Wavelet analysis of inter‐annual variability in the runoff regimes of glacial and nival stream catchments,Bow Lake,Alberta

Continuous wavelet analyses of hourly time series of air temperature, stream discharge, and precipitation are used to compare the seasonal and inter‐annual variability in hydrological regimes of the two principal streams feeding Bow Lake, Banff National Park, Alberta: the glacial stream draining the Wapta Icefields, and the snowmelt‐fed Bow River. The goal is to understand how water sources and flow routing differ between the two catchments. Wavelet spectra and cross‐wavelet spectra were determined for air temperature and discharge from the two streams for summers (June–September) 1997–2000, and for rainfall and discharge for the summers of 1999 and 2000. The diurnal signal of the glacial runoff was orders of magnitude higher in 1998 than in other years, indicating that significant ice exposure and the development of channelized glacial drainage occurred as a result of the 1997–98 El Niño conditions. Early retreat of the snowpack in 1997 and 1998 led to a significant summer‐long input of melt runoff from a small area of ice cover in the Bow River catchment; but such inputs were not apparent in 1999 and 2000, when snow cover was more extensive. Rainfall had a stronger influence on runoff and followed quicker flow paths in the Bow River catchment than in the glacial catchment. Snowpack thickness and catchment size were the primary controls on the phase relationship between temperature and discharge at diurnal time scales. Wavelet analysis is a fast and effective means to characterize runoff, temperature, and precipitation regimes and their interrelationships and inter‐annual variability. The technique is effective at identifying inter‐annual and seasonal changes in the relative contributions of different water sources to runoff, and changes in the time required for routing of diurnal meltwater pulses through a catchment. However, it is less effective at identifying changes/differences in the type of the flow routing (e.g. overland flow versus through flow) between or within catchments. Copyright © 2003 John Wiley & Sons, Ltd.     

Laser ablation coupled with ICP-MS applied to U–Pb zircon geochronology: A review of recent advances

Improvements in the technology of laser ablation and ICP-MS instruments make LA-MC-ICPMS a rapid, precise and accurate method for U–Pb zircon geochronology. In this review we describe the main stages of the evolution of this in situ approach from the early 1990s to the present time. Some key points have been progressively improved. The crater size has been reduced to achieve real in situ measurements. The laser wavelength has been reduced as well as the duration of each pulse in order to lower inter-element fractionation. The blank from the gas has to be lowered as far as possible. Double focusing instruments and magnetic field sectors allow flat-topped peaks required for precise isotope ratio measurement to be obtained. The use of a multi-ion counting system significantly improves the sensitivity of the method and the static mode of integration favours the precision of measurement of the transient signal originating from a noisy laser ablated particle beam.Combining the use of a 213 nm UV laser and a MC-ICPMS equipped with a multi-ion counting system operating in static mode, the common precisions achieved for the key ratios ²⁰⁷Pb/²⁰⁶Pb and ²⁰⁶Pb/²³⁸U are better than 1% and 3% (2σ) respectively, including error propagation associated with standard normalization. Until now, the use of a zircon standard has remained necessary to ensure the accuracy of the calculated age. A strategy for common-Pb correction is proposed according to the age of the zircon and according to the Th/U ratio of the grains. After recording sixteen to twenty spot analyses the precision usually achieved on the age is about 1% and even significantly better for Proterozoic samples.In order to show the performance achieved by modern LA-MC-ICPMS geochronology, we tested four zircon samples covering a wide age range from 290 to 2440 Ma. These new age determinations can be compared in term of precision and accuracy since they have already been dated by reference methods (ID-TIMS and SHRIMP). Further developments in the technology of ion counters equipping modern MC-ICPMS and in laser systems will certainly be applied to a large field of geochronology studies in the near future as an alternative to SIMS for in situ age determination.     

激光剥蚀等离子体质谱分析中激光剥蚀参数对信号响应的影响

探讨了激光剥蚀等离子体质谱固体微区分析中激光剥蚀参数对元素分析信号灵敏度及稳定性的影响。这些参数包括激光功率、脉冲频率、剥蚀孔经、散焦距离、剥蚀方式等。讨论了优化的激光剥蚀等离子体质谱信号采集及数据处理方式。在全质量范围内选用具有代表性的元素作为研究对象,建立了激光剥蚀的一般性特征规律和266nm紫外激光系统的最佳操作条件。在选定的激光剥蚀参数下,大多数被测元素的检出限为22.8~457ng/g,能够满足固体微区分析的要求。     

Preliminary Results from a New 157 nm Laser Ablation ICP-MS Instrument: New Opportunities in the Analysis of Solid Samples

Preliminary results are given from an excimer 157 nm laser ablation multiple-collector inductively coupled plasma-mass spectrometer (LA-MC-ICP-MS), used for the isotopic measurements of solid materials. Elements of geological interest with different volatilities such as Pb and U (e.g. zircon geochronology) and Cu and Zn (as examples of geochemical/biochemical tracers) were analysed. The range of ablation rates of 20-150 nm s^-1 enabled us to ablate the sample down to a depth of 45 μm for a 50 μm diameter pit. The Cu and Zn isotopic measurements gave values that were very stable with, on average, a 0.01 % standard error, comparable with that achieved in liquid mode measurements.     

山谷冰川稳定态时积累区面积比率研究

探讨山谷冰川稳定状态时积累区面积比率，即ＡＡＲ值的大小，认为冰川物质平衡高程分布，平面形态及坡面坡度沿程变化形式是影响山谷冰川稳定态ＡＡＲ值的主要因素，并 山谷冰川稳定态ＡＡＲ值与物质平衡高程分布及平面形态之间的定量关系。山谷冰川适合于应用ＡＲ值法来研究古冰川的零平衡线高程。     

Basal sediment evacuation by subglacial meltwater: suspended sediment transport from Haut Glacier d'Arolla,Switzerland

Proglacial suspended sediment transport was monitored at Haut Glacier d'Arolla, Switzerland, during the 1998 melt season to investigate the mechanisms of basal sediment evacuation by subglacial meltwater. Sub‐seasonal changes in relationships between suspended sediment transport and discharge demonstrate that the structure and hydraulics of the subglacial drainage system critically influenced how basal sediment was accessed and entrained. Under hydraulically inefficient subglacial drainage at the start of the melt season, sediment availability was generally high but sediment transport increased relatively slowly with discharge. Later in the melt season, sediment transport increased more rapidly with discharge as subglacial meltwater became confined to a spatially limited network of channels following removal of the seasonal snowpack from the ablation area. Flow capacity is inferred to have increased more rapidly with discharge within subglacial channels because rapid changes in discharge during highly peaked diurnal runoff cycles are likely to have been accommodated largely by changes in flow velocity. Basal sediment availability declined during channelization but increased throughout the remainder of the monitored period, resulting in very efficient basal sediment evacuation over the peak of the melt season. Increased basal sediment availability during the summer appears to have been linked to high diurnal water pressure variation within subglacial channels inferred from the strong increase in flow velocity with discharge. Basal sediment availability therefore appears likely to have been increased by (1) enhanced local ice‐bed separation leading to extra‐channel flow excursions and[sol ]or (2) the deformation of basal sediment towards low‐pressure channels due to a strong diurnally reversing hydraulic gradient between channels and areas of hydraulically less‐efficient drainage. Copyright © 2005 John Wiley & Sons, Ltd.     

Determination of Lithium, Beryllium and Boron at Trace Levels by Laser Ablation-Inductively Coupled Plasma-Sector Field Mass Spectrometry

The analytical capabilities of laser ablation (LA)-ICP-MS in determining Li, Be and B at trace levels in geological samples have been tested on a series of glass reference materials and natural samples. The LA-ICP-MS instrument used consisted of a sector-field ICP-MS coupled with a laser ablation microprobe operating at either 266 or 213 nm wavelength. Reference glasses from NIST (SRM 612, 614 and 616) and MPI-DING (KL2-G, ML3B-G, StHs6/80-G, GOR128-G, GOR132-G, T1-G and ATHO-G) were selected to develop the analytical method and to assess the best instrumental configuration. A series of calcic amphiboles with different Li, Be and B concentrations were also analysed using both LA-ICP-MS and SIMS to test the applicability of the method to natural minerals. Results indicated that with a spot size of 40 μm the agreement between measured and reference values of Li, Be and B is generally better than 10% for NIST SRM 612 and 20% for NIST SRM 614. Average reproducibility at the 2s level was 10% for Li, 20% for Be and 15% for B. Limits of detection were approximately 100 ng g^-1 for Be and B and 200 ng g^-1 for Li. These results were confirmed by analyses carried out on natural amphiboles and compared well in terms of precision and accuracy with those commonly achieved by SIMS.     

新疆帕米尔跃动冰川遥感监测研究

2015年5月,新疆克孜勒苏柯尔克孜自治州阿克陶县公格尔九别峰北坡克拉牙依拉克冰川发生跃动,造成草场和部分房屋被冰体淹没,本文针对这一冰川跃动事件的发生过程进行研究.利用2013-2015年间ASTER立体像对数据监测了克拉牙依拉克冰川的冰川表面高程的变化,并利用2015年4月13日至2015年7月11日期间的LandsatOLI数据监测了冰川的表面运动速度变化.监测发现,克拉牙依拉克冰川从2015年4月13号开始活动强烈,表面运动速度呈加快趋势,2015年5月8-15日期间冰川表面运动速度达到最高水平,其最大运动速度在西支中部达到了(20.40±0.42)m·d^-1,冰川跃动达到顶峰.冰川跃动"积蓄区"位于西支冰川平衡线以下区域,跃动向下游接收区输送冰体体积约为2.4×10⁸m³,大量冰体堆积在东西支汇合口地段(海拔3100~3500m),造成了该处冰面隆起,其中最大隆起高度为(130.58±0.70)m.本文获得了西支冰川由静止期、跃动状态、恢复到稳定状态期间的冰面高程和表面运动速度变化,为本地区冰川跃动机理的研究奠定了基础.     

天山乌鲁木齐河源一号冰川探地雷达测厚及其数据分析

探地雷达是一种利用电磁波的反射原理探测地下介质分布特征的地球物理勘探技术，在冰川研究中发挥了重要作用。在天山一号冰川上用探地雷达进行了探测，获得了能够清晰地分辨冰一岩界面的雷达剖面。根据这些雷达剖面读出冰厚值，再结合最新的冰川地形图，作出了天山一号冰川的冰厚等值线图和冰下地形图；并由天山一号冰川最新的表面积数据推算了冰储量。     

石羊河流域冰冻圈融水对出山径流的贡献及影响

气候变暖背景下,随着冰冻圈的持续萎缩,冰冻圈融水已成为寒区径流的重要组成部分和寒区水文过程的关键影响因子。以石羊河流域为研究区,2013年7月~2014年6月在系统采集大气降水、河水、泉水、井水、水库水、渠系水、冻土活动层地下水和冰雪融水样品基础上,应用稳定同位素示踪技术,定量评估了石羊河流域冰雪融水和冻土活动层地下水对出山径流的贡献量,结果表明：流域内大气降水、冻土活动层地下水和冰雪融水充分混合后以地下水的形式补给径流,大气降水、冻土活动层地下水和冰雪融水对出山径流的补给率分别为77%、20%和3%。依据多年冻土下界将山区分为冰雪冻土带和植被带,分析证实冰雪冻土带输出水量贡献了出山径流的82%,而植被带贡献了18%。流域出山口径流的补给带为海拔3300m以上,中游浅层地下水的补给带为海拔3700m以上。冰雪融水和冻土活动层地下水对7条支流出山径流的贡献率因自然地理状况而明显差异,东大河、西营河和金塔河降水对出山径流的贡献率分别为72%、78%和87%,相应的冻土活动层地下水贡献率为21%、17%和12%,冰雪融水为7%、5%和1%。降水对西大河、黄羊河、古浪河和大靖河出山径流贡献率分别为84%、91%、76%和73%,冻土活动层地下水对出山径流的贡献率依次为16%、9%、24%和27%。研究确认冻土活动层地下水已成为内陆河流域径流的重要组成部分,未来亟须进一步加强冻土活动层地下水水文机制的研究。