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Jacques Yvon Jean-Maurice Cases Frédéric Villiéras Laurent Michot Fabien Thomas 《Comptes Rendus Geoscience》2002,334(9):717-730
By nature minerals are heterogeneous materials for many of their properties. These properties also vary according to composition and structure fluctuations, compared to definitions. Technical minerals are used in applications where their performances depend on intrinsic properties and processing conditions. It is possible to base rankings on simple criteria, allowing estimating the abilities of minerals for each utilisation. The research of the corresponding mechanisms concerns the molecular level. These questions are discussed for kaolins, raw materials for baked clays, talqueous materials and montmorillonites. To cite this article: J. Yvon et al., C. R. Geoscience 334 (2002) 717–730. 相似文献
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不同层间堆垛密度的HDTMA^+柱撑蒙脱石对对硝基苯酚的吸附实验研究 总被引:2,自引:0,他引:2
本文以阳离子表面活性剂(十六烷基三甲基溴化铵,HDTMAB)为柱撑剂,在不同浓度条件下(0.5~2.5CEC)制备了层间季铵盐离子呈单层平卧、双层平卧和倾斜双层排列的HDTMA 柱撑蒙脱石,并研究了具有不同层间结构的HDTMA 柱撑蒙脱石对对硝基苯酚的吸附能力以及溶液pH值、温度、对硝基苯酚初始浓度等因素对HDTMA 柱撑蒙脱石吸附性能的影响。实验结果表明,HDTMA 柱撑蒙脱石对对硝基苯酚的吸附能力随着介质溶液pH值的升高而升高,这主要受对硝基苯酚在不同pH条件下的离子化程度影响;HDTMA 柱撑蒙脱石对对硝基苯酚的吸附能力随着介质溶液温度的升高而降低,说明吸附反应是一个放热过程。同时,从单层平卧→双层平卧→倾斜双层,HDTMA 柱撑蒙脱石对对硝基苯酚的吸附能力明显提高。钠基蒙脱石和低堆垛密度(单层平卧、双层平卧)的HDTMA 柱撑蒙脱石对对硝基苯酚的吸附等温线呈S型,而高堆垛密度(倾斜双层)的HDTMA 柱撑蒙脱石对对硝基苯酚的吸附等温线呈Linear型,表明前者以表面吸附为主,后者以分配作用为主。 相似文献
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