Transient biouptake flux and accumulation by microorganisms: The case of two types of sites with Langmuir adsorption

The uptake of a chemical species by an aquatic microorganism is modelled considering two kinds of sites where Langmuirian adsorption is followed by first order internalisation kinetics. Simpler models, such as only one internalisation route (while most of the adsorption takes place on non-internalising sites) or a linear isotherm for adsorption on one or both sites, become limiting cases of this double-Langmuirian model. The model considers the sites located on the spherical (or semi-spherical) surface of the organism, and takes diffusion from the medium into explicit account. The numerical solution for the internalisation flux shows a maximum. We provide an estimate for the time needed to reach a certain proximity to steady state. The transient solution confirms that the analytical expressions for the steady-state flux are usually valid and that the accumulated amounts reflect the impact of the short-time uptake. The Instantaneous Steady-State Approximation (ISSA), where an intercept of the linear regression of accumulated amount as a function of time is interpreted as an adsorbed amount, can be critically assessed with the transient numerical code for two cases: (i) when the total burden of metal on the cell is the input data and (ii) when an extraction procedure provides further information on the adsorbed and internalised amount.     

A comparison of three marine ecosystems surrounding the Korean peninsula: Responses to climate change

This study uses a comparative approach to examine responses of marine ecosystems to climatic regime shifts. The three seas surrounding the Korean peninsula, the Japan/East Sea, the East China Sea and the Yellow Sea represent three contiguous but distinct ecosystems. Sampling has been carried out by the National Fisheries Research and Development Institute of South Korea since 1965, using the same methods in all three seas. Sampling was generally synoptic. Amplitude time series of 1st EOF modes for temperature, salinity, zooplankton biomass and concentrations of four major zooplankton taxa were used to determine whether the three marine ecosystems respond in a similar manner to climate variations. Temporal patterns of the variables were strongly similar among the three seas at decadal time scales, but very weakly similar at interannual scales. All three seas responded to a climatic regime shift that occurred in 1989. Temperature, zooplankton biomass and copepod concentrations increased in the late 1980s or early 1990s in all three seas. Concentrations of amphipods, chaetognaths and euphausiids also increased in the Japan/East Sea and the East China Sea, but not the Yellow Sea. The Yellow Sea ecosystem differs strongly from the other two seas, and water exchange between the Yellow Sea and the East China Sea is much weaker than that between the East China Sea and Japan/East Sea. Spatial patterns of zooplankton determined by the EOF analysis were closely related to currents and fronts in each of the three seas.     

Evolution of cool skin and direct air-sea gas transfer coefficient during daytime

Absorption of solar radiation within the thermal molecular sublayer of the ocean can modify the temperature difference across the cool skin as well as the air-sea gas transfer. Our model of renewal type is based on the assumption that the thermal and diffusive molecular sublayers below the ocean surface undergo cyclic growth and destruction, the heat and gas transfer between the successive burst events are performed by molecular diffusion. The model has been upgraded to include heating due to solar radiation. The renewal time is parameterized as a function of the surface Richardson number and the Keulegan number. A Rayleigh number criterion characterizes the convective instability of the cool skin under solar heating. Under low wind speed conditions, the solar heating can damp the convective instability, strongly increasing the renewal time and correspondingly decreasing the interfacial gas exchange. In the ocean, an additional convective instability caused by salinity flux due to evaporation becomes of importance in such cases. The new parameterization is compared with the cool skin data obtained in the western equatorial Pacific during the Tropical Ocean Global Atmosphere Coupled Ocean Atmosphere Response Experiment in February 1993. In combination with a model of the diurnal thermocline it describes main features of the field data both in nighttime and daytime. Under low wind speed conditions (< 5 m s^-1) diurnal variations of the sea surface temperature due to the formation of a diurnal thermocline were substantially larger than those across the cool skin. Under wind speeds > 5 m s^-1, diurnal variations of the surface temperature due to the variations of the thermal molecular sublayer become more important.     

The tectonic regime in Italy inferred from borehole breakout data

In Italy, the horizontal stress directions are well constrained in many regions, but the tectonic regime is not well known because the stress magnitudes are unknown. Our intention is to improve the knowledge of crustal stress in Italy, both at shallow depth and in low seismicity areas. Therefore, we inferred the tectonic regime from the comparison between the depth of breakout occurrence and the physical properties of the rocks in 20 boreholes. The critical value of the maximum horizontal stress, for which the effective tangential stress at the borehole wall overcomes the rock strength to form breakouts, could be computed from rock strength and density. Comparing the theoretical stress distributions for different tectonic regimes with the depth distribution of breakout occurrence, it is possible to infer the tectonic regime that fits best to the breakout depth distribution. We investigated boreholes up to 6 km deep located in different tectonic environments over the Italian peninsula: the Po Plain, the Apenninic chain, the Adriatic foredeep and the Tyrrhenian Quaternary volcanic region. These wells are characterised by breakout data of good quality (A, B and C, according to World Stress Map quality ranking system). The results are in general agreement with the style of faulting derived from earthquake focal mechanisms and other stress indicators. Our results show a predominance of a normal faulting (NF) regime in the inner Apennines and both normal faulting and strike–slip faulting (SS) style in the surrounding regions, possibly also associated with changes in the tectonic regime with depth.     

Geothermal Regime of Meso-Cenozoic Basins and Their Tectonic Background in East China

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Seasonal and Diurnal Variation of Surface Ozone and a Preliminary Analysis of Exceedance of its Critical Levels at a Semi-arid Site in India

The mixing ratios of surface O₃ were measured at St. John's College, Agra, an urban and traffic influenced area for the period of 2000–2002. The monthly averaged O₃ mixing ratios ranged between 8 to 40 ppb with an annual average of 21 ppb. Strong diurnal and seasonal variations in O₃ mixing ratios were observed throughout the year except for monsoon season. The mixing ratios of O₃ follow the surface temperature cycle and solar radiation (r = 0.72 and r = 0.65 with temperature and solar radiation, respectively). Concentrations were higher with winds associated with NE and NW direction indicating the impact of pollution sources on surface O₃ concentration. Exceedance of ozone critical level was calculated using the AOT 40 index and found to be 840 ppb.h and 2430 ppb.h for summer and winter seasons, respectively. The present O₃ exposures are lower than the critical level of O₃ and suggest that the present level of O₃ does not have any impact on reduction in crop yields.     

乌拉苔草光合速率日变化及日同化量

乌拉苔草沼泽是长白山沟谷湿地的重要类型 ,对其光合速率研究的结果表明 ,乌拉苔草光合速率日变化呈单峰曲线 ,最高峰出现在 1 0时 ,最大值是 1 8.0 7μmol(CO2 ) / (m2 ·s) ;与其该群落伴生的修氏苔草光合速率日变化出现“午休”现象。影响光合速率最大的环境因素是光量子通量密度和叶温 ,呈极显著的正相关 ,其他因素亦多呈正相关 ,环境因子综合影响了乌拉苔草的光合日进程。乌拉苔草光合作用的日总同化量为 1 896 0 1 .2 μmol(CO2 ) /m2 ,是光合能力较强的一种沼泽植物     

黑河流域水环境演变及其驱动机制研究进展

基于近几十年来诸多学者对西北干旱区典型内陆河流域——黑河流域水环境演变诸方面研究成果,综述了上游山区成水环境、中游绿洲用水环境和下游荒漠天然绿洲水成环境在不同时间尺度上的演变过程及其驱动机制。通过对各种古环境代用指标的对比研究表明：在大尺度上,流域上下游表现出阶段性的一致性水环境演变趋势;在小尺度上,则表现水环境演变的时空异质性。驱动机制方面,在空间上,流域上、中、下游水环境演变的气候变化和人类活动影响驱动作用各有侧重;在时间上,表现为不同尺度上气候变化与流域人类活动耦合作用的驱动机制。     

目标函数聚类法在地下水动态分类中的应用

地下水动态类型的划分是正确认识研究区水文地质条件与地下水开发利用之间关系的一个重要环节。本文论述了目标函数聚类法的原理与计算过程,并应用该方法对某河流附近的１５个观测孔的水位动态进行分类。分析结果表明该方法具有较高的可靠性与较广的适用性。