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1.
四川石棉大水沟独立碲矿床堪称世界首例,其矿体两侧的围岩蚀变较窄,且蚀变带与矿脉及未蚀变岩呈清楚而截然的接触关系。主要围岩蚀变为白云石化、白(绢)云母化、云英岩化及电气石化等。这些蚀变作用分别发生于177.7~165.1Ma和91.71~80.19Ma。蚀变作用过程中SiO2大量析出,Al2O3、TiO2、CaO、MgO、K2O、H2O、CO2、Fe2O3、MnO则有不同程度地带入。与此同时,REE在此过程中包集体迁出,Te、Bi、AS等元素的含量则决定于蚀变作用及其强度,而与原岩无关。 相似文献
2.
激光拉曼光谱法分析多种显微组分荧光变化及其应用 总被引:1,自引:1,他引:0
利用激发488 nm激光的氩离子激光器作为RENISHAW inVia型激光拉曼光谱仪的光源,建立了多种显微组分荧光变化(FAMM)分析方法,并对镜质体反射率明显抑制的东营凹陷有效烃源岩进行了测定。结果表明,东营凹陷有效烃源岩的有机质类型越好,镜质体反射率抑制程度越高,有效烃源岩的真实成熟度应主要处于0.64%~1.30%,而不是实测镜质体反射率所反映的0.37%~1.10%。 相似文献
3.
4.
针对传统矿化信息提取方法单一,利用光谱或纹理、信息量相对较少、需要大量样本的缺陷,利用基于光谱和纹理的支持向量机(SVM)原理,建立矿化信息提取模型.选择青海泽库县析界日地区作为典型研究区.首先提取研究区光谱和纹理信息,选取训练样本;然后求解最优超平面,进而确定决策函数;最后泛化推广识别其他待识别的样本.通过所提取的遥感蚀变异常信息与重砂异常点叠加分析,叠加基本吻合;从野外实地验证来看,均发现了不同程度的矿化现象,并指出了5个重点异常区. 相似文献
5.
Miwako Nakaseama Jun-Ichiro Ishibashi Keita Ogawa Hiroshi Hamasaki Keiko Fujino Toshiro Yamanaka 《Resource Geology》2008,58(3):289-300
The Wakamiko submarine crater is a small depression located in Kagoshima Bay, southwest Japan. Marine shallow‐water hydrothermal activity associated with fumarolic gas emissions at the crater sea floor (water depth 200 m) is considered to be related with magmatic activity of the Aira Caldera. During the NT05‐13 dive expedition conducted in August 2005 using remotely operated vehicle Hyper‐Dolphine (Japan Agency for Marine‐Earth Science and Technology), an active shimmering site was discovered (tentatively named the North site) at approximately 1 km from the previously known site (tentatively named the South site). Surface sediment (up to 30 cm) was cored from six localities including these active sites, and the alteration minerals and pore fluid chemistry were studied. The pore fluids of these sites showed a drastic change in chemical profile from that of seawater, even at 30 cm below the surface, which is attributed to mixing of the ascending hydrothermal component and seawater. The hydrothermal component of the North site is estimated to be derived from a hydrothermal aquifer at 230°C based on the hydrothermal end‐member composition. Occurrence of illite/smectite interstratified minerals in the North site sediment is attributed to in situ fluid–sediment interaction at a temperature around 150°C, which is in accordance with the pore fluid chemistry. In contrast, montmorillonite was identified as the dominant alteration mineral in the South site sediment. Together with the significant low potassium concentration of the hydrothermal end‐member, the abundant occurrence of low‐temperature alteration mineral suggests that the hydrothermal aquifer in the South site is not as high as 200°C. Moreover, the montmorillonite is likely to be unstable with the present pore fluid chemistry at the measured temperature (117°C). This disagreement implies unstable hydrothermal activity at the South site, in contrast to the equilibrium between the pore fluid and alteration minerals in the North site sediment. This difference may reflect the thermal and/or hydrological structure of the Wakamiko Crater hydrothermal system. 相似文献
6.
Marco Herwegh Jean-Pierre Hürzeler O. Adrian Pfiffner Stefan M. Schmid Rainer Abart Andreas Ebert 《Swiss Journal of Geoscience》2008,101(2):323-340
This excursion guide results form a field trip to the Glarus nappe complex organized by the Swiss Tectonic Studies Group in 2006. The aim of the excursion was to discuss old and recent concepts related to the evolution of the Glarus thrust. The major aspects were (i) the interplay between deformation, fluid flow and geochemical alteration, (ii) episodic versus continuous deformation and fluid flow, and (iii) the link between large-scale structures, microstructures, and geochemical aspects. Despite 150 years of research in the Glarus nappe complex and the new results discussed during the excursion, there exist controversies that still are unsolved. 相似文献
7.
《中国地球化学学报》2006,25(B08):239-239
Methylmercury (MeHg) is a powerful neurotoxicant in humans. In terms of biomarkers of MeHg exposure, hair and blood have long been used in epidemiological studies as the biomarkers of choice. In fact, total hair mercury (Hg) content as well as organic blood Hg concentrations reflects exposure to organic Hg from food consumption. Extensive studies, establishing a constant and linear relation between MeHg intake versus Hg levels in hair and blood, were conducted by governmental officials to establish guidelines on safe levels of MeHg exposure, which were translated into threshold daily fish consumption rates (usually expressed as μg MeHg per kg bodyweight). Nowadays, in most epidemiologic studies blood or hair mercury (Hg) level is commonly used as a valid proxy to estimate human exposure to methylmercury (MeHg) through fish consumption without relating this signal to actual fish consumption patterns among populations. Human variability in mercury toxicokinetics was identified and measurement error has been pointed out to be a substantial contributor to observed variability, particularly where dietary information is retrospective and self-reported. However, experimental evidence indicates that significant variability among individuals may exist in the biokinetics of mercury. Also recent findings from previous population-based studies through COMERN initiative also revealed that MeHg metabolic processes might greatly vary across populations. In fact, it is unlikely that the magnitude of the difference measured between observed and expected levels of mercury, given the reported intake, can be entirely explained by laboratory measurement errors or reporting bias. 相似文献
8.
Distribution of the rare-earth elements (REE) in dacite has been studied so as to get a better understanding of the migration
behavior of REE during alteration. Both unaltered and altered samples were collected in an unpolluted area of Guangxi Zhuang
Autonomous Region, southwest China. The REE concentrations were analyzed by ICP-MS. It is concluded that the REE were enriched
during dacite alteration in varying degrees. The chondrite-normalized REE patterns of altered samples approximately maintain
the characteristics of unaltered samples. However, if we normalize the REE concentrations of altered samples with unaltered
dacite, fractionation of REE will appear. The LREE are more enriched than HREE in all altered samples with the LREE possibly
precipitated as carbonate minerals. Both positive and negative Eu anomalies exist. Enrichment, immobility and depletion are
noticed for the element Lu. Heavy mineral alteration, difference in stability constant between carbonate LREE and HREE complexes,
downward migration of weathering fluid and microenvironment change may be responsible for the fractionation of REE in the
altered dacite. 相似文献
9.
Abstract. Several epithermal gold deposits occur in the Hoshino area, which is located in the western end of the late Cenozoic Hohi volcanic zone, north‐central Kyushu, Japan. The area is characterized by intermediate to felsic extrusive rocks of Pliocene age. In the Hoshino area, the shallow manifestation of the hydrothermal activity is exposed on the surface. Several outcrops of sinter are still preserved on the top of hydro thermally altered volcanic rocks, and high‐grade gold‐bearing quartz veins occur on the surface at lower levels. The hydrothermal alteration resulted into well‐developed alteration zones. The zonal alteration pattern, primarily of near‐neutral pH type, is characterized by the outer smectite zone of a lower temperature, and the inner mixed layer minerals zone of a higher temperature. Quartz vein‐related or fracture‐controlled alteration, is represented by the occurrence of interstratified illite/smectite and K‐feldspar, suggesting a potassium‐enriched alteration. The mineralization in the Hoshino area is recognized on the surface by the occurrence of gold‐bearing quartz veins distributed mainly in the mixed layer minerals zone. The fracture system related to the gold mineralization is mainly characterized by NW‐SE trend. The alteration pattern and the mineralogical composition of the veins suggest that the mineralizing fluids had near‐neutral pH and the mineralization is of low‐sulfidation‐type. Fluid inclusion data and textures observed in quartz veins indicate that gold precipitated during boiling. The chemical composition of quartz veins shows that high‐grade gold‐bearing quartz veins are characterized by higher content of Al2O3, K2O and Rb. Several outcrops of silica‐sinters are distributed on the top of the mixed layer minerals zone. Although their structures are not very well preserved, because of later silicification, the Hoshino sinters still show characteristic textures identical to those observed in modern sinters, such as the presence of plant fossil incorporated into the sinters, the strongly developed depositional laminations and the columnar structures perpendicular to the depositional surfaces. Quartz is the only silica mineral constituting the Hoshino sinters presently. The conversion of amorphous silica into quartz was probably governed by higher temperatures resulting from later hydrothermal activity. This later hydrothermal activity is reflected by the intense silicification affecting mainly the lower parts of the sinters and also by the presence of quartz veins cutting the sinters. The distribution of sinters in the Hoshino area is very significant. The presence beneath the sinters of concealed high‐grade gold‐bearing quartz veins should be highly considered and exploration work is strongly suggested. 相似文献
10.
Ocean Drilling Program (ODP) Hole 504B near the Costa Rica Rift is the deepest hole drilled in the ocean crust, penetrating a volcanic section, a transition zone and a sheeted dike complex. The distribution of Li and its isotopes through this 1.8-km section of oceanic crust reflects the varying conditions of seawater alteration with depth. The upper volcanic rocks, altered at low temperatures, are enriched in Li (5.6-27.3 ppm) and have heavier isotopic compositions (δ7Li=6.6-20.8‰) relative to fresh mid-ocean ridge basalt (MORB) due to uptake of seawater Li into alteration clays. The Li content and isotopic compositions of the deeper volcanic rocks are similar to MORB, reflecting restricted seawater circulation in this section. The transition zone is a region of mixing of seawater with upwelling hydrothermal fluids and sulfide mineralization. Li enrichment in this zone is accompanied by relatively light isotopic compositions (−0.8-2.1‰) which signify influence of basalt-derived Li during mineralization and alteration. Li decreases with depth to 0.6 ppm in the sheeted dike complex as a result of increasing hydrothermal extraction in the high-temperature reaction zone. Rocks in the dike complex have variable isotopic values that range from −1.7 to 7.9‰, depending on the extent of hydrothermal recrystallization and off-axis low-temperature alteration. Hydrothermally altered rocks are isotopically light because 6Li is preferentially retained in greenschist and amphibolite facies minerals. The δ7Li values of the highly altered rocks of the dike complex are complementary to those of high-temperature mid-ocean ridge vent fluids and compatible to equilibrium control by the alteration mineral assemblage. The inventory of Li in basement rocks permits a reevaluation of the role of oceanic crust in the budget of Li in the ocean. On balance, the upper 1.8 km of oceanic crusts remains a sink for oceanic Li. The observations at 504B and an estimated flux from the underlying 0.5 km of gabbro suggest that the global hydrothermal flux is at most 8×109 mol/yr, compatible with geophysical thermal models. This work defines the distribution of Li and its isotopes in the upper ocean crust and provides a basis to interpret the contribution of subducted lithosphere to arc magmas and cycling of crustal material in the deep mantle. 相似文献