海水中一氧化氮的极谱法测定

本文首次采用 Nafion和 Co(salen) /Nafion修饰铂电极测定海水中的 NO,对实验条件进行了选择 ,确定了最佳实验条件 ,即反应池通氮除氧 30 min,富集时间为 4min。同时用线性扫描法对海水中的 NO进行测定 ,测得海水中 NO的浓度与氧化峰电流之间有一定线性关系。对 Nafion修饰电极而言 ,线性范围 1～ 76.9μmol/L,R2 =0 .991 6,检出限为 1 μmol/L。同时对 2种方法修饰的铂电极进行了比较 ,即当 NO浓度在 1 0 -6mol/L数量级时 2种电极基本上无差别 ,而在 1 0 -7mol/L数量级时 Co(salen) /Nafion修饰电极要明显优于 Nafion修饰电极     

Application of X-ray computed tomography for analyzing cleat spacing and cleat aperture in coal samples

New techniques to determine distributions of cleat aperture, cleat orientation and cleat spacing from CT scans have been developed. For cleat orientation and spacing distributions, two different coal blocks were scanned. The CT scans have been analyzed for the three orthogonal directions. Histograms of the cleat orientations are bimodal, expressing the typical cleat texture of face and butt cleats and bedding perpendicular relaxation fractures. Deviations up to 20° from the peak values in the cleat orientation distributions were used as input for automated image analysis of cleat spacing. Distributions of the cleat spacing measurements are related to the face and butt cleat directions. The term “relevant cleat length” is introduced as a measure to extract the amount of cleat length involved with the cleat spacing measurements. The ratio ranges from 0.03 to 0.38 and expresses the difference in cleat texture in both samples. Cleat spacing versus relevant cleat length shows sample specific patterns for face cleat, butt cleat and bedding. To describe cleat aperture quantitatively, peak height and missing attenuation have been used. The image of a cleat was seen as a convolution of a rectangular fracture profile with a Gaussian point spread function.     

Drainage spacing regularity on a fault-block: A case study from the eastern Ruahine Range

Abstract:  Recent research has indicated river basin outlets draining linear sections of large, uplifting mountain belts often show a regularity of spacing, transverse to the main structural trend. A morphometric analysis of part of the Ruahine Range, on the North Island was undertaken to test whether drainage regularity may exist in smaller, younger mountain ranges. The ratio, R , of the half-width of the mountain belt, W , and the outlet spacing, S , was used to characterize drainage networks on the eastern side of the range. The spacing ratio for the range of 1.31 is lower than R results from studies of larger mountain belts ( R  = 1.91–2.23). We suggest the cause of this lower ratio is related to eastward migration of the Ruahine drainage divide.     

不同涂层的二氧化铅电极催化性能的比较

研究了热分解法和电沉积法制备二氧化铅电极的工艺,通过对苯酚的电解和生成羟基自由基的量,比较了两种方法制得的电极的催化性能,并比较了采用电沉积法制备电极时掺杂铋或镧对电极的催化性能的影响。实验结果表明,这4种电极都具有良好的电催化性能,并且明显降低了槽电压,且对苯酚的降解均符合一级反应动力学,电沉积法制得的电极的催化性能优于热分解法制得的电极,掺镧的电极优于无掺杂和掺铋的电极。     

Applicability of a Backprojection Algorithm to Reconstruct Images of Subsurface Horizontal Planes for Laboratory Experiments in Electrical Resistance Tomography

This paper describes the use of a backprojection algorithm to reconstruct subsurface images of the electrical resistivity in horizontal planes parallel to the surface. The algorithm can be applied to detect buried objects such as tanks or pipes and possible leakages from them. Two imaging strategies are compared: juxtaposition of vertical planes, and 3D reconstruction from the sensitivity matrix corresponding to the entire volume whose surface is explored. The electrode arrays used for voltage measurement are the dipole–dipole array and a modified Schlumberger array. A personal computer controls current injection, electrode switching, and voltage detection. The system injects 1 kHz, 20 V peak-to-peak square waveforms, thus avoiding electrode polarization effects. Experimental laboratory measurements show that the algorithm detects localized objects such as an insulating sphere and a conductive cylinder immersed in water. Furthermore, covering half of the cylinder by a rubber sleeve to simulate a nonconductive leak, yields a distinct image for the leak. The backprojection algorithm does not need any regularization parameter and it is very fast in inverting the sensitivity matrix because it approximates the inverse matrix by its transposed. The dipole–dipole array usually yields a lower overall pixel error than the modified Schlumberger array but both allow the detection of simulated underground leaks.     

基于Matlab的水准点稳定性分析

通过使用Matlab功能强大的数学软件，应用于测量工程的数据处理。具体解决变形监测中水准点是否稳定的判定问题。并通过计算实例说明其可行性和优越性。     

四极法电阻率测量在石油管道防腐蚀中的应用

土壤电阻率是地下石油管道一个重要的腐蚀性指标,因为管道的腐蚀程度和土壤电阻率的大小密切相关。本文介绍了四极法电阻率测量的原理和实施过程,并应用于某石油管道周围土壤的勘测,对测试数据做了处理和分析,为输油管道施工设计的防腐蚀提供了科学依据。     

含部分晶须的钛酸锂的制备及其性能表征

L i4T i5O12是一种循环性能好、有很好的充放电平台、理论比容量较大、不与电解液反应的新型负极材料,研究探索以偏钛酸和碳酸锂为主要原料制备含部分晶须的尖晶石型晶型L i4T i5O12的一种方法。通过此工艺在1 000℃煅烧8 h后在样品中约20%的晶须出现,晶须的直径≤0.5μm,晶须的长度约为7μm。     

Bragg reflection of water waves by multiple floating horizontal flexible membranes with submerged rectangular bars on the seabed

Bragg reflection of water waves by multiple floating horizontal flexible membranes is investigated based on the linear wave theory and the assumption of small membrane response. Under the floating horizontal membranes, periodical submerged rectangular bars are arranged on the flat seabed. The total reflection and transmission coefficients are obtained by using the eigenfunction expansion method and the wide spacing approximation. The calculated coefficients are validated with the results available in the literature, which shows that the present method is applicable. The characteristics of Bragg reflection are systematically investigated by changing various parameters including the height of the rectangular bars, the number, the tension, the spacing, and the length of the flexible membranes. The results can help designing multiple floating horizontal flexible membranes as effective floating breakwaters by taking advantage of Bragg reflection.     

大地电场观测深埋铅电极测量系统试验

为使用铅电极替代不极化电极,以解决滨海地区大地电场观测系统稳定性差的问题,先后开展了浅埋的铅电极与不极化电极的大地电场对比观测,以及深埋铅电极与浅埋铅电极的对比观测试验。结果表明:铅电极与固体不极化电极的观测数据在短期内有较好的一致性;深埋铅电极的大地电场观测资料在长期稳定性上优于固体不极化电极;而观测数据的内在观测质量也高于浅埋铅电极。