济宁市嘉祥县石灰岩矿山地质环境评价与治理

在对嘉祥县石灰岩矿进行地质灾害危险性评估、矿山环境地质问题评价的基础上,建立了一套评价体系,其中地质灾害危险性评估分为2个评价指标,矿山环境地质问题评价分为2种要素3个指标,同时将矿山恢复治理难易程度也作为一个评价因子。评价过程中对各指标危害性大、中、小程度均单独赋值,然后将各指标的分值进行叠加,确定出矿山环境地质问题的等级,将概划出的13个评价单元分为极差、差、一般3个区。提出了强化矿山管理、植树造林、科学避让、修建拦水坝等保护与治理措施及建议。     

淮山提取液替代羧甲基纤维素钠作为酸奶稳定剂的效果研究

采用正交试验等方法对淮山提取液（DB-Ext）代替羧甲基纤维素钠(CMC)作为调配型酸奶稳定剂的效果进行了初步探讨。结果表明以原料的6.0倍水量在110℃的温度条件下，提取40min，所得的淮山提取液的粘度为3500mPa     

Study on numerical simulation to water lowering in an open coal mine digging

In view of the situation of excavation of open coal mine for the underground water disaster,we should carry out simulation studies for the numerical value of the water lowering project and improve the accuracy and the level of the water lowering project.On the basis of the hydrological geological conditions of certain open mine digging,a more reasonable seepage numerical model was built according to MODFLOW.It was simulated in advance that the process of the confined water level descending with the time,and combining with the actual observations to test the correctness of the model.The calculation showed that the results coincided well with the results of actual measurement.Based on this,different water lowering numerical simulations were built for the open coal mine digging.It could be simulated and forecast that the changes of the groundwater level in drainage process within and outside the mine pit,and it was quantitatively assessed that the possible water lowering result of the opencast water drainage process,which provide an important basis for the actual water lowering project and the possible project disposal.     

Design of 2-M to 6-M Liquid Mirror Containers

A new design is proposed for large (up to 6-m) liquid mirror containers. The design uses Kevlar, foam and aluminum, as in previous designs, but with a different configuration that makes the container lighter, stronger and more rigid. The results of finite element analysis are presented, consisting in the deformations due to temperature changes and to weight, and in the security factor for each material when maximum constraints are applied. Tilt rigidity is also analyzed. They show that the composite material construction technique gives a good performance up to 6 m diameters. The figures and tables contained in this paper can be used as recipes to build containers having diameters between 2 and 6 m. This revised version was published online in July 2006 with corrections to the Cover Date.     

碱消解-高效液相色谱-电感耦合等离子体质谱法测定生物样品中的甲基汞和乙基汞

建立了碱消解-高效液相色谱-电感耦合等离子体质谱联用系统测定生物样品中甲基汞(MeHg)与乙基汞(EtHg)的分析方法。为提高灵敏度,选用微流量的PFA雾化器,在优化的检测条件下,MeHg及EtHg检出限可达到0.036μg/L和0.03μg/L;线性范围达到4个数量级,两条工作曲线线性相关系数为1。对1.78μg/L MeHg、1.65μg/L EtHg的混合标准溶液重复测定7次,色谱峰面积的相对标准偏差(RSD)分别为1.79%和1.44%。对标准物质BCR 464(金枪鱼)的分析结果表明,测定值与标准值基本吻合,但略低于标准值;甲基汞和乙基汞的加标回收率分别为85.9%和84.5%。高效液相色谱与质谱联用技术的高灵敏度和低检出限能够满足生物样品中汞形态定量分析的要求。     

江西省德兴铜矿矿区重金属元素的环境效应

本文系统研究了德兴铜矿排石场和尾砂库的环境问题,以环境介质（水土植物）中重金属元素含量为研究对象,论述矿区重金属的环境效应。研究结果表明祝家村低品位矿石堆浸场淋滤产生的酸性废水是造成大坞河流域重金属污染的主要来源。大坞河上游水体中Cu元素含量高达14506μg/L,是国家Ⅲ级水标准的14倍之多,Zn元素含量高达2938μg/L,是国家Ⅲ级水标准的2.9倍,同时pH值在3~4范围内;到中下游水体中Cu元素含量减小到几千到几百μg/L,水质有所改善。大坞河沿岸上游和中游土壤重金属含量受河水影响,随着与河岸距离的增加而减小。同时水稻中Pb元素含量是国家粮食标准的2倍。推测4#尾砂库尾砂表层氧化带深度大于80cm;而1#尾砂库库内尾砂中氧化带估计在0~25cm处。推测两个尾砂库产酸能力小于酸中和能力,故坝底水中pH值在7左右,对周围水体影响较小。与4#尾砂库距离近的石墩头村稻田表层土壤中Cu、Mo元素含量较高,远离尾砂库土壤中重金属含量降低。同时4#尾砂库周围土壤中Cd、Pb、Cu元素的吸附态、碳酸盐态比例在20%左右,因而在酸性环境下较容易被植物吸收。1#尾砂库矿建村种植的小白菜中Pb元素含量超过国家蔬菜标准的4倍,Cu、Pb、Zn元素含量严重超过背景值。     

Case history of controlling a landslide at Panluo open-pit mine in China

Controlling of landsides safely and economically is a great challenge to mine operators because landslides are major geological problems especially in open-pit mines. In this paper, a case history at Panluo open-pit mine is presented in detail to share the experiences and lessons with mine operators. Panluo open-pit mine is located in the southwestern Fujian province of China. It is the largest open-pit iron mine in the Fujian province and was planned in 1965 and is in full operation from 1978. In July 1990, an earthquake of magnitude 5.3 in Taiwan Strait and big rainstorms impacted the mine slope, causing tension cracks and rather large-scale failures, and forming a U-shaped landslide. Total potential volume was estimated to be up to 1.0 × 10⁶ m³. This directly threatened the mine production. In order to protect the mine production and the dwellers’ safety around, a dynamic comprehensive method was implemented including geotechnical investigations, in-situ testing and monitoring, stability analysis, and many mitigation and preventive measures. These measures slowed down the development and further occurrence of the landslide. The results showed that the landslides were still active, it was slowed with the control measures and moved rapidly with rainfall and mining down. However, no catastrophic accidents occurred and the pit mining was continued till it was closed at the elevation of 887 m in 2000. As a successful case of landslide control at an open-pit mine for 10 years, this paper reports the controlling measures in details. These experiences of landslide control may be beneficial to other similar mines for landslide control.     

Damage to surface structures due to underground coal mine blasting: apprehension or real cause?

Investigations were carried out at three underground coal mines in India to study the response of surface structures to underground blasting and the likelihood of damage to the structures. The structures in the vicinity of the underground blasting area were single and multistoried residential houses. The amplitudes of vibration due to underground blasting were monitored simultaneously on the ground surface near the foundation of the structures and on various floors of the structures. The vibrations were also monitored near the important surface installations. It was observed that the magnitude of vibration in structures decreased with the increase in the height of the structures. The frequency of blast vibration from underground blasting was higher than the natural frequency of the structures. Little energy was transmitted into the structures, which caused reduction in the vibration level in the structures. The reduction in the vibration levels was up to 45% in the houses. It indicates that the dominant frequency of blast vibration plays an important role in persistence of vibration and its amplification or reduction characteristics in the structures. This paper deals with the effect of the vibrations on structures/houses standing above the blasting faces in underground workings and their potential to likely damage to the structures at different Indian geo-mining conditions.     

Trace Element Partitioning and Accessory Phase Saturation during H2O-Saturated Melting of Basalt with Implications for Subduction Zone Chemical Fluxes

Experimental phase equilibrium and trace element partitioningdata are reported for H₂O-saturated mid-ocean ridge basalt at2·5 GPa, 750–900°C and oxygen fugacities atthe nickel–nickel oxide buffer. Garnet, omphacite andrutile are present at all temperatures. Amphibole and epidotedisappear as residual phases above 800°C; allanite appearsabove 750°C. The Na–Al-rich silicate glass presentin all run products is likely to have quenched from a supercriticalliquid. Trace element analyses of glasses demonstrate the importantcontrol exerted by residual minerals on liquid chemistry. Inaddition to garnet, which controls heavy rare earth elements(HREE) and Sc, and rutile, which controls Ti, Nb and Ta, allanitebuffers the light REE (LREE; La–Sm) contents of liquidsto relatively low levels and preferentially holds back Th relativeto U. In agreement with previous experimental and metamorphicstudies we propose that residual allanite plays a key role inselectively retaining trace elements in the slab during subduction.Experimental data and analyses of allanite-bearing volcanicrocks are used to derive a model for allanite solubility inliquids as a function of pressure, temperature, anhydrous liquidcomposition and LREE content. The large temperature dependenceof allanite solubility is very similar to that previously determinedfor monazite. Our model, fitted to 48 datapoints, retrievesLREE solubility (in ppm) to within a factor of 1· 40over a pressure range of 0–4 GPa, temperature range of700–1200°C and for liquids with anhydrous SiO₂ contentsof 50–84 wt %. This uncertainty in LREE content is equivalentto a temperature uncertainty of only ± 27°C at 1000K, indicating the potential of allanite as a geothermometer.Silicic liquids from either basaltic or sedimentary protolithswill be saturated in allanite except for Ca-poor protolithsor at very high temperatures. For conventional subduction geothermsthe low solubility of LREE (+ Th) in liquids raises questionsabout the mechanism of LREE + Th transport from slab to wedge.It is suggested either that, locally, temperatures experiencedby the slab are high enough to eliminate allanite in the residueor that substantial volumes of H₂O-rich fluids must pass throughthe mantle wedge prior to melting. The solubility of accessoryphases in fluids derived from subducted rocks can provide importantconstraints on subduction zone thermal structure. KEY WORDS: subduction; experimental petrology; allanite; solubility; supercritical liquid; eclogite