Evolutionary Processes in Low-Mass Binary Systems

We consider the evolution of certain low-mass binaries, incorporating models of (a) internal evolution, (b) tidal friction, (c) dynamo activity driven by an elementary α,Ω dynamo, (d) stellar wind driven by the activity, and (e) magnetic braking as a consequence of wind and poloidal dynamo-generated magnetic field. In some circumstances the stellar wind is found to remove mass on a nuclear timescale, as is necessary to explain some observed systems. We can hope that various uncertainties in the model may be clarified by a careful comparison of the models with such observed quantities as rotation periods. These are modified by processes (a), (b) and (e). Assuming that stellar evolution is slow, rotation rate should in some circumstances represent a balance between magnetic braking trying to slow the star down and tidal friction trying to spin it up. Preliminary attempts are promising, but indicate that some fine tuning is necessary. When there is a third body present, in an orbit which is inclined but not necessarily of short period, the eccentricity of a close binary can be strongly modified by ‘Kozai cycles’. We show that this may complicate attempts to account for spin rates of stars in close binaries.     

Ambipolar diffusion in the solar atmosphere

The process of non-linear ambipolar diffusion in the region overlying the solar surface can be an effective mechanism for producing sharp magnetic structures and current sheets. These may be the sites responsible for the occurrence of connectivity of magnetic field lines, and the subsequent explosive input of energy for heating of some of the features in the atmosphere of the Sun..     

Asymmetrically zoned reaction rims: assessment of grain boundary diffusivities and growth rates related to natural diffusion-controlled mineral reactions

This study explores garnet coronas around hedenbergite, which were formed by the reaction plagioclase + hedenbergite→garnet + quartz, to derive information about diffusion paths that allowed for material redistribution during reaction progress. Whereas quartz forms disconnected single grains along the garnet/hedenbergite boundaries, garnet forms ～20‐μm‐wide continuous polycrystalline rims along former plagioclase/hedenbergite phase boundaries. Individual garnet crystals are separated by low‐angle grain boundaries, which commonly form a direct link between the reaction interfaces of the plagioclase|garnet|hedenbergite succession. Compositional variations in garnet involve: (i) an overall asymmetric compositional zoning in Ca, Fe²⁺, Fe³⁺ and Al across the garnet layer; and (ii) micron‐scale compositional variations in the near‐grain boundary regions and along plagioclase/garnet phase boundaries. These compositional variations formed during garnet rim growth. Thereby, transfer of the chemical components occurred by a combination of fast‐path diffusion along grain boundaries within the garnet rim, slow diffusion through the interior of the garnet grains, and by fast diffusion along the garnet/plagioclase and the garnet/hedenbergite phase boundaries. Numerical simulation indicates that diffusion of Ca, Al and Fe²⁺ occurred about three to four, four and six to seven orders of magnitude faster along the grain boundaries than through the interior of the garnet grains. Fast‐path diffusion along grain boundaries contributed substantially to the bulk material transfer across the growing garnet rim. Despite the contribution of fast‐path diffusion, bulk diffusion through the garnet rim was too slow to allow for chemical equilibration of the phases involved in garnet rim formation even on a micrometre scale. Based on published garnet volume diffusion data the growth interval of a 20‐μm‐wide garnet rim is estimated at ～10³–10⁴ years at the inferred reaction conditions of 760 ± 50 °C at 7.6 kbar. Using the same parameterization of the growth law, 100‐μm‐ and 1‐mm‐thick garnet rims would grow within 10⁵–10⁶ and 10⁶–10⁷ years respectively.     

THERIA_G: a software program to numerically model prograde garnet growth

We present the software program THERIA_G, which allows for numerical simulation of garnet growth in a given volume of rock along any pressure–temperature–time (P–T–t) path. THERIA_G assumes thermodynamic equilibrium between the garnet rim and the rock matrix during growth and accounts for component fractionation associated with garnet formation as well as for intracrystalline diffusion within garnet. In addition, THERIA_G keeps track of changes in the equilibrium phase relations, which occur during garnet growth along the specified P–T–t trajectory. This is accomplished by the combination of two major modules: a Gibbs free energy minimization routine is used to calculate equilibrium phase relations including the volume and composition of successive garnet growth increments as P and T and the effective bulk rock composition change. With the second module intragranular multi-component diffusion is modelled for spherical garnet geometry. THERIA_G allows to simulate the formation of an entire garnet population, the nucleation and growth history of which is specified via the garnet crystal size frequency distribution. Garnet growth simulations with THERIA_G produce compositional profiles for the garnet porphyroblasts of each size class of a population and full information on equilibrium phase assemblages for any point along the specified P–T–t trajectory. The results of garnet growth simulation can be used to infer the P–T–t path of metamorphism from the chemical zoning of garnet porphyroblasts. With a hypothetical example of garnet growth in a pelitic rock we demonstrate that it is essential for the interpretation of the chemical zoning of garnet to account for the combined effects of the thermodynamic conditions of garnet growth, the nucleation history and intracrystalline diffusion. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.

Three-dimensional Layer-integrated Modelling of Estuarine Flows with Flooding and Drying

Details are given of the refinement and application of a thee-dimensional (3-D) layer-integrated numerical model of tidal circulation, with the aim of simulating severe tidal conditions for practical engineering applications. The mode splitting strategy has been used in the model. A set of depth-integrated 2-D equations are first solved to give the pressure gradient, and the layer-integrated 3-D equations are then solved to obtain the vertical distributions of the flow velocities. Attention has been given to maintaining consistency of the physical quantities derived from the 2-D and 3-D equations. A TWO=layer mixing length turbulence model for the vertical shear stress distribution has been included in the model. Emphasis has been focused on applying the model to a real estuary, which is geometrically complicated and has large tidal ranges giving rise to extensive flooding and drying. The model has been applied to three examples, including: wind-driven flow in a rectangular lake, tidal circulation in a model rectangular harbour, and tidal circulation in a large estuary. Favourable results have been obtained for both the simple and complex flow beds.     

利用双向缓冲区算法综合海图岛屿

阐述了岛屿综合的内容和原则。介绍了双向缓冲区算法的概念并给出了双向缓冲区算法的定义,研究并证明了双向缓冲区算法的特性。分析了利用双向缓冲区算法综合海图岛屿的原理,并通过实验验证利用双向缓冲区算法综合海图岛屿具有较好的效果。     

In situ estimation of the effective chemical diffusion coefficient of a rock matrix in a fractured aquifer

An in situ method of estimating the effective diffusion coefficient for a chemical constituent that diffuses into the primary porosity of a rock is developed by abruptly changing the concentration of the dissolved constituent in a borehole in contact with the rock matrix and monitoring the time-varying concentration. The experiment was conducted in a borehole completed in mudstone on the campus of the University of the Free State in Bloemfontein, South Africa. Numerous tracer tests were conducted at this site, which left a residual concentration of sodium chloride in boreholes that diffused into the rock matrix over a period of years. Fresh water was introduced into a borehole in contact with the mudstone, and the time-varying increase of chloride was observed by monitoring the electrical conductivity (EC) at various depths in the borehole. Estimates of the effective diffusion coefficient were obtained by interpreting measurements of EC over 34 d. The effective diffusion coefficient at a depth of 36 m was approximately 7.8×10^?6 m²/d, but was sensitive to the assumed matrix porosity. The formation factor and mass flux for the mudstone were also estimated from the experiment.     

Treatment of high fluoride concentration wastewater by layered double hydroxides： Mechanism studies

An appropriate concentration of fluoride in drinking water is required to prevent dental cavities, but long-term ingestion of water that contains more than a suitable level of fluoride can cause bone disease and mottling of the teeth. Fluoride ions can be found in wastewater from the fluoride chemical industry, as well as the semiconductor, metal processing, fertilizer, and glass-manufacturing industries. The discharge standard for fluoride in industrial wastewater in China is 10 mg/L. Efficient treatment of fluoride-containing wastewater is therefore of major concern in China, following the rapid development of the fluoride chemical industry. Several methods have been used to remove fluoride from water, such as adsorption, chemical precipitation, electrodialysis, ion exchange and electrochemical processes. Layered double hydroxides （LDHs） are anionic clays with high anion exchange capacities which are effective adsorbents for removal of a variety of anionic pollutants. LDHs have been studied as potential adsorbents for removing toxic anionic species such as CrO4^2-, TcO4^-, SeO3^2-, pesticides, and anionic surfactants from aqueous systems. One of the main attractions of using LDHs for fluoride removal, is that unlike other chemical treatment methods, no chemical sludge should be produced. In the present study, an attempt was made to investigate the mechanism of fluoride removal by LDHs under different conditions using batch methods. In addition, the release of fluoride adsorbed on LDHs by treatment with an aqueous solution of Na2CO3 was studied. The residual fluoride was found to be 10 mg/L in a solution with an initial concentration of 1000 mg/L, which meets the discharge standard for fluoride in industrial wastewater in China.     

惯性／双星组合导航系统的滤波与仿真

介绍了惯性导航系统和双星导航系统各自的运行方式和优缺点；详细推导了组合导航系统的误差方程和量测方程；介绍了Kalman滤波的整个过程并最后进行了仿真计算。仿真结果显示，惯性导航系统和双星导航系统的组合弥补了各自的不足，具有较好的精度和可靠性。