双酶法制备低黏度辛烯基琥珀酸淀粉钠的工艺条件

对双酶法制备用作微胶囊壁材的低黏度辛烯基琥珀酸淀粉钠的工艺路线与工艺条件进行了研究。正交实验结果表明 ,在酯化淀粉乳质量浓度 2 0 %、每 g淀粉α 淀粉酶的用量为 6SKBU的条件下 ,影响产品性能的各因素中 ,糖化酶的用量对产品的DE值和流度的影响最大 ,各因素的重要性依次是 :糖化酶的用量、糖化酶作用时间、α 淀粉酶保温作用时间。最佳工艺条件是 :α 淀粉酶保温作用时间 4min ,每 g淀粉糖化酶用量 0 .2GAU ,糖化酶作用时间 2 .5h ,此时产品的DE值为 30 ,流度为 80左右     

Size and shape evolution of pores in a viscoplastic matrix under compression

The frequent use of soils and earth materials for hydraulic capping and for geo‐environmental waste containment motivated our interest in detailed modelling of changes in size and shape of macro‐pores to establish links between soil mechanical behaviour and concurrent changes in hydraulic and transport properties. The objective of this study was to use finite element analysis (FEA) to test and extend previous analytical solutions proposed by the authors describing deformation of a single macro‐pore embedded in linear viscoplastic soil material subjected to anisotropic remote stress. The FEA enables to consider more complex pore geometries and provides a detailed picture of matrix yield behaviour to explain shortcomings of approximate analytical solutions. Finite element and analytical calculations agreed very well for linear viscous as well as for viscoplastic materials, only limited for the case of isotropic remote stress due to the simplifications of the analytical model related to patterns and onset of matrix‐yielding behaviour. FEA calculations were compared with experimental data obtained from a compaction experiment in which pore deformation within a uniform modelling clay sample was monitored using CAT scanning. FEA predictions based on independently measured material properties and initial pore geometry provided an excellent match with experimentally determined evolution of pore size and shape hence lending credence to the potential use of FEA for more complex pore geometries and eventually connect macro‐pore deformation with hydraulic properties. Copyright © 2006 John Wiley & Sons, Ltd.     

An algorithm for detecting and estimating cycle slips in single-frequency GPS

An algorithm for detecting outliers and cycle slips in single-frequency GPS using a 3rd order polynomial model of the Kalman filter and for estimating the ambiguity by using optimal wavelet is presented in this paper. It is applicable to the carrier phase measurement with sample rate of one per second. The results of calculation with the GPS data aboard satellite Topex on 1995 June 22 show that the algorithm is so efficient that it can accurately estimate the ambiguity even for signals interrupted by a few seconds.     

Upwelling and river runoff as sources of dissolved nitrous oxide to the Alsea estuary,Oregon

Surface waters of Alsea Bay, an unpolluted estuary on the Oregon coast, were analysed for nitrous oxide, nitrate and nitrite on a weekly or biweekly basis during the summer of 1979. The estuary was found to be a variable source of N₂O to the atmosphere. Large and rapid increases in the concentrations of N₂O, NO₃^?, and NO₂^? occurred at the beginning of the sampling period and are attributed to the influx of nutrient-rich upwelling water into the estuary with the tide. The subsequent decline in concentrations of nitrate, nitrite and nitrous oxide over the remainder of the summer is attributed to a decrease in upwelling intensity, a decline in nitrification rates and to assimilatory nitrate reduction. Measurements of nitrous oxide at six stations along the Alsea River were also made in September and October before and after the onset of the rainy season. Samples taken after flood conditions were established were systematically 50% higher than pre-flood samples. The data suggest that soil runoff results in elevated concentrations of N₂O in rivers.     

凤太矿田层控铅锌(铜)矿床的成矿物质来源探讨

秦岭凤太矿田层控铅锌(铜)矿床的金属物质、硫和成矿溶液主要来自深部基底的岩石,属海底喷流—沉积成因矿床。从这一理论认识出发可进一步分析控矿地质条件及今后在该区有效地寻找同类矿床。     

Nitrogen uptake,ammonium oxidation and nitrous oxide (N2O) levels in the coastal waters of western Cook Strait,New Zealand

Vertical measurements of $\text{NH}{}_4{}^{\mathrm{+}}$, $\text{NO}{}_3{}^{\mathrm{?}}$ and N₂O concentrations, $\text{NO}{}_3{}^{\mathrm{?}}$ and $\text{NH}{}_4{}^{\mathrm{+}}$ uptake, and $\text{NH}{}_4{}^{\mathrm{+}}$ oxidation rates were measured at 5 sites in western Cook Strait, New Zealand, between 31 March and 3 April 1983. Nitrate increased with depth at all stations reaching a maximum of 10.5 μg-atom $\text{NO}{}_3{}^{\mathrm{?}}\text{N l}{}^{\mathrm{?1}}$ at the most strongly stratified station whereas $\text{NH}{}_4{}^{\mathrm{+}}$ was relatively constant with depth at all stations (～0.1 μg-atom $\text{NH}{}_4{}^{\mathrm{+}}\text{N l}{}^{\mathrm{?1}}$). The highest rates of $\text{NH}{}_4{}^{\mathrm{+}}$ oxidation generally occurred in the near surface waters and decreased with depth. N₂O levels were near saturation with respect to the air above the sea surface and showed no obvious changes during 24 h incubation. $\text{NH}{}_4{}^{\mathrm{+}}$ oxidation by nitrifying bacteria may account for about 30% of the total $\text{NH}{}_4{}^{\mathrm{+}}$ utilization (i.e. bacterial+agal) and, assuming oxidation through to $\text{NO}{}_3{}^{\mathrm{?}}$, may supply about 40% of the algal requirements of $\text{NO}{}_3{}^{\mathrm{?}}$ in the study area. These results suggest that bacterial nitrification is of potential importance to the nitrogen dynamics of the western Cook Strait, particularly with respect to the nitrogen demands of the phytoplankton.     

Motive force of Qinghai-Tibet Plateau moving to east

A calculation formula on spherical pattern of Qinghai-Tibet plateau moving model is established. Tibet massif moves norward by east in speed of 28 mm/a, Ganshu-Qinghai massif moves to northeast in speed of 15 mm/a, Qomolangma Feng moves northward by a few east in speed of 35 ～42 mm/a. The low latitude perimeter is longer than the nigh latitude perimeter. When the Tibet massif moves northward, its latitude perimeter must be contracted and the Tibet massif must move eastward by Coriolis. Coriolis force is inertial in earth rotation. It makes the fall body turning to east and the rising block turning westward. In the Northern Hemisphere, it makes the northward body turning to east and the southward block turning to west.This is the reason why the tectonic zones of western Pacific are different from those of eastern Pacific.     

Time scale of an early to mid-Paleozoic orogenic cycle of the long-lived Central Asian Orogenic Belt, Inner Mongolia of China: Implications for continental growth

We present a detailed, new time scale for an orogenic cycle (oceanic accretion–subduction–collision) that provides significant insights into Paleozoic continental growth processes in the southeastern segment of the long-lived Central Asian Orogenic Belt (CAOB). The most prominent tectonic feature in Inner Mongolia is the association of paired orogens. A southern orogen forms a typical arc-trench complex, in which a supra-subduction zone ophiolite records successive phases during its life cycle: birth (ca. 497–477 Ma), when the ocean floor of the ophiolite was formed; (2) youth (ca. 473–470 Ma), characterized by mantle wedge magmatism; (3) shortly after maturity (ca. 461–450 Ma), high-Mg adakite and adakite were produced by slab melting and subsequent interaction of the melt with the mantle wedge; (4) death, caused by subduction of a ridge crest (ca. 451–434 Ma) and by ridge collision with the ophiolite (ca. 428–423 Ma). The evolution of the magmatic arc exhibits three major coherent phases: arc volcanism (ca. 488–444 Ma); adakite plutonism (ca. 448–438 Ma) and collision (ca. 419–415 Ma) of the arc with a passive continental margin. The northern orogen, a product of ridge-trench interaction, evolved progressively from coeval generation of near-trench plutons (ca. 498–461 Ma) and juvenile arc crust (ca. 484–469 Ma), to ridge subduction (ca. 440–434 Ma), microcontinent accretion (ca. 430–420 Ma), and finally to forearc formation. The paired orogens followed a consistent progression from ocean floor subduction/arc formation (ca. 500–438 Ma), ridge subduction (ca. 451–434 Ma) to microcontinent accretion/collision (ca. 430–415 Ma); ridge subduction records the turning point that transformed oceanic lithosphere into continental crust. The recognition of this orogenic cycle followed by Permian–early Triassic terminal collision of the CAOB provides compelling evidence for episodic continental growth.     

从准层序到米级旋回——层序地层学与旋回地层学相互交融的纽带

层序地层学的基本单位是层序。准层序和准层序组构成了层序的基本结构单元,它们在层序内有规律的空间叠置样式是识别体系域的客观标准。准层序被定义为以海泛面为界的向上变浅序列,但是准层序是一个比较松散的概念,存在问题是对其成因机制研究不足。米级旋回作为旋回地层学的基本单位,定义为数厘米至数米厚的向上变浅的岩相序列,是高频率海平面升降变化的产物,其形成时限为相应的米兰柯维奇天文旋回周期。作为旋回地层学的基本单位,米级旋回以其明确的沉积学涵义和有规律的天文成因机制,是对层序地层学概念体系中的"准层序"的良好补充,对其进行深入研究具有重要的理论意义和应用价值。从准层序到米级旋回这一概念体系的演变,代表了层序地层学与旋回地层学相互交融的纽带。最后介绍旋回地层学的最新进展亚米兰柯维奇旋回,它对精确数字定年具有重大意义。     

车镇凹陷上古生界高分辨率层序地层研究

以高分辨率层序地层学原理为指导,利用测井、岩芯和录井等资料,对车镇凹陷上古生界不同级次基准面旋回进行了高分辨率层序划分。将上古生界划分为2个超长期、7个长期、16个中期和45个短期基准面旋回,精细对比研究了短期、中期和长期基准面旋回。其中,短期基准面旋回可分为2大类3种亚类,并区别出A型、B型不对称短期基准面旋回和C型对称性短期基准面旋回,总结了它们的结构特征、形成条件、岩性岩相组成;通过研究不同沉积体系下中期、长期基准面旋回特点,得出中期、长期基准面旋回的特点和发育特征,区别出不同沉积环境下层序界面特点;分析了研究区内超长期基准面旋回特征,综合分析认为车镇凹陷超长期基准面旋回以下降半旋回为主。