高能偏振能量色散X射线荧光光谱仪应用现状和进展

对高能偏振能量色散X射线荧光光谱仪基本特点及其用于环境、生物、地质样品中痕量元素的分析和RoSH检测等领域的应用现状予以介绍,并对二次靶与滤光片在痕量元素分析中的应用作了探讨。     

Influence of Structural Non-Stationarity of Surface Roughness on Morphological Characterization and Mechanical Deformation of Rock Joints

Summary Structural non-stationarity of surface roughness affects accurate morphological characterization as well as mechanical behaviour of rock joints at the laboratory scale using samples with a size below the stationarity threshold. In this paper, the effect of structural non-stationarity of surface roughness is investigated by studying the scale dependence of surface roughness and mechanical behaviour of rock joints. The results show that the structural non-stationarity mainly affects the accurate characterization of the surface roughness of the fracture samples. It also controls the amount and location of the contact areas during shear tests, which in turn affects the mechanical properties and asperity degradation of the samples. It is concluded that for accurate determination of the morphological and mechanical properties of rock joints at laboratory and field scales, samples with size equal to or larger than the stationarity threshold are required. Author’s address: Nader Fardin, Rock Mechanics Group, Department of Mining Engineering, Faculty of Engineering, University of Tehran, P.O. Box: 11365/4563, Tehran, Iran     

气举反循环采矿方法单井试验及应用探讨

湖南道县一个矿区,铁锰矿体储量约2200万t。由于复杂的水文地质和工程地质条件,从20世纪70年代发现后,一直没有开采。笔者通过多年大直径工程井的实践经验,查阅国内外资料后,提出了钻井-气举反循环法试开采的方法,并在现场进行了单孔开采试验,获得了比较满意的效果。以该矿体Ⅱ号矿为例,介绍了钻井-气举反循环法采矿的适用条件、工艺过程以及试采情况,并就以后大面积开采提出了若干技术措施。     

淮南刘庄煤矿地基人工冻融土工程性质与中微观结构之间关系研究

以淮南刘庄煤矿主井地基的人工冻融土为研究对象,以偏光显微镜,扫描电镜（SEM）为主要研究手段,研究分析了人工冻融土与原状土的中微观结构、冻融前后的中微观结构的变化规律及内在原因。此外,还研究分析了人工冻融土冻融前后的中微观结构及其变化与人工冻融土的物理、力学、工程性质之间的关系。研究显示中微观结构对人工冻融土的物理、力学、工程性质有很大的影响,冻融前后中微观结构的变化受到土的种类、埋深、原状土的中微观结构等因素的影响,且冻融前后的中微观结构的变化在一定程度上主导了冻融前后的物理、力学、工程性质的改变。     

Interactive effects of the type of milling media and CuSO4 addition on the flotation performance of sulphide minerals from Merensky ore Part II: Froth stability

The limitations of pulp chemistry measurements in the flotation of a platinum group mineral (PGM) bearing Merensky ore were demonstrated in Part 1 of this article. In this paper the importance of the contribution of the froth structure due to changing froth stability is analysed using the batch flotation data. The effects of mild steel (MS) and stainless steel (SS) milling media and the addition of copper sulphate on the flotation performance of the sulphide minerals in Merensky ore have been evaluated in relation to the changes in stability of the froth phase. The effects of pulp chemistry and froth stability on the flotation of sulphide minerals were distinguished by using two different rate constants (k_t and k_w). The rate constant (k_w) calculated as a function of cumulative water recovery was used to describe characteristics of froth phase and k_t was calculated as a function of flotation time. The results revealed that the type of grinding media and copper sulphate addition had an interactive effect on the froth stability. While mild steel (MS) milling increased the froth stability due to the presence of hydrophilic iron hydroxides and colloidal metallic iron, the addition of copper sulphate reduced the stability, especially with stainless steel (SS) milling. Copper sulphate addition had a dual role in the flotation of Merensky ore in that it caused destabilisation of the froth zone as well as activation of selected sulphide minerals. The dominant effect was found to depend on the type of milling media and floatability of the mineral in question and this work has demonstrated the importance of using a combination of measurements to evaluate flotation performance holistically.     

Evaluation of three waterborne polymers as stabilizers for sandy soil

This study reports on waterborne polymer emulsion systems that were used for structural modification of sandy soils. The first emulsion used was a styrene-acrylic, copolymer emulsion; the second and third were vinyl-acrylic, copolymer-based emulsions. Specimens were prepared by adding different polymer emulsions to the sand and water in prescribed amounts. The performance of the different emulsion systems as sand stabilizers was estimated through measurement of the hydraulic conductivity and compressive strength. Measurements of hydraulic conductivity were conducted in a flexible membrane test apparatus. The hydraulic conductivity for the three emulsions decreased at different rates, with an increase in polymer content up to 3 wt. (i.e., % by weight). Additional increase of polymer content did not introduce significant decrease in hydraulic conductivity, and, at 5 wt.%, the three emulsions had essentially the same effect. Measurements made on dry cylindrical specimens disclosed remarkable enhancement in the mechanical behavior of the system. The compressive strength and modulus of elasticity of the examined emulsions increased with a higher concentration of polymer. Scanning electron microscope (SEM) revealed that the reduction in the permeability and the improved mechanical properties can be attributed to three dominant structural changes: the development of interconnecting ties between the sand particles, the development of adhesion between neighboring sand particles in contact, and the covering of the sand particles with a thin polymer film.     

超声与振荡提取沉积物中松散结合态磷的比较

用超声技术提取沉积物样品中松散结合态磷,并与振荡提取结果进行比较。结果表明,超声提取结果与振荡提取结果大致相当。超声提取耗时短,操作简单易行,测试结果精密度为3.8%(RSD,n=7),可以替代振荡方法提取沉积物中的松散结合态磷。     

机械研磨对平鲁煤系高岭石热行为的影响

对煤系高岭石进行0-2h的研磨之后，再在900℃、1000℃、1400℃的温度条件下分别对其加热1h，然后利用X射线衍射（XRD）、差热分析（DTA）、红外光谱（IR）等手段，研究机械研磨对于煤系高岭石晶体结构的破坏作用以及对其热行为的影响。结果显示，煤系高岭石被研磨1h之后，高岭石的晶体结构几乎全部跨塌。把研磨1h的煤系高岭石加热到1000℃（加热1h），便能形成结晶良好的莫来石。     

地震前兆时空非均匀性指标Cv值的实验检验

在双向加载条件下，对两种构造和介质不同的岩石标本进行变形实验，测量了标本表面不同部位的应变．在此基础上，利用王晓青和陈学忠等提出的描述地震前兆非均匀分布的参量————Cv值，分析了标本变形失稳过程中应变异常的分布，以期从实验角度检验Cv值方法并探讨其物理意义．研究表明，Cv值的变化与岩石变形特征的变化有关，是描述前兆分布非均匀性的一种有效指标；Cv值在失稳发生前先异常上升，然后下降，并在Cv值恢复过程中或恢复后伴随着失稳事件的发生．因此，Cv值是一种有效的预报指标．      

云南松根系对土壤牵引效应测试系统的设计与实现

目前在野外对云南松根系与土壤的机械效庆的研究，由于测试研究受多种因数的影响，开展研究困难较大，研究精度也受到一定程度的影响，这对较深入的描述根系与土壤相互作用的机械效应带来一定的困难。本文基于这一实际，设计了能在室内和野外进行实时测试分析的测试系统，并配套了支持PCMCIA插槽的DAQP－12型模数转换（A／D）卡，以及直流电供电的QT－300型调理装置。结合所配套的硬件，利用Visual C在Windows95/98平台编写了软件，经过实际试验测试，系统各项性能能够满足云南松根系对土壤的机械效应研究的测试分析要求。