全文获取类型
收费全文 | 1133篇 |
免费 | 290篇 |
国内免费 | 620篇 |
专业分类
测绘学 | 9篇 |
大气科学 | 65篇 |
地球物理 | 127篇 |
地质学 | 1533篇 |
海洋学 | 135篇 |
天文学 | 6篇 |
综合类 | 119篇 |
自然地理 | 49篇 |
出版年
2024年 | 10篇 |
2023年 | 30篇 |
2022年 | 38篇 |
2021年 | 53篇 |
2020年 | 51篇 |
2019年 | 68篇 |
2018年 | 58篇 |
2017年 | 65篇 |
2016年 | 84篇 |
2015年 | 83篇 |
2014年 | 148篇 |
2013年 | 131篇 |
2012年 | 159篇 |
2011年 | 117篇 |
2010年 | 104篇 |
2009年 | 77篇 |
2008年 | 93篇 |
2007年 | 66篇 |
2006年 | 71篇 |
2005年 | 61篇 |
2004年 | 47篇 |
2003年 | 48篇 |
2002年 | 48篇 |
2001年 | 30篇 |
2000年 | 41篇 |
1999年 | 34篇 |
1998年 | 27篇 |
1997年 | 42篇 |
1996年 | 22篇 |
1995年 | 19篇 |
1994年 | 7篇 |
1993年 | 25篇 |
1992年 | 16篇 |
1991年 | 12篇 |
1990年 | 14篇 |
1989年 | 9篇 |
1988年 | 4篇 |
1987年 | 7篇 |
1986年 | 7篇 |
1985年 | 9篇 |
1984年 | 3篇 |
1983年 | 2篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1978年 | 1篇 |
排序方式: 共有2043条查询结果,搜索用时 125 毫秒
1.
2.
《Planetary and Space Science》2002,50(9):871-876
C10H6-Fe+ complexes were observed by Fourier transform mass spectrometry by Marty et al. (Chem. Phys. Lett. 256 (1996) 669). In this article, we present the infra-red (IR) spectra of the two isomers calculated by ab initio methods of quantum chemistry. In the past, the same approach has predicted successfully unexpected features of the IR spectra of polycyclic aromatic hydrocarbon (PAH) cations which were confirmed by measurements in matrices (J. Phys. Chem. 98 (1994) 9187). The C10H6-Fe+ systems are models for larger PAHs-Fe+ complexes, which are believed to play a key rôle in space chemistry. 相似文献
3.
电感耦合等离子体发射光谱法同时测定玻璃中铝钙铁钾镁钠钛硫 总被引:2,自引:2,他引:0
通过选择分析谱线、处理样品方法和消除干扰因素等实验,建立了电感耦合等离子体发射光谱法同时测定玻璃中的Al2O3、CaO、Fe2O3、K2O、MgO、Na2O、TiO2和SO3的方法,克服了利用常规化学法测定玻璃中各氧化物步骤繁琐、耗时长、工作量大的不足。方法的回收率为95.0%~103.0%,精密度(RSD,n=10)为0.20%~1.72%。方法具有快速、简便、线性范围宽等优点,分析误差满足常规化学分析法的要求。用于钠钙硅玻璃及其制品的分析,结果令人满意。 相似文献
4.
5.
熔积岩指的是侵入、混合到未固结或弱固结的湿沉积物中的熔浆分解、原位形成的一类特殊岩石。正确地认识该类岩石,有利于增进人们对岩浆-水(沉积物)相互作用过程的理解,恢复古环境。在青海南部沱沱河地区发现了一套角砾为撕片状、锯齿状及浑圆状的安山岩,胶结物为铁硅质组合的特殊熔积岩。研究表明,该熔积岩的角砾为岩浆遇水后快速淬火、裂解的产物,铁硅质组合为海底喷气沉积形成的含铁建造;且安山岩与含铁建造发生混合时,含铁建造尚未固结。该套熔积岩的发现,改变了长期以来对开心岭铁矿为火山热液交代安山岩而形成的认识,对于在矿区寻找VMS型矿床、区域内寻找海底热水喷流沉积型矿床具有重要的启示意义。 相似文献
6.
新疆阿尔泰蒙库铁矿床的成矿流体及成矿作用 总被引:30,自引:8,他引:22
蒙库大型铁矿床赋存于上志留统—下泥盆统康布铁堡组变质火山-沉积岩系中,容矿岩石为石榴子石矽卡岩、变粒岩、浅粒岩和大理岩。矿体总体顺层分布,空间上与矽卡岩密切相关。研究表明,矽卡岩期石榴子石以发育玻璃质熔融包裹体、流体熔融包裹体和流体包裹体为特征,晚期矽卡岩阶段矿物中发育液相包裹体,变质期矿物中主要发育液相包裹体和含子矿物包裹体。矽卡岩期熔融包裹体的均一温度为1100℃,早期矽卡岩阶段流体包裹体均一温度变化于193~499℃,在450℃、350℃和230℃出现峰值。中期矽卡岩阶段均一温度变化于236~550℃,峰值为350℃。区域变质期均一温度介于132~513℃,在350℃、230℃和190℃出现峰值。流体包裹体的盐度w(NaCleq)介于1.23%~60.31%,流体密度变化于0.60~1.16g/cm3。石榴子石、石英和方解石的δ18OSMOW变化于0.2‰~8.4‰,δ18OH2O介于-5.1‰~5.33‰,δD为-127‰~-81‰,表明矽卡岩期成矿流体主要是岩浆水,混合少量大气降水;变质期流体主要为大气降水,为混合变质水。方解石δ13CPDB变化于-6.1‰~-2.3‰,表明流体中碳来自深部或地幔。成矿时代为早泥盆世早期(略晚于404~400Ma),成矿作用与矽卡岩的退化变质作用有关。 相似文献
7.
山东省济宁强磁异常区深部铁矿初步验证及其意义 总被引:8,自引:1,他引:7
山东省济宁磁异常是一个重、磁同源体,面积大于100 km2,磁异常峰值为3800nT。钻探验证在孔深1041.57~1796.54m位置发现铁矿体,矿体总厚度74.04~220m,磁性铁平均品位15.89~25.19%。矿石类型有条带状方解磁铁石英岩和条带状磁铁石英大理岩,矿石的主要组成矿物为石英、方解石、磁铁矿、磁赤铁矿、菱铁矿。矿体产于济宁岩群浅变质岩系中,矿床特征与条带状铁建造(BIF)铁矿或鞍山式铁矿有明显区别,铁矿成因类型属与千枚岩、变质中酸性火山岩、大理岩有关的沉积变质型铁矿床。该区铁矿资源潜力巨大。 相似文献
8.
Conventional understanding of the nitrogen cycle in marine sediments has changed in recent years with the discovery of an alternative pathway for ammonia oxidation via the reduction of manganese oxides (during anoxic nitrification). In anoxic sediments, the potential for manganese oxides to serve as oxidant for nitrification may be considerable yet previous work on manganese-rich sediments has suggested anoxic nitrification may not be significant. In this study, the potential for anoxic nitrification in a range of sediment types was investigated. Laboratory incubation of sediment from three sites on the Humber Estuary, a microbially diverse environment, showed anoxic accumulation of nitrate, nitrite and dinitrogen gas, with and without the addition of synthetic manganese oxides. Incubation experiments confirmed anoxic nitrification as microbially mediated, with heat-killed controls yielding negative results. The anoxic nitrification reaction significantly depleted ammonia concentrations, and occurred simultaneously with manganese-, iron- and sulphate reduction, and methanogenesis. Taken in conjunction with other studies, results suggest anoxic nitrification may not only be dependent on total manganese concentrations but on manganese dynamics. Anoxic nitrification may be explained as a non-steady state reaction, dependent on the recent stability of a sediment system. Physical perturbation of sediments may cause the redistribution and/or introduction of manganese oxides and promote anoxic nitrification. The significance and persistence of anoxic nitrification is likely to depend on the frequency and magnitude of sediment perturbation, which explains why the reaction varies so widely across studied sites, and why it may not occur in some manganese-rich sediment. 相似文献
9.
应用^57Fe穆斯堡尔谱学的方法研究了四个不同生长期合浦珠母贝铁的化学状态和Fe^2 /Fe^3 的值,它们的Fe^2 和Fe^3 的相对含量分别为4.1%~29.4%和76.6%~95.9%,Fe^2 /Fe^3 值的变化为0.043~0.42。3个月龄的Fe^2 /Fe^3 值大于10个月龄,从10个月龄到22个月龄的Fe^2 /Fe^3 值呈增加的趋势,这可能反映了不同生长期合浦珠母贝对不同价态的铁的需求。 相似文献
10.
Community Structure and Dynamics of Phytoplankton in the Western Subarctic Pacific Ocean: A Synthesis 总被引:1,自引:1,他引:1
The phytoplankton community in the western subarctic Pacific (WSP) is composed mostly of pico- and nanophytoplankton. Chlorophyll
a (Chl a) in the <2 μm size fraction accounted for more than half of the total Chl a in all seasons, with higher contributions of up to 75% of the total Chl a in summer and fall. The exception is the western boundary along the Kamchatka Peninsula and Kuril Islands and the Oyashio
region where diatoms make up the majority of total Chl a during the spring bloom. Among the picophytoplankton, picoeukaryotes and Synechococcus are approximately equally abundant, but the former is more important in term of carbon biomass. Despite the lack of a clear
seasonal variation in Chl a concentration, primary productivity showed a large seasonal variation, and was lowest in winter and highest in spring. Seasonal
succession in the phytoplankton community is also evident with the abundance of diatoms peaking in May, followed by picoeukaryotes
and Synechococcus in summer. The growth of phytoplankton (especially >10 μm cell size) in the western subarctic Pacific is often limited by
iron bioavailability, and microzooplankton grazing keeps the standing stock of pico- and nano-phytoplankton low. Compared
to the other HNLC regions (the eastern equatorial Pacific, the Southern Ocean, and the eastern subarctic Pacific), iron limitation
in the Western Subarctic Gyre (WSG) may be less severe probably due to higher iron concentrations. The Oyashio region has
similar physical condition, macronutrient supply and phytoplankton species compositions to the WSG, but much higher phytoplankton
biomass and primary productivity. The difference between the Oyashio region and the WSG is also believed to be the results
of difference in iron bioavailability in both regions.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献