液核地球自转速率变化的带谐潮效应Ⅱ--数值计算与比较

地球自转速率的潮汐变化可由无量纲参数k/cm)(k和cm分别为壳幔的有效Love数和有效极转动惯量)来表征。对于一个具有弹性地幔、平衡海潮和核幔不耦合的地球k/cm=0.944,且与潮波频率无关。海潮的非平衡扰动使k/cm为复数,且与频率有关。大气对自转速率有效勒夫数的贡献约为Δkat=0.0075。同时地幔滞弹性对勒夫数也产生扰动。利用本文得到的理论公式和最新的潮汐数据计算了地球自转速率的潮汐变化,及其有关地球物理机制的影响。     

Anthropogenic trace metals in an ice core at Vestfonna,Svalbard, Norway

1　IntroductionAnicecoreobtainedfrom polarglaciersoricesheetsisoneofthemostimportantarchivestoreconstructpaleoclimaticandpaleoatmosphericcondition .Informationonpale o environmentcanbeextractedfromicecoresaschemicaland/orphysicalsignals.Amongthechemicalsignals,heavymetalsarenotedassignalsofterrestrialenvironmentalchangeandanthropogenicpollution (e.g .Murozumietal.1 969;NgandPatterson 1 981 ;Hongetal.1 994) .SinceconcentrationsofmostofthemetalsinpolarsnowincentralGreen landareatorbelowthepptl…     

Metamorphic evolution of exhumed middle to lower crustal rocks in the Mojave Extensional Belt, southern California, USA

The Waterman Metamorphic Complex of the central Mojave Desert was exposed as a consequence of early Miocene detachment-dominated extension. However, it has evidence consistent with a more extensive geological history that involves collision of a crustal fragment(s), tectonic thickening by overthrusting and two periods of extension. The metamorphic complex contains granitoid intrusives and felsic mylonitic gneisses as well as polymetamorphic rocks that include marble, calc-silicate, quartzite. mafic granulite, pyribolite, amphibolite, migmatite and biotite schist. The latter group of rocks was affected by an initial series of high-grade metamorphic events (M1 and M2) and a localized lower grade overprint (M3). The initial metamorphism (M1) can be separated into two stages along its high-grade P–T path: M1a, a granulite facies metamorphism at 800–850° C and 7.5–9 kbar and Mlb, an upper amphibolite facies overprint at 750–800° C and 10–12 kbar. M1a developed mineral assemblages and textures consistent with granulite facies conditions at a reduced activity of H₂O and is associated with intense ductile deformation (D1) and minor local partial melting. M1b overprinted the granulite assemblages with a series of hydrous phases under conditions of increasing pressure and H₂O activity and is accompanied by little or no deformation. M2 developed at lower pressures and temperatures (650–750° C, 4.5–5.5 kbar) and is distinguished by a second local overprint of hydrous phases that reflects an input of aqueous fluids probably associated with the intrusion of a series of granitic dykes and veins. Effects of M3 are confined to the Mitchel detachment zone, an anastomosing early Miocene detachment fault, and are characterized by local ductile/brittle deformation (D2) of the pre-existing high-grade rocks and granitoid intrusives and by the production of mylonites and mylonitic gneisses under greenschist facies conditions (300–350° C, 3–5 kbar). The initial overprint (M1a) represents metamorphism, devolatilization and minor partial melting of supracrustal rocks under granulite facies conditions as a consequence of tectonic and, possibly, magmatic thickening. The increasing pressure transition of M1a to M1b reflects a period of continued compressional tectonism, thrusting and influx of H₂O, in part, locally related to crystallization of partial melts. The near isothermal decompression between M1b and M2 probably represents a pre-112-Ma extensional episode that may have been the result of a decompressional readjustment of a thickened crust. Following the initial extensional event, the metamorphic complex remained at depths of 10–17 km for at least 90 Ma until it was uplifted following Miocene extension. M3 develops locally in response to this second extensional period resulting from the early Miocene detachment faulting.     

南极威尔克斯地SGR钻孔处雪冰转化过程中的密度变化特征

本文着重描述了SGR钻孔处冰盖上的积雪在密实化过程中的特征变化,并对该过程进行了分段的和全面的回归分析.结果表明,冰盖密度随深度增大,但增长幅度随深度减小.作者提出密度变化减小度的概念.计算得出的所研究冰芯钻取点的密度变化减小度为-0.15kg/m~3·m~2,粒雪成冰前的密实速率平均值为4.08kg/m~3·a.本文得到的冰盖密度变化“临界点”与以往报道的有所不同.分析这一现象时,作者强调当积雪还在活动层时冰盖温度的影响,并以此解释密度剖面的异常变化以及离差的回升.特别指出,积雪的密度变化具有气候学意义,它在一定程度上能够反映出积雪形成及变化过程中气候变化的某些信息.本文由密度变化确定的钻孔点雪冰转化深度为50米.     

氢化物发生-原子荧光光谱法直接测定地球化学样品中痕量碲

采用硝酸-氢氟酸-高氯酸溶解样品,以Fe3+作减缓剂,不需分离富集,用氢化物发生-原子荧光光谱法直接测定地球化学样品中痕量碲。对测定介质、KBH4浓度、铁盐的作用等条件进行试验。方法检出限为0.0031μg/g,精密度(RSD,n=11)<6.10%。方法用于国家一级地球化学标准物质中痕量碲的测定,结果与标准值一致。     

碱消解-高效液相色谱-电感耦合等离子体质谱法测定生物样品中的甲基汞和乙基汞

建立了碱消解-高效液相色谱-电感耦合等离子体质谱联用系统测定生物样品中甲基汞(MeHg)与乙基汞(EtHg)的分析方法。为提高灵敏度,选用微流量的PFA雾化器,在优化的检测条件下,MeHg及EtHg检出限可达到0.036μg/L和0.03μg/L;线性范围达到4个数量级,两条工作曲线线性相关系数为1。对1.78μg/L MeHg、1.65μg/L EtHg的混合标准溶液重复测定7次,色谱峰面积的相对标准偏差(RSD)分别为1.79%和1.44%。对标准物质BCR 464(金枪鱼)的分析结果表明,测定值与标准值基本吻合,但略低于标准值;甲基汞和乙基汞的加标回收率分别为85.9%和84.5%。高效液相色谱与质谱联用技术的高灵敏度和低检出限能够满足生物样品中汞形态定量分析的要求。     

存储式岩心定向取心技术应用研究

采用岩心定向取心技术不仅可以迅速而方便地确定地下矿层和结构面的产状,而且还可以判断矿层的走向,了解地层倾向,预测钻孔弯曲的趋势。介绍了存储式岩心定向取心原理、关键技术问题、器具构成、技术参数以及现场应用情况。     

台湾海峡西部柱状沉积物粘土矿物的分析

根据台湾海峡西部10个柱102个样品的X 射线衍射等分析,鉴定了该区粘土矿物组合与含量变化,分析了其与沉积环境的关系.结果表明,该区粘土矿物组合大多数站位以伊利石含量占首位,绿泥石和高岭石次之,且含少量蒙脱石;伊利石含量随距岸、水深的增加而递增,高岭石则反之;蒙脱石含量与火山活动密切相关,绿泥石含量呈斑块状分布;775和819号站有典型的陆相层,为早玉木冰期的“台湾陆桥”或“东山陆桥”提供有力证据.     

冰心中的气候环境记录与全球变化研究

冰心是高分辨地记录全球变化的主要信息载体之一。本文总结了冰心中提取古气候和古环境信息的系列记录，包括同位素、微量气体、阴阳离子、微粒、生物和有机质等。着重讨论了由这些记录提取的古气候和古环境变化方面的研究进展，并提出了今后的研究重点。     

A community-wide intercomparison exercise for the determination of dissolved iron in seawater

The first large-scale international intercomparison of analytical methods for the determination of dissolved iron in seawater was carried out between October 2000 and December 2002. The exercise was conducted as a rigorously “blind” comparison of 7 analytical techniques by 24 international laboratories. The comparison was based on a large volume (700 L), filtered surface seawater sample collected from the South Atlantic Ocean (the “IRONAGES” sample), which was acidified, mixed and bottled at sea. Two 1-L sample bottles were sent to each participant. Integrity and blindness were achieved by having the experiment designed and carried out by a small team, and overseen by an independent data manager. Storage, homogeneity and time-series stability experiments conducted over 2.5 years showed that inter-bottle variability of the IRONAGES sample was good (< 7%), although there was a decrease in iron concentration in the bottles over time (0.8–0.5 nM) before a stable value was observed. This raises questions over the suitability of sample acidification and storage.