预防油页岩地层钻进中压差卡钻的措施

分析了油页岩地层钻进中压差卡钻发生的原因,提出了预防压差卡钻的途径及处理方法,并通过工程实例来强调预防为主的重要性。     

安徽省耿皇勘探区煤系地层沉积环境及成煤条件浅析

以耿皇勘探区钻孔资料为基础,对该区煤系地层沉积环境及成煤条件进行分析,简述了本区煤系地层是在海退基础上,以三角洲为主体的三角洲相与泻湖海湾潮坪相相互交替的沉积体系,通过对该特点的分析研究,为今后地质勘探和煤矿开采提供了借鉴和依据。     

黑色页岩与土壤重金属污染

本文利用ICP—MS等技术分析了湘中地区黑色页岩及其相应土壤的重金属含量,在对分析结果进行统计分析的基础上,探讨了黑色页岩与土壤重金属污染的关系。研究表明,黑色页岩是富集多种重金属元素的特殊岩石。以黑色页岩岩系为母岩的土壤,不仅明显富集Cu、Cd、Cr、Co、Pb、Zn、Mo、Ni、V、U、Sn、Sb、T1、Th等多种重金属元素,而且受到Mo、Sb、Cd、U、Tl、Cu、V、Sn、Th等重金属的污染,其中以Mo、Cd、Sb、U、Tl等的污染尤为严重。黑色页岩土壤重金属污染在一些地方已产生明显的负面环境效应,值得关注。     

寒武系古流体地球化学特征及其对页岩气保存的指示意义 ——以中扬子地区寒武系页岩气发现井宜地2井为例

保存条件是中扬子地区页岩气富集的关键因素之一，宜地2井是中扬子寒武系页岩气发现井，通过对该井全井段岩芯裂缝古流体的地球化学分析，探讨了寒武系古流体成因和对水井沱组页岩气保存条件的指示意义。结果认为：① 覃家庙组膏岩层之上方解石脉缺少Fe2+、Mn2+，且δ13C和δ18O值较围岩偏负，指示其形成于氧化的环境，石牌组方解石脉δ13C偏负，黄铁矿脉δ34S值与膏盐相似，表明其成因与TSR密切相关；水井沱组脉体δ13C和δ18O与围岩相似，形成于封闭的环境。② 方解石脉包裹体群SO42-、Ca2+、Mg2+含量整体上由覃家庙组向上向下分别递减，钠氯系数以水井沱组最低，整体上向上升高，表明覃家庙组是高盐度卤水的主要来源，水井沱组受外来流体影响弱；包裹体水溶液δD和δ18O也指示娄山关组、石牌组方解石脉成因分别与大气水、TSR相关。③ 古流体地球化学研究表明宜昌地区页岩气保存条件整体较好，页岩气散失的主要通道是垂直裂缝，页岩气保存条件好与膏盐盖层发育、后期构造破坏弱、脉体对裂缝的及时封闭以及白垩系盖层等因素密切相关。     

Geochemistry of soils derived from black shale, central Hunan, China

The black shale formed under anoxic conditions usually contains high concentrations of many metals. Weathering of such black shale might cause the emission of many metals. Moreover, soils derived from black shale （SBS） are believed to be affected by black shale weathering. In recent years, many studies such as Lee et al. （2002）, Woo et al. （2002）, Fang et al. （2002）, Pasava et al. （2003）, and Peng et al. （2004） have approached the heavy metal contaminations of SBS, but systematical geochemical study is rare. Presently, the SBS and its corresponding black shales （CBS） were both sampled from central Hunan （China）, and analyzed for a large number of elements, using an Elan6000 ICP-MS/AES machine at Guangzhou Institute of Geochemistry, CAS. In this paper, some preliminary results are reported. The analytical results show that the SBS in central Hunan contains very high concentrations of heavy metals such as Co, Cu, Hg, Mo, Pb, Zn, U, Th, Sb, T1, Cd, Cr, Sc, V, Sn, As, Se, and Ni.     

Attenuation of aqueous metal transport at two natural acid rock drainage occurrences in the Yukon Territory, Canada

Naturally acidic drainage associated with pyritic black shale has been observed in many locations in the Yukon Territory. While not necessarily linked to known mineral deposits, most of these natural acid rock drainage occurrences show elevated dissolved concentrations of trace elements, especially zinc, nickel, copper, cadmium and arsenic. Based on field observations, microbial investigation, chemical analyses and geochemical modeling, the fate and transport of potentially deleterious elements at two natural acid drainage occurrences with slightly different settings are examined. The Macintosh Creek is a small, acidic stream （pH 2.98-3.40）, 2 km long, located in the Macmillan Pass area of east-central Yukon amidst known sedimentary exhalative massive sulfide mineralization but remains undisturbed by exploration activities. Its trace metal content is apparently derived from groundwater discharges, which gave as much as 5.0, 2.5, 0.7, 0.13 and 0.03 mg/L ofZn, Ni, Cu and As, respectively. Interaction and sorption reactions with algal mats, biofilms and iron oxyhydroxides appear to be the dominant mechanisms attenuating aqueous contaminant transport along the stream. Cryogenic precipitation further consolidates the ferricrete formation and reduces the mobility of the sorbed metals. The tributaries of the Engineering Creek along the Dempster Highway in northern Yukon drain through a series of dolomite, phyllite, argillite, limestone, black shale, sandstone and conglomerate with no known concentration of mineralization. In this area, the water chemistry fully reflects the local geology with acidic streams invariably associated with black shale occurrences. Groundwater seeps in the headwaters area of the km-180 Creek completely enclosed in black shale gave pH 3.0 and as much as 148, 39, 2.9 and 9.1 mg/L of Zn, Ni, Cu and As, respectively. Sorption with iron oxyhydroxide and organic matter appear to dominate the attenuation of contaminant transport along the stream. However, once entered into carbonate-dominated terrains, secondary carbonate minerals exercise additional geochemical control on the local water chemistry as a result of neutralization.     

油页岩综合利用对周围环境的影响——以抚顺矿区为例

世界能源日益减少的局面为油页岩的开发应用带来广阔的前景，但油页岩工业所带来的环境影响亦不容忽视。以抚顺油页岩为例，从油页岩综合利用和油页岩工业对环境的影响等方面系统讨论了在我国发展油页岩工业时，如何本着节约能源、保护环境、实现可持续发展的观念，利用现有先进技术，科学发展油页岩工业，降低生产过程中的固、液、气污染物对环境的危害。     

机械研磨对平鲁煤系高岭石热行为的影响

对煤系高岭石进行0-2h的研磨之后，再在900℃、1000℃、1400℃的温度条件下分别对其加热1h，然后利用X射线衍射（XRD）、差热分析（DTA）、红外光谱（IR）等手段，研究机械研磨对于煤系高岭石晶体结构的破坏作用以及对其热行为的影响。结果显示，煤系高岭石被研磨1h之后，高岭石的晶体结构几乎全部跨塌。把研磨1h的煤系高岭石加热到1000℃（加热1h），便能形成结晶良好的莫来石。     

遵义市城区及周边地带制砖页(泥)岩地质特征和开发前景

文章对遵义市城区及周边地带各地质时代的页（泥）岩已有资料进行了系统收集、归纳和适当的野外调研，认为区内制砖页（泥）岩层位可分为三类，第一、二类利用价值小或仅有部分可以利用，第三类则易于露采，大部分可利用，其层位为下奥陶统湄潭组和下三叠统夜郎组九级滩段，是区内可作制砖页（泥）岩利用最有开发前景的层位。同时对页（泥）岩的形成沉积环境作了简要分析，对其资源量进行了概略估算，经优化筛选，提出了10个供制砖厂企设置布局和矿源地选择之前需进行地质勘查的区块。     

遵义牛蹄塘组发现的多水硫磷铝石

遵义牛蹄塘组黑色岩系发现的多水硫磷铝石主要产出在Ni-Mo多金属层的微裂隙中，偶尔在多金属层下部的黑色粉砂岩中以脉体形式产出。该矿物结构不稳定，结构中一部分水分子很容易失去，在X射线衍射鉴定时其特征谱线变化较大；在自然条件下存放一定时间后，样品具有稳定的X射线衍射特征。此外，对这些样品进行了红外光谱、热重和差热分析、TEM观测、化学分析和晶胞参数计算，与纤磷铝石进行了对比和讨论。