A MESO-β SCALE SIMULATION OF THE EFFECTS OF BOREAL FOREST ECOSYSTEM ON THE LOWER ATMOSPHERE

Based on the Intensive Field Campaign(IFC-1)data of Boreal Ecosystem-Atmosphere Study(BOREAS).a three-dimensional meso-β scale model is used to simulate the effect of boreal forests onthe lower atmosphere.A fine horizontal resolution of 2 km×2 km is used in order to distinguish thevegetative heterogeneity in the boreal region.A total of 20×25 grid points cover the entire sub-modeling area in BOREAS' South Study Area(SSA).The ecosystem types and their coverage ineach grid square are extracted from the North American Land Cover Characteristics Data Base(NALCCD)generated by the U.S.Geographical Survey(USGS)and the University of Nebraska-Lincoln(UNL).The topography of the study area is taken from the Digital Elevation Map(DEM)of USGS.The model outputs include the components of the energy balance budget within the canopyand at the ground.the turbulence parameters in the atmospheric boundary layer and the wind.temperature and humidity profiles extending up to a height of 1500 m.In addition to the fine timeand spatial step,the unique feature of the present model is the incorporation of both dynamic andbiological effects of the Boreal forest into the model parameterization scheme.The model resultscompare favorably with BOREAS' IFC-1 data in 1994 when the forest was in the luxuriant growingperiod.     

微型氢化物发生装置在冷原子吸收分光光度法测汞中的应用

采用微型氢化物发生装置-冷原子吸收分光光度法测定了焊锡料及纽扣电池中的汞。在酸性介质中,用硼氢化钾将汞离子还原为汞原子,用载气将汞蒸气导入石英管,原子吸收分光光度计在波长253.7 nm处进行测定。选择了实验条件,对共存离子的干扰等进行了考察。方法的检出限为0.34 ng/mL,11次测定的相对标准偏差(RSD)小于6%,加标回收率为94.4%~104.7%。     

分光光度法测定海洋河弧菌510脂多糖

本文研究了直接测定海洋河弧菌 (vibrio fluvailis) 5 10脂多糖的分光光度法。利用 1,9-二甲基亚甲蓝 (DMB) ,在适当条件下同脂多糖发生染色反应 ,在 5 5 0 nm波长下 ,反应体系的吸光值同脂多糖含量呈线性相关。相关系数为 0 .9993,最低检出限为 10 μg/m L,相对标准偏差为 1.6 2 ,平均回收率为 (10 5± 2 .18) %。     

海水中液-固界面的台阶型动力学曲线 Ⅰ.动力学曲线之台阶的消长和变化规律

对海水中Zn(Ⅱ),Ca(Ⅱ),Cd(Ⅱ)与高岭石、伊利石和蒙脱石等粘土矿物;无定形水合氧化铁、α-FeOOH等铁的水合氧化物;δ-MaO_2,γ-MnOOH,水锰矿等锰的水合氧化物等30个左右实验体系的液-固界面台阶型动力学曲线进行了系统的实验测定和全面的条件研究。在实验测定上提出两种方法、互为校核。对动力学曲线之台阶的消长和变化规律作了系统研究,确定主要影响因素是:金属离子初始浓度、固体交换剂量、体系的pH值和温度,以及搅拌速度等。     

Study on the characteristics of the marine boundary layer in the Equatorial Pacific

ＳｔｕｄｙｏｎｔｈｅｃｈａｒａｃｔｅｒｉｓｔｉｃｓｏｆｔｈｅｍａｒｉｎｅｂｏｕｎｄａｒｙｌａｙｅｒｉｎｔｈｅＥｑｕａｔｏｒｉａｌＰａｃｉｆｉｃ￥ＺｈａｎｇＺｉｙｕａｎｄＺｈｏｕＭｉｎｇｙｕ（ＲｅｃｅｉｖｅｄＡｕｇｕｓｔ２１，１９９３；ａｃｃｅｐｔｅｄ...     

“暖池”表层对大气局地强迫的响应特征

利用湍流动能垂直混合模式和ＴＯＧＡ－ＣＯＡＲＥ加强观测期的观测资料,对“暖池”上混合层的垂直混合过程进行数值试验和数值模拟,分析表层温度、盐度的变化特征。结果表明：ＴＫＥ模式可以较好地模拟混层,尤其是表层温度、盐度对大气局地强迫的响应;太阳辐射是热源,感热、潜热通量等会造成“暖池”上混合层的温度降低,“暖池”对大气释放热量;降水有利于“淡水盖”形成和维持,从则使层结稳定,ＳＳＴ升高。但在气温低于海     

Calculation of Environmental Capacity of Petroleum Hydrocarbon in Jiaozhou Bay

The method has been established to calculate the environmental capacity (ECo),surplus environment capacity (SECo) of water with respect to marine petroleum hydrocarbons associated with oil (PHAOs) and the self-purification capacity (SPCo) of main self-purification process to PHAOs in the Jiaozhou Bay, China, according to the dynamic model for distribution of marine PHAOs among multiphase environments. The variation of concentration of PHAOs in the Jiaozhou Bay is well simulated by the dynamic model. Based on the model.the ECo, SECo of water with respect to PHAOs in the Jiaozhou Bay were calculated during the last 10 years under the first-class and second-class quality standard requirement, according to SPCoof main self-purification process to PHAOs. The results show that about 200 tons of PHAOs could be discharged into the Jiaozhou Bay for maintaining the first class seawater quality standard, and about 600 tons of PHAOs for the second class seawater quality standard later.     

围隔实验中海洋浮游植物对石油烃污染物中正构烷烃的生物富集

本文应用海洋围隔生态实验研究了浮游植物对石油烃污染物生物富集动力学过程 ,提出了“水相差法”测定海洋浮游植物体内石油烃浓度 ,以及包括石油烃挥发和生物生长等影响因素的石油烃生物富集动力学模型 ,并利用非线性拟合技术得到了海洋浮游植物对 0 #柴油 WAF中正构烷烃的生物富集动力学参数 kup,kel和 BCFPOC,结果与 Kováts色谱保留指数具有很好的相关性 ,与利用生物分析平衡法测定的文献数据基本一致。本模型及实验方法简便可靠 ,可在现场实验中广泛应用 ,得到的动力学参数应用于多介质环境模型和生态动力学模型 ,用以研究石油烃污染物中正构烷烃在海洋环境中的迁移变化规律     

On the pH-dependent formation constants of iron(III)-sulfur(IV) transient complexes

An experimental study is described of Fe(III)-S(IV) formation constants measured as a function of pH (1–3), ionic strength (0.2–0.5 M) and [Fe(III)] _T (2.5–5.0×10^–4 M) using a continuous-flow spectrophotometric technique to make observations 160 ms after mixing. Preliminary experiments using pulse-accelerated-flow (PAF) spectrophotometry to measure rate constants on a microsecond timescale are also described. The conditional formation constant at 25 °C can be modeled with the following equation: {ie307-1} where {ie307-2}K ₇ andK ₈ can be interpreted as intrinsic constants for the coordination of HSO ₃ ^– by FeOH²⁺ and Fe³⁺, respectively, but until further evidence is obtained they should be regarded as fitting constants. PAF spectrophotometry showed that the initial reaction of Fe(III) with S(IV) (pH 2.0) is characterized by a second-order rate constant of 4×10⁶ M^–1 s^–1 which is comparable to rate of reaction of FeOH²⁺ with SO ₄ ^2– . However, the PAF results should be regarded as preliminary since unexpected features in the initial data indicate that the reaction may be more complex than expected.     

邻苯二酚螯合树脂的合成及水样中铝的测定

合成并表征了新螯合树脂———邻苯二酚螯合树脂(XAD-2-Catechol),研究了XAD-2-Catechol吸附铝的特性和茜素红-铝的显色反应,在pH4.5的HAc-NaAc缓冲介质中,茜素红和铝(Ⅲ)反应生成红色络合物,λm ax=500 nm,铝的含量在0-50μg/25 mL内符合比耳定律。建立了邻苯二酚螯合树脂分离/富集-茜素红分光光度法测定天然水样中铝的新方法,对水样中铝形态进行测定,结果满意。