Wave Decay and Its Characteristics in Surf Zone

In accordance with the similarity between breaking waves and hydraulic jumps, the expressions for estimating wave decay and wave energy dissipation in the surf zone are derived based on the fundamental equations of fluid mechanics. Using the numerical solution of cnoidal wave theory, the various kinematic properties of waves in the surf zone, including the relative wave crest height, wave energy, and radiation stress are discussed. The values calculated with the method proposed in this paper are in good agreement with the experimental data gained by other researchers. The present expressions can be used in the studies of sediment transport on gently sloping beaches, especially on muddy beaches.     

Scattering of Semidiurnal Internal Kelvin Wave at Step Bottom Topography

A three-dimensional, multi-level model was used to study the energy dissipation of semidiurnal internal Kelvin waves due to their interaction with bottom topography. A simplified topography consisting of a channel with an additional shallow bay was used to clarify the wave’s scattering process. When the first mode semidiurnal internal wave given at an open boundary arrives at the bay mouth, higher-mode internal waves are generated at a step bottom of the bay mouth. As a result, the energy of the first mode internal Kelvin wave is effectively decayed. The decay rate of the internal Kelvin wave depends on both the width and length of the additional bay. The maximum decay rate was found when a resonance condition occurs the bay, that is, the bay length is equal to a quarter of wave length of the first mode internal wave on the shallow region. The decay rate in the wide bay cases is higher than that in a narrow case, due to a contribution from the scattering due to the Poincare wave that emanates from the corners of the bay head. The decay rate with the additional bay is 1.1–1.8 times that of the case without the additional bay. The decay rate due to the scattering process is found to be of the same order as that of the internal and bottom friction.     

闽南近海常见鲨鳐类肝油的四种理化常数和角鲨烯含量

本文分析测定了闽南近海常见鲨鳐类肝油的理化常数和角鲨烯含量。尖头斜齿鲨肝油的碘值特别高，说明其中脂肪酸的不饱和程度很高；非皂化物含量很低，约占肝油重的38×10－3（m／m）；角鲨烯含量极微，在肝油中仅占84×10－5（m／m）。闽南近海常见鲨鳐类肝油的角鲨烯含量均很低，变化在（31～116）×10－5（m／m）之间。在相同的气相色谱条件下，小孔沙条鲨和狭纹虎鲨肝油中没有检测到角鲨烯。     

Complexation of mercury by dissolved organic matter in surface waters of Galveston Bay, Texas

The chemical speciation of dissolved mercury in surface waters of Galveston Bay was determined using the concentrations of mercury-complexing ligands and conditional stability constants of mercury-ligand complexes. Two classes of natural ligands associated with dissolved organic matter were determined by a competitive ligand exchange-solvent solvent extraction (CLE-SSE) method: a strong class (L_s), ranging from 19 to 93 pM with an average conditional stability constant (K_HgLs) of 10²⁸, and a weak class (L_w) ranging from 1.4 to 9.8 nM with an average K_HgLs of 10²³. The range of conditional stability constants between mercury and natural ligands suggested that sulfides and thiolates are important binding sites for dissolved mercury in estuarine waters. A positive correlation between the estuarine distribution of dissolved glutathione and that of mercury-complexing ligands supported this suggestion. Thermodynamic equilibrium modeling using stability constants for HgL, HgCl_x, Hg(OH)_x, and HgCl(OH) and concentrations of each ligand demonstrated that almost all of the dissolved mercury (> 99%) in Galveston Bay was complexed by natural ligands associated with dissolved organic matter. The importance of low concentrations of high-affinity ligands that may originate in the biological system (i.e., glutathione and phytochelatin) suggests that the greater portion of bulk dissolved organic matter may not be important for mercury complexation in estuarine surface waters.     

Equilibrium constants of triethanolamine in major seawater salts

Acid–base equilibrium constants of triethanolamine (TEA) have been determined by potentiometric titrations with a glass electrode, at 25 °C. Ionic strength was kept constant with only one electrolyte (using one of these salts: NaCl, KCl, MgCl₂ or CaCl₂), with binary mixtures of MgCl₂ and CaCl₂, and finally, in a solution with a composition approximately similar to that of natural seawater without sulfate. Equilibrium constants have been expressed in function of ionic strength by means of Pitzer equations and interaction parameters proposed in this theory have been obtained. It has been found that acid–base behaviour of TEA depends greatly on the salt used: basicity of TEA is decreased by CaCl₂, while it is increased by the other electrolytes used in this work.     

水波在软淤泥底床上的衰减

本文研究了二层流体系统中波浪的衰减。上层为理想流体，下层为粘弹性Ｖｏｉｇｔ体。导出了色散关系，计算了波浪衰减系数。对于粘性或弹性很大或很小的情况，导出了各种水深情况下近似的显式的衰减系数表示式。与精确的数值结果比较，近似程度很好。可供工程设计参考、使用。     

厦门潮间带表层沉积物天然放射系不平衡研究

用HPGeγ谱仪测定了厦门潮间带表层沉积物中的放射性核素,得到11种核素238U2、34Th2、26Ra2、22Rn2、10Pb2、28Ra2、28Ac2、28Th2、24Ra2、12Pb、40K的平均比活度分别为:40.2、82.7、32.4、28.9、94.2、69.3、57.1、71.6、64.0、71.4、692Bq/kg.结果表明潮间带沉积物中天然放射系不平衡,其中234Th相对于238U2、10Pb相对于226Ra过剩,222Rn相对于226Ra2、28Ac相对于228Ra2、24Ra相对于228Th亏损.     

近58a来影响和登陆浙江的热带气旋统计特征分析

本文利用1949-2006年热带气旋资料,对58a来影响和登陆浙江热带气旋的登陆位置、登陆时间的年际、月际和日变化、登陆后的移速及路径变化与降水中心分布的关系、登陆后维持和衰减情况等进行了统计分析.统计结果表明：影响和登陆浙江的热带气旋有较明显的年际、月际和日变化特征;登陆浙江的热带气旋陆上维持时间与登陆时的强度正相关,登陆后12h内热带气旋衰减较快;登陆后移向偏北分量大的或移速加快的热带气旋,主要降水区出现在路径右侧的可能性大.     

三种类型烃-烃不混溶包裹体组合的特征和热力学条件的计算

在自然界广泛分布着烃-烃不混溶体系中捕获的流体包裹体,由于这些包裹体具有复杂的组成和相态,因此不混溶包裹体组合的判别和热力学参数的计算常常难以进行。根据烃-烃不混溶体系中两个端员组分流体包裹体室温下的相态特征和在温度-压力平面图上等容线交点显示的位置,划分成三种类型流体包裹体组合,本介绍了三种类型流体包裹体组合特征,叙述了不混溶烃-烃包裹体组合的测定和判别方法,并且阐述均一化包裹体相态方程和气-液平衡常数原理和方法与此同时列举了自然界简单的三种类型不混溶烃-烃包裹体组合的测定、判别和计算的几个实例,利用相态方程和气-液平衡常数,不但精确地计算出包裹体均一压力,并且精确地计算出流体密度和体积等热力学参数。最后,利用均一成气相和液相的两种包裹体在 p-T 平面图上等容线交点同样计算出流体包裹体组合的捕获温度和压力。     

裂隙型单斜介质中弹性系数的计算及波的传播特性研究

根据Hudson等关于裂隙介质弹性系数计算的扰动理论及Bond变换矩阵原理，给出了各向同性介质中含多组垂直裂隙时等效弹性系数的计算方法。计算了含两组斜交的垂直裂隙形成的单斜各向异性介质中的等效弹性系数，并根据Christoffel方程推导、得出水平面内平面波传播的相速度和群速度随方位变化的特性。