辽宁省鞍本地区铁尾矿资源现状及其开发利用

辽宁省的鞍山、本溪两市为我国重要的钢铁基地，各矿山长期生产遗留的铁尾矿问题越来越引起人们的重视，如污染环境、诱发地质灾害等，如何解决已成为地质、环保、水工界的关注。     

四川拉拉铁氧化物铜金矿床（IOCG）形成的矿相学证据

四川拉拉铜矿是我国西南重要的大型铜矿,并且共（伴）生丰富的金—钼—钴—稀土—铁可供综合利用。系统的矿相学研究表明,矿石矿物主要为热液磁铁矿、黄铜矿、黄铁矿、白铁矿和辉钼矿;矿床围岩蚀变种类较多,主要有黑云母化、硅化、碳酸盐化、钠长石化、钾长石化、磷灰石化、阳起石化、萤石化等;矿石结构包括自形- 半自形- 它形晶粒结构、交代残余结构、包含结构和枝状结构,矿石构造包括浸染状构造、条带状构造、脉状- 网脉状构造和角砾状构造;载铜矿物主要为黄铜矿,钴主要赋存于黄铁矿和白铁矿中,钼赋存于辉钼矿中,金主要以自然金或含银自然金形式赋存于黄铜矿、黄铁矿和叶碲铋矿中;磁铁矿中钛含量低,矿石中硫含量低,罕见铅锌硫化物矿物。因此,拉拉铜矿应属于典型的铁氧化物铜金矿床。     

Negative Ce Anomaly in the Indian Banded Iron Formations: Evidence for the Emergence of Oxygenated Deep-Sea at 2.9-2.7 Ga

Abstract: Major and rare earth element contents are reported for Late Archean banded iron formations (BIFs) in the Bababudan Group of the Dharwar Craton, South India. The BIFs are mostly composed of SiO₂ (average1ρ = 54.88.1 wt%) and Fe₂O₃* (44.38.2 wt%). The Al₂O₃ and TiO₂ contents are remarkably low, suggesting that detrital components were starved during the BIF deposition. The BIFs have a LREE-enriched pattern with a relatively high (La/Yb)_N (6.644.07). Total REE concentrations (RE) vary from 5.2 to 65.3 ppm. The REE patterns are characterized by the presence of a very large negative Ce anomaly (Ce/Ce*: 0.13-0.83) and a positive Eu anomaly (Eu/Eu*: 0.96-2.45). The Eu/Eu* decreases and (La/Yb)_N increases with a increase of RE. These correlations of REE indices are similar to those of modern hydrothermal iron-rich sediments near a mid-ocean ridge (MOR). Greenstones associated with the BIFs have MORB-like geochemical features. These geochemical and geological lines of evidence indicate that the depositional site of the BIFs was remote from a continent and/or island arc and that the BIFs were in situ hydrothermal sediments near a MOR. A striking negative Ce anomaly in the BIFs indicates that oxygenated deep-sea environments emerged at 2.9-2.7 Ga. The existence of contemporaneous Mn deposits in the Dharwar Craton supports this assertion. Our scenario of oxygen in the Earth's surface of the Late Archean is different from long-held notion that the atmosphere and ocean were persistently anoxic throughout the Archean.     

Fe3+纳米胶体颗粒的光吸收边蓝移与溶液中Al/Fe比的关系

合成了n（Al）／n（Fe）和碱化度不同的45个聚合氯化铝铁（PAFC）样品,进行了光谱分析,结果显示光吸收边蓝移或红移以及Fe（Ⅲ）羟基氧化物和Al-Fe共聚体纳米胶体颗粒大小分布与溶液的Al／Fe比和碱化度（B=[OH]／[Al＋Fe]）密切相关。电镜观察和电子衍射分析表明：Al（Ⅲ）的加入使Fe（Ⅲ）羟基氧化物和Al-Fe共聚体纳米胶体颗粒变小、有序度降低是造成PAFE光吸收边蓝移和保持胶体颗粒在亚稳定状态下存在的重要原因。当n（Al）／n（Fe）〉8：2后,PAFC溶液中Fe（Ⅲ）羟基氧化物和Al-Fe共聚体胶体主要以〈10m的纳米颗粒形态存在,对应的光谱能级提高到26000cm^-1以上,且各种曰值下Fe^3＋的光谱能级趋于一致。这表明,在大量Al（Ⅲ）存在条件下,PAFE中Fe3^＋的所处的化学环境相似。点能谱分析显示,n（Al）／n（Fe）=4：6的样品中颗粒物的化学计量比最接近AlOOH,FeOOH,溶液的稳定性最差。     

Cobalt‐Bearing Grunerite in the Metamorphosed Banded Iron Formation in Orissa,India

Banded iron formation (BIF) comprising high grade iron ore are exposed in Gorumahisani‐Sulaipat‐Badampahar belt in the east of North Orissa Craton, India. The ores are multiply deformed and metamorphosed to amphibolite facies. The mineral assemblage in the BIF comprises grunerite, magnetite/martite/goethite and quartz. Relict carbonate phases are sometimes noticed within thick iron mesobands. Grunerite crystals exhibit needles to fibrous lamellae and platy form or often sheaf‐like aggregates in linear and radial arrangement. Accicular grunerite also occur within intergranular space of magnetite/martite. Grunerite needles/accicules show higher reflectivity in chert mesoband and matching reflectance with that of adjacent magnetite/martite in iron mesoband. Some grunerite lamellae sinter into micron size magnetite platelets. This grunerite has high ferrous oxide and cobalt oxide content but is low in Mg‐ and Mn‐oxide compared to the ones, reported from BIFs, of Western Australia, Nigeria, France, USA and Quebec. The protolith of this BIF is considered to be carbonate containing sediments, with high concentrations of Fe and Si but lower contents of cobalt and chromium ± Mg, Mn and Ni. During submarine weathering quartz, sheet silicate (greenalite) and Fe‐Co‐Cr (Mg‐Mn‐Ni)‐carbonate solid solution were formed. At the outset of the regional metamorphic episode grunerite, euhedral magnetite and recrystalized quartz were developed. Magnetite was grown at the expense of carbonate and later martitized under post‐metamorphic conditions. With the increasing grade of metamorphism greenalite transformed to grunerite.     

Iron oxidation state in lower mantle mineral assemblages: II. Inclusions in diamonds from Kankan, Guinea

Inclusions of ferropericlase and former (Mg,Fe)(Si,Al)O₃ perovskite in diamonds from Kankan, Guinea believed to originate in the lower mantle were studied using Mössbauer spectroscopy to determine Fe³⁺/ΣFe. Fe³⁺ concentration in the (Mg,Fe)(Si,Al)O₃ inclusion is consistent with empirical relations relating Fe³⁺/ΣFe to Al concentration, supporting the inference that it crystallised in the perovskite structure at lower mantle conditions. In ferropericlase there is a nearly linear variation of trivalent cation abundance with monovalent cation abundance, suggesting a substitution of the form Na_0.5M_0.5³⁺O (M=Fe³⁺, Cr³⁺, Al³⁺). Excess positive charge is likely balanced by cation vacancies, where their abundance is observed to increase with increasing iron concentration, consistent with high-pressure experiments. The abundance of cation vacancies is related to oxygen fugacity, where ferropericlase inclusions from Kankan and São Luiz (Brazil) are inferred to have formed at conditions more oxidising than Fe-(Mg,Fe)O equilibrium, but more reducing than Re-ReO₂ equilibrium. Fe²⁺/Mg partition coefficients between (Mg,Fe)(Si,Al)O₃ and ferropericlase were calculated for inclusions co-existing in the same diamond using Mössbauer data and empirical relations based on high-pressure experimental work. Most values are consistent with high-pressure experiments, suggesting that these inclusions equilibrated at lower mantle conditions. The measured ferropericlase Fe³⁺ concentrations are consistent with diamond formation in a region of redox gradients, possibly arising from the subduction of oxidised material into reduced lower mantle. Reduction of carbonate to form ferropericlase and diamond is consistent with a slight shift of Kankan δ¹³C values to isotopically heavy compositions compared to the worldwide dataset, and could supply the oxygen necessary to satisfy the high Fe³⁺ concentration in (Mg,Fe)(Si,Al)O₃ perovskite, as well as account for the high proportion of ferropericlase in the lower mantle paragenesis. The heterogeneity of lower mantle diamond sources indicates that the composition of lower mantle diamonds do not necessarily reflect those of the bulk mantle.     

唐山市钢铁工业发展特征及动力机制分析

唐山市钢铁工业自20世纪80年代以来一直为唐山市的支柱产业,90年代以来,省属特大型企业唐钢和地方钢铁企业都得到了迅速发展,在唐山市经济总量中占据着举足轻重的地位。本文详细分析唐山市钢铁产业的发展过程,探讨改革开放以来影响城市最具代表性产业的驱动因素。研究表明,基于本地化的区域产业基础和国家引导下的制度因素是唐山市钢铁工业迅速发展的主要驱动力,企业在动态的环境中适应和创新的能力则是内在因素。产品结构雷同、彼此利益独立使企业之间面临着激烈竞争,因此建议发挥政府的协调作用,引导地方企业调整工艺流程和产品结构,扶植相关产业,促进区域经济整体发展。     

矿山酸性水中铝相次生矿物及环境学意义的研究进展

酸性矿山排水（AMD）是硫化矿床矿山环境污染防治的难点,因而持续受到国内外学者的关注。众多的学者对矿区AMD中次生矿物进行了研究。为深入了解AMD中次生矿物的形成和演化,为AMD污染防治提供科学依据,笔者对前人不同环境下AMD中的次生矿物类型、次生矿物形成顺序,以及铝相次生矿物的形成、特征、环境危害及意义进行了简要综述。目前与AMD有关的主要次生矿物存在3种类型,即铁相次生矿物、铝相次生矿物和其他相次生矿物,AMD中的pH、Eh和温度对于次生矿物的形成具有控制性的作用。铁、铝相次生矿物具有吸附金属能力,这一性质有助于在一定程度上实现河流的自净化作用。由于AMD形成条件高,矿物相不稳定,目前有关AMD中铝相次生矿物及“酸性白水”的研究成果有限。因此,加强铝相次生矿物以及“酸性白水”的研究,可以更好地解析蒿坪河流域石煤矿区河流酸性磺水–酸性白水的形成演化机制,以及铝相次生矿物吸附重金属的地球化学过程。     

高精度磁测在IOCG型铁矿勘查中的应用——以智利英格瓦塞铁矿为例

IOCG型（铁氧化物铜金型）矿床富含铁氧化物,且常缺失硫化物,高精度磁测是寻找IOCG矿床重要的有效手段之一。英格瓦塞铁矿位于智利中北部IOCG型矿床成矿带,前期地质工作程度较低。在智利英格瓦塞铁矿矿区地质特征调查基础上,重点针对中部矿区的7个磁异常区,利用RGIS对其高精度磁测数据进行面积上延、面积下延、剖面下延及2.5D反演拟合处理,结果表明,本区引起磁异常的磁性地质体整体呈NE向延伸、倾向NW、倾角较陡。除Ⅰ号和Ⅴ号磁异常规模较小外,其他几个磁异常中心找矿前景较大,有规模的磁异常区大多埋深在50~120 m之间,为下一步地质找矿钻探验证提供了有效的基础。同时,该勘查方法可为中国IOCG型铁矿找矿工作提供参考依据。     

辽宁本溪南芬铁矿地质特征

南芬铁矿床成因类型为太古宙鞍山式火山沉积变质铁矿床,矿床规模为超大型,矿体形态和组构较简单,矿石有用组分分布均匀.矿体由分布于太古宇鞍山群茨沟岩组中的3个铁矿层组成,控矿构造为单斜构造,矿体的规模、产状、矿物组成、品位（TFe）稳定.