含油玄武岩中绿泥石的形成温度

以苏北盆地高邮凹陷闵桥地区含油玄武岩中的绿泥石为研究对象，探讨了其成因和形成温度，认为玄武岩中绿泥石有两种形成方式、五条形成途径：其一为蚀变演化，包括：火山玻璃、斜长石、辉石的蚀变，交代橄榄石斑晶，以及皂石的进一步演化；其二为沉淀结晶，包括从热液中直接沉淀生长和胶体溶液充填后的结晶。计算结果显示，蚀变演化形成的绿泥石，其形成温度为128－271℃；沉淀结晶形成的绿泥石，其形成温度为31－63℃。玄武岩中绿泥石形成温度与埋藏深度间没有明显的线性相关。进一步研究表明，本区玄武岩作为储油层，其进油时的温度为62－118℃，不超出48－137℃。     

金山金矿热液蚀变粘土矿物特征及水-岩反应环境研究

粘土矿物是流体作用过程中水—岩反应的产物，因此其特征反映了流体活动的特征和水-岩反应的环境。金山金矿蚀变粘土矿物主要由伊利石和绿泥石组成，其中，蚀变糜棱岩中的伊利石含量大于绿泥石含量；而蚀变超糜棱岩中的绿泥石含量大于伊利石含量。蚀变糜棱岩中伊利石的多型为2M1，超糜棱岩中为2M1和1M。金山金矿蚀变绿泥石的成份分析结果表明其为富铁绿泥石，由蠕绿泥石、铁镁绿泥石和密绿泥石组成，绿泥石中Fe、Mg质组分不仅来自围岩，而且也有一部分来自流体。利用地质温度计计算绿泥石的形成温度为206-258℃，流体的f(O2)为10^29.56～10^-31.48。本文认为金山金矿热液蚀变为酸性蚀变，其环境为还原环境，流体作用的水／岩比较高；在水—岩反应过程中，流体中的Fe、Mg、Si为带出组分。粘土矿物的形成机制为溶解—迁移—沉淀。     

八卦庙金矿床的绿泥石特征及成岩成矿意义

绿泥石是八卦庙大型金矿床的主要热液蚀变矿物，本文系统地研究了绿泥石的产状、矿物学、化学成分等特点。在此基础上应用Walshe的绿泥石六组分热力学模型计算了绿泥石形成的物理化学条件：形成温度247.6～335.1℃，lgfo2值为一27.35～37.99，lgfs2的值是－7．46～－13.02，与根据成矿期石英包裹体所计算的值相近。     

The role of moisture cycling in the weathering of a quartz chlorite schist in a tropical environment: findings of a laboratory simulation

Long‐term weathering of a quartz chlorite schist via wetting and drying was studied under a simulated tropical climate. Cubic rock samples (15 mm × 15 mm × 15 mm) were cut from larger rocks and subjected to time‐compressed climatic conditions simulating the tropical wet season climate at the Ranger Uranium Mine in the Northern Territory, Australia. Fragmentation, moisture content and moisture uptake rate were monitored over 5000 cycles of wetting and drying. To determine the impact of climatic variables, five climatic regimes were simulated, varying water application, temperature and drying. One of the climatic regimes reproduced observed temperature and moisture variability at the Ranger Uranium Mine, but over a compressed time scale. It is shown that wetting and drying is capable of weathering quartz chlorite schist with changes expected over a real time period of decades. While wetting and drying alone does produce changes to rock morphology, the incorporation of temperature variation further enhances weathering rates. Although little fragmentation occurred in experiments, significant changes to internal pore structure were observed, which could potentially enhance other weathering mechanisms. Moisture variability is shown to lead to higher weathering rates than are observed when samples are subjected only to leaching. Finally, experiments were conducted on two rock samples from the same source having only subtle differences in mineralogy. The samples exhibited quite different weathering rates leading to the conclusion that our knowledge of the role of rock type and composition in weathering is insufficient for the accurate determination of weathering rates. Copyright © 2005 John Wiley & Sons, Ltd.     

合肥盆地钻井地层的同位素测年与地层划分

合肥盆地内部中、新界地层大面积被第四系覆盖，其地层的时代与划分主要依赖已有的6口深井地层资料。由于缺乏可靠的化石记录，这6口深井地层时代与划分一直存在着很大的分歧，制约了对该盆地的油气勘探与远景评价。本文利用这6口深井泥岩类岩屑中自生伊利石，在其结晶度分析基础上，进行了K-Ar同位素测年，成功地获得了不同深度上的地层形成时代。据此地层年龄，文中对这6口深井所钻遇的地层进行了重新的划分。     

鄂尔多斯盆地纳岭沟铀矿床绿泥石特征及地质意义

纳岭沟铀矿床位于鄂尔多斯盆地北部,具有明显的后期热液作用的特征,矿体空间展布主要受控于绿色-灰色砂岩的过渡界面,与绿泥石化的蚀变砂岩关系密切。通过对纳岭沟铀矿床不同颜色砂岩中的绿泥石进行详细的岩相学研究和电子探针化学成分分析,依据绿泥石的成因与共生矿物的关系,识别出绿泥石主要的3种类型:填隙物型绿泥石,片状与黄铁矿共生型绿泥石以及黑云母蚀变型绿泥石;同时通过绿泥石的Fe-Si图解确定了纳岭沟铀矿床不同颜色砂岩中的绿泥石主要为铁镁绿泥石和密绿泥石。根据Al/(Fe+Mg+Al)-Mg/(Fe+Mg)的关系图解确定出不同颜色砂岩中的绿泥石具有铁镁质流体和泥质两种来源,通过绿泥石中主要阳离子与镁的关系图解和计算得出的绿泥石形成温度共同确定出绿泥石是多期次的中低温热液流体作用的产物。综合研究表明,纳岭沟铀矿床的绿泥石形成至少经历了温度稍高的还原性流体和温度稍低的氧化性流体等两个期次的流体作用,稍高温的还原性流体与成矿关系更为重要。与绿泥石形成有关的热液流体作用不仅带入了部分铀,还促进了铀的活化和运移。     

内蒙古迪彦钦阿木斑岩钼矿床绿泥石和绿帘石矿物化学特征及其成矿指示意义

迪彦钦阿木矿床位于大兴安岭中段二连浩特-东乌旗多金属成矿带,是区内新近发现的一个超大型斑岩钼矿床.为了厘清蚀变矿物的成分对找矿的指示意义,文章运用电子探针和LA-ICP-MS对迪彦钦阿木矿床青磐岩化带绿帘石亚带的绿泥石和绿帘石的主微量元素成分进行了分析.电子探针数据表明,这些绿泥石属于铁斜绿泥石(辉绿泥石).绿泥石四面...     

渤海湾表层沉积物元素地球化学分布特征与影响因素

对取自渤海湾的307个表层沉积物进行了元素测试和粒度分析。渤海湾表层沉积物的常微量元素呈现4种组合:富集于粗粒沉积区的SiO_2、Na_2O亲碎屑元素组合;富集于细粒沉积区的以Al_2O_3和重金属元素为代表的亲黏土元素组合;与缺氧环境有关的MnO、V、TOC元素组合和与河流输入有关的陆源CaO、TiO_2元素组合。粒度粗细主导了渤海湾元素含量分布的整体格局;海域河流物源供应不同较大影响了渤海湾南部(富Na_2O、CaO和SiO_2)和北部(富Ba和P_2O_5)在元素含量上的差异;高流速潮流对海底的冲刷再分配导致曹妃甸南侧Sr、Ca元素的条带状富集异常;有机质在细粒沉积区的富集导致缺氧环境的形成和K_2O、Mn、V、自生黄铁矿的海洋自生化学沉积;人类活动导致以Pb为代表的重金属污染在河流入海口、港口及沿岸海域的元素分布异常;曹妃甸沙坝内侧的泻湖(海洋钙质生物沉积)与沙坝外侧水下岸坡(陆源碎屑沉积)的截然不同的物源,导致了独特地貌沉积环境下元素分布的局部差异。     

南海神狐海域沉积物自生黄铁矿和石膏S同位素特征及对甲烷渗漏强度的示踪

The northern slope of the South China Sea is a gas-hydrate-bearing region related to a high deposition rate of organic-rich sediments co-occurring with intense methanogenesis in subseafloor environments.Anaerobic oxidation of methane(AOM) coupled with bacterial sulfate reduction results in the precipitation of solid phase minerals in seepage sediment,including pyrite and gypsum.Abundant aggregates of pyrites and gypsums are observed between the depth of 667 and 850 cm below the seafloor(cmbsf) in the entire core sediment of HS328 from the northern South China Sea.Most pyrites are tubes consisting of framboidal cores and outer crusts.Gypsum aggregates occur as rosettes and spheroids consisting of plates.Some of them grow over pyrite,indicating that gypsum precipitation postdates pyrite formation.The sulfur isotopic values(δ~(34) S) of pyrite vary greatly(from –46.6‰ to –12.3‰ V-CDT) and increase with depth.Thus,the pyrite in the shallow sediments resulted from organoclastic sulfate reduction(OSR) and is influenced by AOM with depth.The relative high abundance and δ~(34) S values of pyrite in sediments at depths from 580 to 810 cmbsf indicate that this interval is the location of a paleo-sulfate methane transition zone(SMTZ).The sulfur isotopic composition of gypsum(from–25‰ to –20.7‰) is much lower than that of the seawater sulfate,indicating the existence of a 34 S-depletion source of sulfur species that most likely are products of the oxidation of pyrites formed in OSR.Pyrite oxidation is controlled by ambient electron acceptors such as MnO_2,iron(Ⅲ) and oxygen driven by the SMTZ location shift to great depths.The δ~(34) S values of gypsum at greater depth are lower than those of the associated pyrite,revealing downward diffusion of 34 S-depleted sulfate from the mixture of oxidation of pyrite derived by OSR and the seawater sulfate.These sulfates also lead to an increase of calcium ions from the dissolution of calcium carbonate mineral,which will be favor to the formation of gypsum.Overall,the mineralogy and sulfur isotopic composition of the pyrite and gypsum suggest variable redox conditions caused by reduced seepage intensities,and the pyrite and gypsum can be a recorder of the intensity evolution of methane seepage.