Crystal-Melt Separation and the Development of Isotopic Heterogeneities in Hybrid Magmas

If a magma is a hybrid of two (or more) isotopically distinctend-members, at least one of which is partially crystalline,separation of melt and crystals after hybridization will leadto the development of isotopic heterogeneities in the magmaas long as some of the pre-existing crystalline material (antecrysts)retains any of its original isotopic composition. This holdstrue whether the hybridization event is magma mixing as traditionallyconstrued, bulk assimilation, or melt assimilation. Once a magma-scaleisotopic heterogeneity is formed by crystal–melt separation,it is essentially permanent, persisting regardless of subsequentcrystallization, mixing, or equilibration events. The magnitudeof the isotopic variability resulting from crystal–meltseparation can be as large as that resulting from differentialcontamination, multiple isotopically distinct sources, or insitu isotopic evolution. In one model, a redistribution of one-thirdof the antecryst cargo yielded a crystal-enriched sample with⁸⁷Sr/⁸⁶Sr of 0·7058, whereas the complementary crystal-poorsample has ⁸⁷Sr/⁸⁶Sr of 0·7068. In other models, crystal-richsamples are enriched in radiogenic Sr. Isotopic heterogeneitiescan be either continuous (controlled by the modal distributionof crystals and melt) or discontinuous (when there is completeseparation of crystals and liquid). The first case may be exemplifiedby some isotopically zoned large-volume rhyolites, formed bythe eruptive inversion of a modally zoned magma chamber. Inthe latter case, the isotopic composition of any (for example)interstitial liquid will be distinct from the isotopic compositionof the bulk crystal fraction. The separation of such an interstitialliquid may explain the presence of isotopically distinct late-stageaplites in plutons. Crystal–melt separation provides anadditional option for the interpretation of isotopically zonedor heterogeneous magmas. This option is particularly attractivefor systems whose chemical variation is otherwise explicableby fractionation-dominated processes. Non-isotopic chemicalheterogeneities can also develop in this fashion. KEY WORDS: isotopic heterogeneity; zoning; hybrid magma; crystal separation; Sr isotopes; aplite; rhyolite     

海拉尔盆地贝尔凹陷兴安岭群储层粘土矿物组成及成因研究

油田注水开发是保持地层能量,提高采收率的有效手段.海拉尔地区由于粘土矿物含量高,在开发过程中储层遇水易泥化、坍塌,严重影响油气的有效开采.通过X射线衍射、偏光显微镜观察和扫描电镜分析,确定了海拉尔盆地贝16断块兴安岭群储层自上而下存在三种粘土矿物组合:蒙脱石 高岭石 (绿泥石)→高岭石 伊/蒙间层 伊利石 (绿泥石)→伊利石 绿泥石 绿/蒙间层 伊/蒙间层.粘土总量在9.1%～69.1%之间,由地层浅部到深部呈现由高到低的变化规律.详细研究了水敏性极强的钠蒙脱石及其间层矿物,认为凝灰物质的水解蚀变以及长石和中、酸性岩屑在成岩过程中的次生变化是造成海拉尔地区粘土含量高的主要因素.     

草莓红绿柱石(Pezzottaite)的晶体结构测定及其意义

利用CCD单晶衍射仪对草莓红绿柱石进行晶体结构测定,测定其空间群为R3c,并讨论了结构中Li 有序地置换Be2 造成c/a值的变化特征。晶体中发现复三方偏三角面体的负晶包裹体,其宏观对称属m,它与空间群Rc相对应,但与测出晶体结构的空间群有矛盾。X射线结构测定已否定了其空间群为Rm的看法。要解决草莓红绿柱石晶体空间群是否有对称中心(Rc或Rc)的问题,还需进一步将X射线结构的数据及其有关的电性实验结合分析。     

水晶包裹体的类型及成因综述

水晶中的包裹体是在水晶生长过程中被包裹在晶体内的由一相或多相物质组成的封闭系统。水晶中包裹体的形成与生长时的物化条件密切相关 ,而生长过程中的物化环境又直接影响了水晶的结晶习性。     

Structure cristalline d'une ménéghinite naturelle pauvre en cuivre,Cu0,58Pb12,72(Sb7,04Bi0,24)S24Crystal structure of a Cu-poor natural meneghinite,Cu0.58Pb12.72(Sb7.04Bi0.24)S24

Cu-poor meneghinite from La Lauzière Massif (Savoy, France) has the composition (electron microprobe) (in wt%): Pb 59.50, Sb 20.33, Bi 1.19, Cu 0.87, Ag 0.05, Fe 0.03, S 17.62, Se 0.05, Total 99.64. Its crystal structure (X-ray on a single crystal) was solved with R1=0.0506, wR2=0.1026, with an orthorhombic symmetry, space group Pnma, and a=24.080(5) Å, b=4.1276(8) Å, c=11.369(2) Å, V=1130.0(4) Å³, Z=4. Relatively to the model of Euler and Hellner (1960), this structure shows a significantly lower site occupancy factor for the tetrahedral Cu site (0.146 against 0.25). Among the five other metallic sites, Bi appears in the one with predominant Sb. Developed structural formula: Cu_0.15Pb₂(Pb_0.53Sb_0.47)(Pb_0.46Sb_0.54)(Sb_0.75Pb_0.19Bi_0.06)S₆; the reduced one: Cu_0.58Pb_12.72(Sb_7.04Bi_0.24)S₂₄. The formation of such a Cu-poor variety seems to be related to specific paragenetic conditions (absence of coexisting galena), or to crystallochemical constraints (minor Bi). To cite this article: Y. Moëlo et al., C. R. Geoscience 334 (2002) 529–536.     

压电双晶片双向大幅振动的探讨

通过压电陶瓷的逆压电效应对压电陶瓷双晶片在自动生产送料线上的应用研究，得出在二元系Ph(Ni1／3Nb2／3)O3-PhTiO3-PhZrO3的基础上作调整制作的压电双晶片。经运用在振动料斗上，作调频调幅控制。达到了压电双晶片振子结构，振子谐振频率为300Hz，当外加电压达300V时，振子偏转位移量大于1．7mm，故可作为一种理想的振动源。     

我国各地膨润土的热性质

对各地膨润土的热性质进行了考察，讨论了膨润土差热曲线和热失重的形态特征，以及膨润土热性质与其他物理化学性质的关系。研究表明，供试膨润土均可观察到三组吸热效应，部分样品可观察到一组放热效应。其中第一组吸热谷因层间所含有阳离子的种类和数量不同而呈现单谷或复谷两种不同的形态；根据第三吸热谷与放热峰这两个效应的峰间隔差和形态变化对供试膨润土进行属型划分简单易行。     

小秦岭金矿含金石英脉中石英晶体微形貌研究

利用微分干涉显微镜等手段对小秦岭金矿含金石英脉中不同成矿阶段的石英晶体微形貌进行了研究。石英晶体{101^-1}、{011^-1}、{101^-0}单形晶面上不同特征的微形貌对了解石英晶体的生长机理、生长速率、生长环境的变化及成矿溶液的过饱和度具有重要意义，同时也可提供成矿阶段划分及晶体生长时热力学条件的信息。     

苏北榴辉岩中水晶的形成时代及其对超高压变质岩折返的示踪意义

江苏东海水晶以其晶体粒大和产量巨大而闻名，在地质上也因其产于高压超高压变质带而独具特色。在对大别—苏鲁超高压变质带的区域成矿作用进行研究和对中国大陆科学钻探工程(CCSD)主孔岩心进行编录的过程中，认识到超高压带存在着超低压成矿现象，包括中国最主要的水晶矿床成矿带在内的许多矿床都可能是在超高压变质之后退变质结束阶段的超低压环境中形成的，对水晶进行流体包裹体的Rb-Sr等时线年代学研究，获得208Ma的等时线年龄，表明成矿时代为印支期。该年代可视为超高压变质带折返并经历了退变质之后而“稳定”下来的时间。     

时频测控技术的发展

目前，在所有的物理量中时间与频率标准的物理实现具有最高的准确度和稳定度，它们的发展不但在计量技术中，而且在几乎整个高科技领域中起着十分重要的作用。这方面的发展一直受到发达国家的高度重视。根据近年来与国外同行的技术交流和了解的情况，对时频测控技术的发展和影响等作了介绍。