Fe-Cu-Zn-Mo同位素示踪氧化还原过程

非传统稳定同位素（Fe-Cu-Zn-Mo）理论与数据相结合提高了科研工作者对地质体系氧化还原过程的理解。本文对这一相对较新的领域进行了综述,包括与氧化还原过程相关的同位素分馏理论和实验约束、时空尺度下的氧逸度以及同位素示踪氧化还原过程。稳定同位素理论预测,Fe-Cu-Zn-Mo同位素应该对氧化还原状态的变化能够做出响应。结果表明,Fe同位素作为岩浆过程、表生过程、俯冲带流体性质"氧逸度计"应用前景广阔;Cu同位素在岩浆、热液、陆地系统可以很好地示踪氧化还原过程;Zn同位素由于络合过程分馏已经被用在许多不同环境中作为含硫/碳流体迁移的敏感示踪剂;Mo同位素作为古氧逸度计可有效重建古海洋-大气氧化还原状态。     

Influence of oxygen fugacity on mineral compositions in peralkaline melts: The Katzenbuckel volcano, Southwest Germany

The igneous rocks of the Katzenbuckel, Southwest Germany, represent a unique and unusual alkaline to peralkaline association within the European Volcanic Province. The magmatic activity can be subdivided into two main phases. Phase I comprises the main rock bodies of phonolite and nepheline syenite, which were later intruded by different peralkaline dyke rocks (tinguaites and alkali feldspar syenite dykes) of phase II. The dyke assemblage was accompanied by magnetite and apatite veins and was followed by a late-stage pneumatolytic activity causing autometasomatic alterations.

As is typical for alkaline to peralkaline igneous rocks, early mafic minerals of phase I rocks comprise olivine, augite and Fe–Ti oxides, which are substituted in the course of fractionation by Na-amphibole and Na-pyroxene. For the early magmatic stage, calculated temperatures range between 880 and 780 °C with low silica activities (0.4 to 0.6) but high relative oxygen fugacities between 0.5 and 1.9 log units above the FMQ buffer. Even higher oxygen fugacities (above the HM buffer) are indicated for the autometasomatic alteration, which occurred at temperatures between 585 and 780 °C and resulted in the formation of pseudobrookite and hematite.

The unusually high oxygen fugacities (even during the early magmatic stage) are recorded by the major element compositions of the mafic minerals (forsterite content in olivine between 68 and 78 mol%, up to 6.2 wt.% ZrO₂ and 8.5 wt.% TiO₂ in clinopyroxene), the unusual mineral assemblages (pseudobrookite, freudenbergite) and by the enrichment of Fe³⁺ in the felsic minerals (up to 2.8 wt.% Fe₂O₃ in alkali feldspar and up to 2.6 wt.% Fe₂O₃ in nepheline). These observations point to a metasomatically enriched and highly oxidized lithospheric mantle as a major source for the Katzenbuckel melts.     

P–T–fO2 controls on a partly inverse chromite-bearing ultramafic intrusive: an evaluation from the Sukinda Massif, India

The chromites from the alpine type ultramafic intrusive of Sukinda, India, display a typical partly inverse spinel form and occur in two distinct zones: Brown Ore Zone (BOZ) and Grey Ore Zone (GOZ). The host ultramafites are mostly altered and are represented by the serpentinite, tremolite-talc(chlorite) schist, talc-serpentine schist and chlorite rock. The less altered variants are dunite, harzburgite and websterite. A dyke of orthopyroxenite runs through the main ultramafic body.The composition of olivine (Fo₉₂), orthopyroxene (En_92–89) and Al₂O₃ contents of the parental liquid (10.40–11.45%) determined from chromites, suggest that the parent melt is of boninitic affinity. The chemical plot of TiO₂ content against cr# of chromites corroborates a boninitic parental melt. The Fe–Mg partitioning in olivine and chromite depicts the temperature for chromitites as 1200 °C. A compositional plot of mg# and cr# suggests crystallization at high pressure conditions, corresponding to the kimberlite xenolith field. From the P–T diagram of pyrolite melting and mineral assemblage, the pressure of crystallization is stipulated to be ≥1.2 GPa. The f_O2 values estimated from Fe³⁺/Cr+Al+Fe³⁺ ratios range from 10^−8.3 to 10^−9.3 for the GOZ and 10^−7.1 to 10^−7.3 for the BOZ. The f_O2 values together with the pressure range suggest crystallization at upper mantle conditions. The heterogeneity in chemical composition and f_O2 conditions for the GOZ and BOZ could be linked to heterogeneity in the upper mantle.     

Iron-Titanium Oxide Geothermometry and Petrogenesis of Lava Flows and Dykes from Mandla Lobe of the Eastern Deccan Volcanic Province, India

Compositional studies on different forms of magnetite, ulvospinel, ilmenite and hematite mineral phases occurring in 37 lava flows and 6 dykes of the Mandla lobe are presented in this paper. Ilmenite (0001) in equilibrium with titanomanetite show high values of temperature of equilibration, ranging from 1172–974°C, for high alumina quartz normative tholeiitic lava flows of Chemical Type - A; 1129–1229°C for low alumina quartz normative tholeiitic lava flows of Chemical Type - B; 1283–1124°C for tholeiitic lava flows of Chemical Type - F and 1243°C and 99O°C for two diopside olivine normative tholeiite flows of Chemical Type D. High olivine normative flows of Chemical Type - G and H show 1095°C and 1092°C respectively. Whereas, high hypersthene normative tholeiite flow of Chemical me C shows temperature of 1187°C. Data plots disposition over iron-titanium oxide equilibration temperature vs – logfo₂, diagram for Mandla lava flows and other parts of the Deccan (Igatpuri, Mahabaleshwer, Nagpur and Sagar areas) revealed that tholeiitic (evolved) basalt of the eastern Deccan volcanic province formed at high temperatures whereas, picritic (primitive) lavas of Igatpuri and tholeiitic basalt of Mahabaleshwar areas were formed at low temperatures. Mahabaleshwer basalts follow FMQ (fayalite-magnetite-quartz) buffer curve but, plots of the Mandla basalts lie above this curve indicating higher temperatures of crystallisation of ilmenite-titanomagnetite than that of the lava flows from other parts of Deccan 'Raps. The eastern Deccan Traps are most evolved types of lava as characterised by its low Mg-number and Ni content whereas, Igatpuri lava flows are picritic (primitive), having high Mg-number and Ni contents. Temperature vs FeO + Fe₂O₃ / FeO + Fe₂O₃ + MgO ratio data plots for Mandla and other Deccan lava flows and liquidus data for Hawaiian tholeiites, indicated that Igatpuri basalts lie parallel to the liquidus line of Hawaiian tholeiite but at lower temperatures. Large data plots of Mandla lava flows lie along the liquidus line of the Hawaiian lava. The highly vesicular nature of compound lava flows having large amount of volatile is responsible for low temperature values whereas, lava flows represented by high temperatures show high modal values of glass and opaque minerals.     

Formation of Carbon and Hydrogen Species in Magmas at Low Oxygen Fugacity

Studies of iron-bearing silicate melt (ferrobasalt) + iron metallicphase + graphite + hydrogen equilibria show that carbon andhydrogen solubilities in melts are important for the evolutionof the upper mantle. In a series of experiments conducted at3·7 GPa and 1520–1600°C, we have characterizedthe nature (oxidized vs reduced) and quantified the abundancesof C- and H-compounds dissolved in iron-bearing silicate melts.Experiments were carried out in an anvil-with-hole apparatuspermitting the achievement of equal chemical potentials of H₂in the inner Pt capsule and outer furnace assembly. The fO₂for silicate melt–iron equilibrium was 2·32 ±0·04 log units below iron–wüstite (IW). Theferrobasalt used as starting material experienced a reductionof its iron oxides and silicate network. The counterpart wasa liberation of oxygen reacting with the hydrogen entering thecapsule. The amount of H₂O dissolved in the glasses was measuredby ion microprobe and by step-heating and was found to be between1 and 2 wt %. The dissolved carbon content was found to be 1600ppm C by step-heating. The speciation of C and H componentswas determined by IR and Raman spectroscopy. It was establishedthat the main part of the liberated oxygen was used to formOH^– and to a much lesser extent H₂O, and only traces ofH₂, CO₂ and     

Iron isotopic systematics of UHP eclogites respond to oxidizing fluid during exhumation

The iron stable isotope compositions (δ⁵⁶Fe) and iron valence states of ultrahigh‐pressure eclogites from Bixiling in the Dabie orogen belt, China, were measured to trace the changes of geochemical conditions during vertical transportation of earth materials, for example, oxygen fugacity. The bulk Fe³⁺/ΣFe ratios of retrograde eclogites, determined by Mössbauer spectroscopy, are consistently higher than those of fresh eclogites, suggesting oxidation during retrograde metamorphism and fluid infiltration. The studied eclogites (five samples) display limited mid‐ocean ridge basalts (MORB)‐like (~0.10‰) δ⁵⁶Fe values, which are indistinguishable from their protoliths, that is, gabbro cumulates formed through differentiation of mantle‐derived basaltic magma. This suggests that Fe isotope fractionation during continental subduction is limited. Garnet separates display limited δ⁵⁶Fe variation ranging from ?0.08 ± 0.07 ‰ to 0.02 ± 0.07‰, whereas coexisting omphacite displays a large variation of δ⁵⁶Fe values from 0.15 ± 0.07‰ to 0.47 ± 0.07‰. Omphacite also has highly variable Fe³⁺/ΣFe ratios from 0.367 ± 0.025 to 0.598 ± 0.024, indicating modification after peak metamorphism. Omphacite from retrograde eclogites has elevated Fe³⁺/ΣFe ratios (0.54–0.60) compared to that from fresh eclogites (~0.37), whereas garnet displays a narrow range of ferric iron content with Fe³⁺/ΣFe ratios from 0.039 ± 0.013 to 0.065 ± 0.022. The homogenous δ⁵⁶Fe values and Fe³⁺/ΣFe ratios of garnet suggest that it survived the retrograde metamorphism and preserved its Fe‐isotopic features and ferric contents of peak metamorphism. Because of similar diffusion rates of Fe and Mg in garnet and omphacite, and constant Δ²⁶Mg_{omphacite‐garnet} values (1.14 ± 0.04‰), equilibrium iron isotope fractionation between garnet and omphacite was probably achieved during peak metamorphism. Elevated Fe³⁺/ΣFe ratios of omphacite from retrograde eclogites and variant Δ⁵⁶Fe_{omphacite‐garnet} values of the studied eclogites (0.13 ± 0.10‰ to 0.48 ± 0.10‰) indicate that oxidized geofluid infiltration resulted in the elevation of δ⁵⁶Fe values of omphacite during retrograde metamorphism.     

班公湖-怒江缝合带东段丁青地幔橄榄岩成因:来自钻孔ZK02地幔橄榄岩矿物学及地球化学特征约束

丁青蛇绿岩位于班公湖-怒江缝合带东段,是该缝合带出露面积最大的蛇绿岩。为查明岩体成因,在丁青东岩体中实施了一口165.19m的钻孔。除最顶部有约0.5m厚的第四系残坡积物外,其余均为地幔橄榄岩。结合显微镜鉴定将岩心划分出17个岩性单元层,岩性主要以方辉橄榄岩为主,夹少量纯橄岩和含铬铁矿纯橄岩。地幔橄榄岩中橄榄石的Fo变化于88.79~93.73,铬尖晶石的Cr^#变化于44.33~81.66,揭示丁青地幔橄榄岩可能经历过约20%~40%的中高度部分熔融作用;全岩地球化学分析表明其具有富镁（MgO=45.98%~49.45%）、贫铝（Al₂O₃=0.19%~1.37%）和贫钙（CaO=0.28%~0.70%）的特点,属于熔融程度较高的地幔残余物质。岩石具有明显不同于阿尔卑斯蛇绿岩的轻稀土元素富集特征,指示区内地幔橄榄岩先经历了较强程度的部分熔融,后经历了俯冲消减过程中的流体交代。利用地幔橄榄岩中的铬尖晶石成分计算母熔体Al₂O₃含量对应的FeO/MgO值,与不同构造环境原始岩浆成分相比较,发现丁青地幔橄榄岩母熔体大多处于玻安岩中。纯橄岩氧逸度估算FMQ=-3.05~-0.71,方辉橄榄岩氧逸度FMQ=-3.89~+1.47,显示丁青地幔橄榄岩有俯冲作用的参与。通过丁青钻孔岩心的研究,提出丁青东岩体可能形成于俯冲带之上的弧前环境这一观点。     

鲁西地区角闪石岩地球化学、矿物学特征及其地质意义

基性-超基性岩脉群通常形成于伸展构造背景,是示踪地幔源特征以及大陆和超大陆破裂的重要标志.鲁西地区角闪石岩为研究古元古代岩浆源和构造演化提供了一个窗口.本文对鲁西地区角闪石岩进行了岩相学、全岩地球化学及角闪石、黑云母电子探针原位分析.角闪石岩具板内构造环境,来自富集地幔.通过角闪石、黑云母成因分析,均具有幔源成因,角闪石结晶温度为702～781℃;结晶压力为29.8～228.8 MPa,结晶深度1～7.5 km,结晶时氧逸度变化范围在NNO+2.68到NNO+3.35之间.结合本次获得角闪石岩磷灰石U-Pb年龄为(1817±35)Ma,认为鲁西地区(1817±35)Ma处于板内拉伸环境,存在幔源岩浆上侵,已进入大陆裂解阶段.     

滇西姚安金矿床磷灰石化学特征及指示意义

姚安金矿床位于金沙江-哀牢山富碱斑岩带中段,大地构造位置处于扬子板块西缘与三江特提斯造山带结合部位,其成矿与新生代富碱岩浆-岩浆热液密切相关.野外调查发现矿化仅存在于黑云母正长斑岩体内,而与黑云母正长斑岩空间关系密切的石英正长斑岩却未发现矿化.为探讨黑云母正长斑岩与石英正长斑岩岩体含矿性差异,运用电子探针、LA-ICP...     

米仓山碱性岩中的主要矿物研究及其成因信息

米仓山碱性岩中的主要矿物为富铝的(次硅)铝铁质透辉石、钙质角闪石、霞石等,且大量出现霞石,但无或极少有碱性暗色矿物。研究表明:氧逸度低是碱性岩浆不能结晶出碱性暗色矿物的原因。本区这种无碱性暗色矿物的碱性岩是在封闭体系及深成条件下结晶的,而其它地区含有碱性暗色矿物的岩石则是在开放体系中形成的。