Flotation and depression control of arsenopyrite through pH and pulp redox potential using xanthate as the collector

The role of pH and pulp redox potential (E_H) to control the flotation and depression of arsenopyrite has been investigated through studies on microflotation of arsenopyrite crystals and batch flotation of an arsenopyritic ore using isopropyl xanthate as collector. The transition between flotation and depression of arsenopyrite is established by the reversible potential of the xanthate/dixanthogen couple. Adsorption of arsenate ions on ferric hydroxide has been studied through electrokinetics to delineate mechanisms involved in the depression of arsenopyrite using oxidants. Chemical binding between arsenate species and ferric hydroxide sites on arsenopyrite is suggested as the mechanism responsible for depression of arsenopyrite. E_H conditions are given for the flotation and depression of arsenopyite at various pH values for the arsenopyritic ore.     

环境矿物材料治理镉（Cd^2＋）污染研究进展

近年来,环境矿物材料以其经济、有效、无二次污染等特点,在重金属废水处理和土壤修复方面显示出了众多优势,可替代传统的镉污染处理方法。本文综述了国内外环境矿物材料在处理镉污染方面的研究进展,并对今后应用环境矿物材料治理镉污染提出了一些建议。     

Effects of detailed soil spatial information on watershed modeling across different model scales

Hydro-ecological modelers often use spatial variation of soil information derived from conventional soil surveys in simulation of hydro-ecological processes over watersheds at mesoscale (10–100 km²). Conventional soil surveys are not designed to provide the same level of spatial detail as terrain and vegetation inputs derived from digital terrain analysis and remote sensing techniques. Soil property layers derived from conventional soil surveys are often incompatible with detailed terrain and remotely sensed data due to their difference in scales. The objective of this research is to examine the effect of scale incompatibility between soil information and the detailed digital terrain data and remotely sensed information by comparing simulations of watershed processes based on the conventional soil map and those simulations based on detailed soil information across different simulation scales. The detailed soil spatial information was derived using a GIS (geographical information system), expert knowledge, and fuzzy logic based predictive mapping approach (Soil Land Inference Model, SoLIM). The Regional Hydro-Ecological Simulation System (RHESSys) is used to simulate two watershed processes: net photosynthesis and stream flow. The difference between simulation based on the conventional soil map and that based on the detailed predictive soil map at a given simulation scale is perceived to be the effect of scale incompatibility between conventional soil data and the rest of the (more detailed) data layers at that scale. Two modeling approaches were taken in this study: the lumped parameter approach and the distributed parameter approach. The results over two small watersheds indicate that the effect does not necessarily always increase or decrease as the simulation scale becomes finer or coarser. For a given watershed there seems to be a fixed scale at which the effect is consistently low for the simulated processes with both the lumped parameter approach and the distributed parameter approach.     

利用现有重力场模型求定CHAMP卫星加速度计修正参数

CHAMP卫星加速度计数据的标定是通过确定其尺度因子和偏差参数来完成的.本文基于能量守恒方程,给出利用现有重力场模型标定CHAMP卫星加速度数据的基本原理和数学模型;提出相邻历元间差分算法,大大简化了观测方程,同时避免积分常量的计算.该算法既能同时解算尺度因子和偏差参数,也可任意求解其中之一.基于实测的CHAMP卫星加速度数据,利用EGM96模型和最新公布的EIGEN-2模型进行计算与比较,验证该方法的有效性.     

CMIP5模式对东太平洋ITCZ偶极子模态模拟能力的评估

本研究利用第五次国际间耦合模式比较计划(Coupled Model Intercomparison Project phase 5, CMIP5)中的24个模式的工业革命前控制试验(Pre-industrial Control, picontrol)模拟结果, 结合观测资料, 评估了24个CMIP5 模式对东太平洋热带辐合带偶极子(Eastern Pacific ITCZ dipole, EPID)降水模态的模拟能力, 并建立了其与模式对热带太平洋气候态模拟之间的联系。结果表明: 1) 绝大多数模式在北半球春季(2—4月)对EPID模态模拟能力较差, 主要原因在于CMIP5模式对热带辐合带(Intertropical Convergence Zone, ITCZ)的模拟偏差, 其中模拟效果较差的模式在2—4月的气候态降水分布在赤道以南, 且降水普遍偏强; 2) 对各模式的EPID模态选取的季节按照技巧评分最高进行调整后, 大部分模式能较好地模拟出EPID模态的空间分布特点, 技巧评分在0.6以上, 其中模拟效果好的模式(技巧评分大于0.7)中EPID模态出现的月份同时在中东太平洋气候态表现出“双ITCZ”特征, 且多模式集合结果的模拟误差小于绝大多数模式。     

孔道结构化合物(H3NCH2CH2NH3)3[(VO)4(PO4)2(HPO4)4]的钒氧化态与热稳定性关系研究

热处理脱除有机模板易导致VPO体系孔道结构化合物结构破坏,从而阻碍此类材料的实际应用。以孔道结构化合物(H3NCH2CH2NH3)3[(VO)4 (PO4 )2 (HPO4 )4 ](简称V2P3 en)为研究对象,利用热分析(DSC TG)、动态原位高温X 射线衍射(XRD)及多功能X 射线光电子能谱(XPS)等方法,研究了该化合物在不同气氛热处理过程中模板脱除及结构演化规律,重点探讨了钒氧化态的变化对结构稳定性的影响。结果表明,加热过程中随着有机模板的分解脱除,形成较强的还原环境,骨架中的部分钒被还原(V4+→V3+),使原有的配位环境([VⅣO5]三角双锥、[VⅣO6]畸变八面体)与钒的氧化态不符而导致结构重组。因此,钒氧化态的变化是影响热稳定性的重要因素之一。     

Titanium Isotope Analysis of Igneous Reference Materials using a Double-spike MC-ICP-MS Method

Ti separation was achieved by ion-exchange chromatography using Bio-Rad AG 1-X8 anion-exchange and DGA resins. For high-Fe/Ti and high-Mg/Ti igneous samples, a three-column procedure was required, whereas a two-column procedure was used for low-Fe/Ti and low-Mg/Ti igneous samples. The Ti isotopes were analysed by MC-ICP-MS, and instrumental mass bias was corrected using a 47Ti-49Ti double-spike technique. The 47Ti-49Ti double-spike and SRM 3162a were calibrated using SRM 979-Cr, certificated value 53Cr/52Crtrue = 0.11339. Isobaric interference was evaluated by analysing Alfa-Ti doped with Na, Mg, Ca, and Mo, and results indicate that high concentrations of Na and Mg have no significant effect on Ti isotope analyses; however, Ca and Mo interferences lead to erroneous δ49/47Ti values when Ca/Ti and Mo/Ti ratios exceed 0.01 and 0.1, respectively. Titanium isotopic compositions were determined for 12 igneous reference materials, BCR-2, BHVO-2, GBW07105, AGV-1, AGV-2, W-2, GBW07123, GBW07126, GBW07127, GBW07101, JP-1, and DTS-2b. Samples yield δ49/47Ti (‰) of ?0.035 ± 0.022, ?0.038 ± 0.031, 0.031 ± 0.022, 0.059 ± 0.038, 0.044 ± 0.037, 0.000 ± 0.015, 0.154 ± 0.044, ?0.044 ± 0.018, 0.010 ± 0.022, 0.064 ± 0.043, 0.169 ± 0.034, and ?0.047 ± 0.025 (relative to OL-Ti, ±2SD), respectively; of which isotopic compositions of DTS-2b, JP-1, GBW07101, GBW07105, GBW07123, GBW07126, and GBW07127 are reported for the first time. Standard Alfa-Ti was analysed repeatedly over a ten-month period, indicating a reproducibility of ±0.047 (2SD) for δ49/47Ti, similar to the precisions obtained for geochemical reference materials.     

T213 降水预报订正系统的建立与研究

目前T213降水预报存在一定程度上的系统性误差,为了更好地使用T213降水预报产品,减小系统性误差对主观预报的影响,利用一种统计学方法可以对T213降水预报进行订正,减小T213降水预报的系统性误差。通过对2004年6—11月订正前后的T213降水预报进行统计学和天气学检验分析,检验该订正系统的订正效果。结果表明,订正后的降水预报的预报偏差B值有了显著改善,其他统计检验量也有了不同程度的提高;订正后雨带的位置和轮廓更加接近降水实况。     

利用多分辨率半边进行全球多分辨率DEM无缝表达

矢量化的复杂建筑平面图纸受各类图元的干扰,其空间布局识别难度非常高,然而在5G基站建设、智能家居以及AR/VR（augmented reality/virtual reality）中广为应用。提出了一种结合栅格图像和矢量表示的高性能融合对偶识别方法。首先,采用建筑平面图纸的栅格化表示,提取建筑图纸的主要发展方向,构建分割的若干个封闭区域空间。然后,采用建筑平面图纸的矢量化表示,利用空间识别的有向性和邻接特性,创新地提出使用半墙数据结构进行墙体几何位置和拓扑关系的计算,从而根据空间对偶原理高精度地整体重建墙体布局。最后,获取包含各类墙体布局的矢量建筑平面图数据集,并进行方法的实验验证。实验结果证明了所提出的先空间后墙体的融合对偶识别算法对于各类建筑模型类型均具有可用性和有效性。与传统先墙体后空间的识别方法相比,所提方法具有更高的鲁棒性,受特定建筑图纸类型的干扰更少。     

基于方差递推法的Kalman滤波在钟差预报中的应用

卫星导航系统中星载原子钟的钟差预报对于导航、定位及授时具有重要的作用。为了提高卫星钟差预报的精度,设计了一种两步确定卫星钟噪声协方差矩阵的Kalman滤波钟差预报模型。该方法首先基于Hadamard总方差确定卫星钟噪声协方差矩阵的初值,然后,使用方差递推法得到滤波过程中卫星钟的噪声协方差矩阵。使用GPS系统的星载铷钟数据进行短期预报,并与常用的二次多项式模型、灰色模型进行对比,结果表明:本文中提出的方法可以实现高精度的卫星钟差预报且预报效果优于两种常用模型,同时,该方法能够在一定程度上弥补预报误差随预报时间增加而不断变大的不足。