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1.
Lars Olov Andersson 《Physics and Chemistry of Minerals》2008,35(9):505-520
The EPR spectra of Maxixe-type beryl contain a large number of overlapping signals. The angular dependence of the 1:3:3:1
signal typical for the CH3 radical shows that this radical is located at the center of the channel cavity with its symmetry axis parallel to the crystal
c-axis and is rotating around this axis. Its EPR spectrum is axially symmetric with g
// = 2.00263, g
⊥ = 2.00249 and A// = 2.288 mT, A⊥ = 2.256 mT. These anisotropies have the opposite signs of those found for surface-adsorbed methyl radicals. Hydrogen atoms
are located at position 2a at the center of the beryl cavity and the EPR parameters of the narrow doublet signal are A
0 = 1,407 MHz and g = 2.00230. Another doublet signal, which is broader and has axial symmetry with g
// = 2.00265, g
⊥ = 2.00625 and A// = 0.895 mT, A⊥ = 0.885 mT, could come from a HCO3 radical. One narrow and easily saturated signal with g
// = 2.00227 and g
⊥ = 2.00386 is interpreted to arise from a carbon monoxide radical in the beryl channel, oriented with its axis parallel to
the crystal c-axis. Additional weak doublet lines, which have similar g values as the carbon monoxide radical, are created by nearby hydrogens. A powder spectrum with g
// = 2.0017 and g
⊥ = 2.0004 appears upon UV irradiation of the single crystal and is easily saturated. This spectrum is interpreted to arise
from a carbon dioxide radical, which rotates around its symmetry axis. 相似文献
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新疆阿尔泰绿柱石的矿物学特征 总被引:3,自引:0,他引:3
新疆阿尔泰绿柱石的矿物学特征*王元龙(中国科学院地球化学研究所,贵阳550002)易爽庭(新疆地质矿产局测试中心,乌鲁木齐830000)关键词绿柱石矿物学成因类型新疆阿尔泰绿柱石是新疆阿尔泰地区重要矿产资源,它不仅是铍的主要载体,而且是海蓝宝石的母体... 相似文献
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辐照绿柱石的色心与赋色机制 总被引:4,自引:1,他引:4
在不同辐照剂量的带电粒子作用下,四川无色绿柱石因赋色而呈现浅蓝色,蓝绿色,黄绿色,浅黄色及橙黄色,紫外可见吸收光谱(UV-VIS)和阴极发光光谱(CLS)研究表明,辐照绿柱石中存在两组与赋色密切相关的色心组合,其一为相对稳定的[Fe^3 ]OH和[Fe^3 4]心,其二则为不稳定的[H^0]i心和F^ 心,二者对可见光的能量分别具有不同程度的选择性吸收和发射,由此产生特征的吸收与发射光谱。低温退火处理(210℃),有助于消除辐照绿柱石中不稳定的色心,使相对稳定的[Fe^3 ]OH心黉度再度聚集,并形成新的缺陷(二次缺陷),进而提高稳定色心的主波长和饱和度。研究证实,二次缺陷形成的初始温度,可近似代表辐照绿柱石的最佳热固色温度点,经辐照与热固色作用而形成的黄色,橙黄色绿柱石的颜色相对稳定,并不因长期日照或低温受热(<280℃)而褪色。 相似文献
7.
四川平武板状绿柱石矿物学特征及板状成因 总被引:7,自引:0,他引:7
在综合该区绿柱石产出背景的基础上,从围岩蚀变、矿物共生组合、矿物标型形态和绿柱石测温测压等方面确定平武绿柱石矿床是气成高温浅成石英脉型矿床。文中对绿柱石矿物进行了湿法化学分析、X射线粉晶衍射分析、微形貌分析,研究了该区绿柱石的形态、物性、化学成分及类质同象特征,确定该区绿柱石为板状晶形的含铯钠锂绿柱石,碱金属平均质量分数为2.412%(Li2O+Na2O+K2O+ Rb2O+Cs2O)。板状含碱绿柱石一般发育在伟晶岩中,气成高温热液矿床中产出板状含碱绿柱石极为罕见。在以上工作基础上,从绿柱石形成的内因和外因两方面探讨了绿柱石的板状成因。 相似文献
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新疆阿尔泰库威伟晶岩中绿柱石形成的物理化学条件 总被引:3,自引:0,他引:3
本文利用包裹体研究探讨了新疆阿尔泰库威伟晶岩中绿柱石形成时的物理化学条件。绿柱石中包裹体类型主要有二类:含硅酸盐子晶流体包裹体和不含硅酸盐子晶气液流体包裹体。含硅酸盐子晶流体包裹体代表岩浆-热液过渡阶段时的一种超临界流体相。结合显微镜观察和含硅酸盐子晶流体包裹体喇曼探针成分测定,得出绿柱石形成时体系中二氧化碳密度较高,ρco2=0.68 ̄0-.96g/cm^3;盐度很低,NaCl(wt%)=3.2 相似文献
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绿柱石与硅铍石均为铍矿物家族中的主要成员,是重要的工业铍矿物,利用背散射和电子探针研究矿物特性时,常可见两者共生或发生交代的现象(饶灿,2009;Reyf, 2008; Evensen, 1999),其结晶条件对于成矿环境与成矿机制均具有重要的指示意义。前人已进行了关于绿柱石,硅铍石等铍矿物稳定性的实验研究,但研究多采用高温淬火的高温高压实验装置,误差大,且无法原位观测矿物结晶习性(王振杰, 1992;Sirbescu et al., 2009),本文利用热液金刚石压腔,原位观测了绿柱石与硅铍石的结晶过程,得到了它们结晶的温压条件及结晶习性。 相似文献
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LIU Yan DENG Jun LI Guowu SHI Guanghai State Key Laboratory of Geological Processes Mineral Resources China University of Geosciences Beijing Key Laboratory of Lithosphere Tectonics Lithoprobing Technology of the Ministry of Education China University of Geosciences Beijing Laboratory of Single-Crystal X-Ray Diffraction China University of Geosciences Beijing 《《地质学报》英文版》2007,81(1):61-67
1 Introduction Natural beryl is an accessory mineral mainly in pegmatite, partly in some highly diffractionated granite or metamorphic rocks, with the crystal shapes beingprismatic, or occasionally tabular. For tabular beryl found in pegmatite it is believed that the tabular configuration is connected with alkali metals (Bieus, 1960; Wang et al., 1981) and geneses of the tabular configuration have been reported before. In recent years, tabular beryl has been found in the Xuebaoding W-Sn-Be d… 相似文献