理后,制得的微晶玻璃的主晶相均为莫来石。扫描电镜分析表明,较高的温度下热处理有利于晶体的生长。微晶玻璃的理化性能如吸水率、气孔率、体积密度、抗折强度和化学稳定性,随热处理温度的不同而发生相应的变化。1500℃热处理2 h制得的微晶玻璃具有优良的理化性能,在工程和结构领域具有潜在的应用前景。     

Study on extracting alumina from fly ash by compound additive activation method

According to the chemical and mineral composition characteristics of the fly ash, alumina can be extracted from fly ash through the calcining method by using sodium carbonate and calcium carbonate additives. The effects on leaching rate of alumina have been investigated. The results showed that the fly ash can be activated effectively and the leaching rate of alumina can be improved to more than 92% through this method. The best process parameters were the ratio of raw materials, i.e. the material weight ratio of fly ash, calcium carbonate and sodium carbonate was 1.0：1.2：0.9. The activating temperature was 850℃-900℃, activating time was 3 h. This process has a potential application prospect and improves the value of comprehensive utilization of fly ash.     

X射线荧光光谱法测定重晶石中的硫酸钡方法研究

应用XRF可快速测定重晶石中钡元素的总量,但当测定硫酸钡含量时,由于样品中的碳酸钡计入钡量造成硫酸钡的测定结果不准确,铜、铅、锌等有色金属元素对熔样坩埚会造成损害,需要进行酸处理除去碳酸钡、铅等干扰。而样品经酸处理后不同样品的剩余量不同,造成熔剂与样品的比例不确定,也不能准确测定硫酸钡的含量,因此保证熔剂与样品比例一致是解决该问题的关键。本文优化了样品前处理、熔片制样和仪器工作条件,将一定量样品以10%盐酸和10%硝酸溶解,过滤除去碳酸钡、硫酸钙及铜、铅、锌等有色金属元素,未溶解样品在700℃下灼烧后以氧化铝补充到原取样量,实现了熔剂与样品比例一致,再以硝酸铵作氧化剂,溴化锂和碘化铵作脱模剂,1075℃熔融制片,即可用XRF准确测定硫酸钡的含量。本方法的相对标准偏差(RSD)小于0.4%,检出限为72μg/g,较ICP-OES等方法的检测周期短、干扰元素少,提高了测试效率和分析质量。     

Adsorption of Chromium(III), Nickel(II), and Copper(II) from Aqueous Solution by Activated Alumina

The possible use of activated alumina powder (AAP) as adsorbent for Cr(III), Ni(II), and Cu(II) from synthetic solutions was investigated. The effect of various parameters on batch adsorption process such as pH, contact time, adsorbent dosage, particle size, temperature, and initial metal ions concentration were studied to optimize the conditions for maximum metal ion removal. Both higher (molar) and lower (ppm) initial metal ion concentration sets were subjected to adsorption on AAP. Adsorption process revealed that equilibrium was established in 50 min for Cr(III) at pH 4.70, 80 min for Ni(II) at pH 7.00, and 40 min for Cu(II) at pH 3.02. Percentage removal was found to be highest at 55°C for Cr(III) and Ni(II) with 420 µm and 45°C for Cu(II) with 250‐µm particle size AAP. A dosage of 2 g for Cr(III), 8 g for Ni(II), and 10 g Cu(II) gave promising data in the metal ion removal. The adsorption process followed Langmuir as well as Freundlich models. The thermodynamics of adsorption of these metal ions on activated aluminum indicated that the adsorption was spontaneous and endothermic in nature. Present study indicates that AAP can act as a promising adsorbent for industrial wastewater treatment.     

废重整催化剂中铂的分光光度法的测定

分光光度法测定用于废氧化铝载体铂催化剂中铂含量。铂被还原成铂黑从杂质中分离出，用王水溶解形成六氯铂酸盐酸溶液，加入氯化亚锡形成橙黄色络合物溶液在４０３ｎｍ进行测定。对该方法的回收率，钼存在对测定的影响进行了研究，方法回收率９８～１０２％，在１０－６数量级，即使钼浓度与铂浓度相等并不影响铂的测定     

Late Jurassic intraplate extension in southern Central Asian Orogenic Belt: Evidence from Beidashan mafic rocks in AlxaSCIEI北大核心CSCD

阿拉善地块北缘晚中生代(晚侏罗世-早白垩世)时期发育有广阔的伸展盆地体系,其形成可能与陆内伸展作用有关。本文首次在阿拉善地块西北缘北大山陶来地区识别出一套晚侏罗世镁铁质-超镁铁质岩,对其进行系统的岩石学、年代学和地球化学研究,从而为该地区陆内伸展提供岩浆作用方面的证据。LA-ICP-MS锆石U-Pb定年结果表明,北大山陶来地区角闪辉长岩形成时代为155.7±4.6Ma(MSWD=1.5),即晚侏罗世。角闪辉长岩显示出高铝基性岩的地化特征,如低SiO 2(48.0%~52.5%),高Al 2O 3(15.3%~18.2%)、MgO(8.78%~10.6%)和CaO(12.8%~16.7%)。此外,它们还显示出高的Mg#(72~82)、Cr(295×10^(-6)~960×10^(-6))和Ni(97.4×10^(-6)~186×10^(-6)),N-MORB型和平坦的HREE配分形式、Eu正异常,较高的Nb/La比值,这些都表明其可能为软流圈地幔减压熔融产生的原始岩浆与壳幔过渡带中含斜长石堆晶岩相互作用后分离结晶的产物。富铝和富钙源区以及岩浆中高的水含量抑制斜长石早期成核与生长共同控制了高铝角闪辉长岩的形成。辉长岩表现出N-MORB型全岩地球化学特征和板内成因岩浆锆石特征(高Nb/Hf及低Hf/Th、Th/Nb),均揭示了阿拉善西北缘陶来地区晚侏罗世镁铁质-超镁铁质岩体是板内岩石圈伸展作用的产物。在古亚洲洋最终碰撞闭合后伸展基础上,蒙古-鄂霍茨克洋闭合与古太平洋俯冲后撤叠加作用引发了岩石圈伸展,并沿中亚造山带南缘多个古生代缝合带产出了194~124Ma多期镁铁质-超镁铁质岩。     

Availability of Bauxite Reserves

Based upon a large database, this paper analyzes the record of bauxite mine production, exploration success, and resource depletion and evaluates the availability of bauxite reserves in the near future. The record clearly shows that for the past 50 years world bauxite production rose by an annual increase of over 5% while per capita consumption rose during the same period by about 4%. Time trends of the world bauxite reserve life index (RLI); that is, known world reserves of a given year divided by world production of the same year, are episodic and seem to follow bauxite price cycles. The present-day RLI indicates adequate bauxite supply for about 180 years and is the same as it was in 1950. However, if an annual growth rate of 5% is considered, the currently known reserves will be exhausted within the next 20 years and the reserve base will be adequate for not more than 25 years. This scenario is based, of course, on the unrealistic assumption that future exploration efforts fail to discover additional reserves. Evaluation of the quality, in terms of bauxite signatures, and quantity of presently known bauxite prospects that may be mined in future suggests that there is sufficient potential for adequate bauxite supply for the next 20 to 25 years at least. Bauxite signatures cover a wide range of values that allows selection of the most favorable bauxite prospects for future mining, both in economic as well as environmental terms. Although, there is the general believe that the world abundance of bauxite resources will ensure sufficient supply to meet future demands significant additional reserves have to be discovered if exponential growth rates continue. As the question of future bauxite supply is subject to economic and geologic principles one has to take into consideration that increasing exploration maturity in many mineral provinces will make it difficult to locate additional bauxite reserves and that decreasing real commodity prices will influence the level of investment in bauxite exploration.     

Determination of the Trace Refractory Elements V, Nb and Ta in Environmental Samples by ICP-MS After Separation and Preconcentration with Nanometre-Sized Alumina Microcolumns Following Chemical Modification by Gallic Acid

Nanometre-sized alumina was chemically modified with gallic acid (GA) and used as a solid phase adsorption material for the determination of trace amounts of V, Nb and Ta in natural water, soil and stream sediment samples by inductively coupled plasma-mass spectrometry. The effects of pH, sample flow rate and volume, elution solution and interfering ions on the recovery of the analytes were investigated. The results showed that V, Nb and Ta could be adsorbed at pH 4.0 and recovered with 1 ml of 2.0 mol l^-1 HCl. Under optimised conditions, the adsorption capacity of GA-modified nanometre-sized Al₂O₃ was found to be 7.0, 8.9, 13.3 mg g^-1 for V, Nb and Ta, respectively. The limits of detection were as low as 0.25, 0.24 and 0.66 ng l^-1 for V, Nb and Ta, respectively with a concentration factor of fifty. The recovery of V, Nb and Ta for spiked water samples was between 85.7 and 116%. The developed method has also been applied to the determination of trace V, Nb and Ta in soil and stream sediment certified materials, and the determined values were in a good agreement with the certified values.     

A study on the preparation of fine and low soda alumina

A simple process to produce fine and low soda α-alumina (α-Al₂O₃) from a commercial grade aluminium trihydroxide (gibbsite, Al(OH)₃) produced by KC Corporation Ltd was developed. There are two options for this process with the first one producing low soda α-alumina (< 0.05% Na₂O) having a mean particle size of 50 μm. The second option yields a fine product with a mean size of less than 10 μm. In the first option, a plant aluminium trihydroxide containing 0.20% Na₂O was first fluidized with nitrogen at 400–600 °C to yield an amorphous activated alumina. This intermediate product was then treated with acetic or oxalic acid, washed with water and heated to 1200 °C to form calcined α-alumina, having a Na₂O content of less than 0.05%. A 20 min leaching using 0.2 M acetic or oxalic acid could yield an alumina product containing 0.04% Na₂O. In the second option, a new technique for the preparation of fine and low soda α-alumina was evaluated using an attrition mill working also as a leaching vessel at 80 °C. Fine (< 10 μm in mean particle size) and low soda (< 0.04% Na₂O) alumina was produced by a 20 min leaching step with 0.2 M acetic acid and concurrent attrition milling.