γ射线暴的研究进展（Ⅳ：特强γ射线暴和软γ重复暴

最近CGRO上的仪器观测到了两个迄今为止发现的最强的λ暴GB930131和GB940217,其光子最高能量均达GeV量级;GB930131的峰值计数率达2×10~6个光子s~(-1);而GB940217的持续时间竟长达90min。另外沉寂了多年的软重复暴源SGR1900 14和SGR1806-20的再次爆发也由BATSE发现。一系列的观测还发现这些软重复暴均与X射线源对应且与超新星遗迹成协。文中对特强暴和软重暴(SGR)的性质及研究进展作了较为详细的评述。     

Optical Flash of GRB 990123: Constraints on the Physical Parameters of the Reverse Shock

The optical flash accompanying GRB 990123 is believed to be powered by the reverse shock of a thin shell. With the best-fit physical parameters for GRB 990123 and the assumption that the parameters in the optical flash are the same as in the afterglow, we show that: 1) the shell is thick rather than thin, and we have provided the light curve for the thick shell case which coincides with the observation; 2) the theoretical peak flux of the optical flash accounts for only 3×10~-4 of the observed. In order to remove this discrepancy, the physical parameters, the electron energy and magnetic ratios, εe and εB, should be 0.61 and 0.39, which are very different from their values for the late afterglow.     

Sequences in the Hardness Ratio-Peak Energy Plane of Gamma-Ray Bursts

The narrowness of the distribution of the peak energy of the vFv spectrum of gamma-ray bursts (GRBs) and the unification of GRB populations are great puzzles yet to be solved. We investigate the two puzzles based on the global spectral behaviors of different GRB populations, the long GRBs, the short GRBs, and the X-ray flashes (XRFs), in the HR - Ep plane (HR the spectral hardness ratio) with BATSE and HETE-2 observations. It is found that the long GRBs and the XRFs observed by HETE-2 seem to follow the same sequence in the HR-Ep plane, with the XRFs at the low end of this sequence. We fit the sequence by a universal Band function, and find that this sequence is mainly defined by the low energy index α, and is insensitive to the high energy index,β. With fixed β=-5, a best fit is given by α=-1.00 with X^2min/dof=2.2. The long and short GRBs observed by BATSE follow significantly different sequences in the HR-Ep plane, with most of the short GRBs having a larger hardness ratio than the long GRBs at a given Ep. For the long GRBs a best-fit yields α=-0.30 and β=-2.05. For the short GRBs, a best fit gives α=-0.60 with x^2min=1.1 (withβfixed at-2.0 because it is numerically unstable). The α value for the short GRBs is significantly greater than that for the long GRBs. These results indicate that the global spectral behaviors of the long GRB sample and the XRF sample are similar, while that of the short GRBs is different. The short GRBs seem to be a unique subclass of GRBs, and they are not the higher energy extension of the long GRBs.     

The klein–nishina Effects in Blazar Jets

Blazars are the only (with one or two exceptions) extragalactic objects which were detected and identified at gamma-ray energies so far. It is suspected that most of the unidentified gamma-ray sources may be the blazars as well. Because the entire electromagnetic spectrum of these objects is dominated by non-thermal radiation from relativistically moving jets, the effects such as the Klein–Nishina regime in the Compton scattering may play a major role in shaping some parts of the blazar spectrum. Within the framework of external radiation Compton model, we present how these effect influence the spectra of blazars for which the production of gamma rays is dominated by Comptonization of external radiation.     

雾化进样石墨炉原子吸收光谱法的研究 Ⅰ.直接雾化进样装置及其性能

介绍一种自行设计和加工的直接雾化石墨炉进样装置的结构、工作原理和操作方法。该装置由微机控制与石墨炉加热程序同步工作,可以实现自动控制和自动测量。对雾化进样石墨炉分析的仪器参数和实验条件进行了研究和选择。结果表明,该装置与石墨炉结合具有自动化程度高、重现性好、样品利用率高和分析速度快等特点。     

电感耦合等离子体质谱法同时测定地下水中硼溴碘

建立了电感耦合等离子体质谱法同时测定地下水中B、Br、I的方法。选定φ=2%(体积分数)的稀NH3.H2O介质消除碘的记忆效应。采用干扰较少的10B和79Br同位素。B、Br、I在0~10 000 ng/mL呈良好的线性关系。方法的检出限为10B 0.176 ng/mL,79Br 0.876ng/mL,127I 0.132 ng/mL;精密度(RSD,n=12)为10B 2.86%,79Br 3.36%,127I 2.69%;10B的阶梯加标回收率为94.6%~101.5%,79Br为98.3%~104.9%,127I为96.5%~102.0%。     

电感耦合等离子体发射光谱法同时测定玻璃中铝钙铁钾镁钠钛硫

通过选择分析谱线、处理样品方法和消除干扰因素等实验,建立了电感耦合等离子体发射光谱法同时测定玻璃中的Al2O3、CaO、Fe2O3、K2O、MgO、Na2O、TiO2和SO3的方法,克服了利用常规化学法测定玻璃中各氧化物步骤繁琐、耗时长、工作量大的不足。方法的回收率为95.0%~103.0%,精密度(RSD,n=10)为0.20%~1.72%。方法具有快速、简便、线性范围宽等优点,分析误差满足常规化学分析法的要求。用于钠钙硅玻璃及其制品的分析,结果令人满意。     

氢化物发生-原子荧光光谱法直接测定地球化学样品中痕量碲

采用硝酸-氢氟酸-高氯酸溶解样品,以Fe3+作减缓剂,不需分离富集,用氢化物发生-原子荧光光谱法直接测定地球化学样品中痕量碲。对测定介质、KBH4浓度、铁盐的作用等条件进行试验。方法检出限为0.0031μg/g,精密度(RSD,n=11)<6.10%。方法用于国家一级地球化学标准物质中痕量碲的测定,结果与标准值一致。     

纺织品中偶氮染料还原液内芳香胺的电喷雾电离质谱分析

在优化的条件下,用电喷雾电离质谱(ESI-MS)检测了多种纺织品中由偶氮染料还原获得的芳香胺。当毛细管温度为100℃、鞘气流速为25单位、进样流速为10μL/min、电压为5kV时,信号的总离子流强度高且较稳定。实验分析了19种致癌芳香胺标准溶液的二级质谱,获得了相应物质的特征碎片离子;在此基础上,建立了基于ESI-MS对毛巾、棉布等样品中芳香胺进行快速定性分析的方法,具有灵敏度高、特异性好、检测速度快等优点。     

能量色散X射线荧光光谱法测定钼矿石中钼铅铁铜

建立了能量色散X射线荧光光谱法测定钼矿石中钼、铅、铁、铜的方法,讨论了粒度效应、矿物效应的影响因素,确定了采取粉末样品,用系列标准样品建立工作曲线,通过元素间相互校正消除基体效应,用内控标准样品考察了方法的精密度(RSD,n=11)为0.44%～15.4%。实际样品的测定结果和化学法相符,可满足日常分析工作需要。