Trichodesmium erythraeum (Ehrenberg) bloom along the southwest coast of India (Arabian Sea) and its impact on trace metal concentrations in seawater

The incidence of a large scale Trichodesmium erythraeum bloom along the southwest coast of India (Arabian Sea) observed in May 2005 is reported. Around 4802 filaments of T. erythraeum ml⁻¹ seawater was observed and a colony consisted of 3.6 × 10⁵ cells. The bloom was predominant off Suratkal (12° 59′N and 74° 31′E) with a depth of about 47 m, covering an area of 7 km in length and 2 km width. The concentrations of Zinc, Cadmium, Lead, Copper, Nickel and Cobalt were determined in samples collected from the bloom and non-bloom sites using stripping voltammetry. The observed hydrographical and meteorological parameters were found to be favorable for the bloom. The concentrations of Zinc, Cadmium and Nickel were found to be higher at bloom stations, while the concentrations of Lead, Copper and Cobalt were found to be very low at bloom stations. Elevated concentrations of Cadmium and Cobalt were observed at Valappad mainly due to the decomposition of detrital material produced in the bloom. Statistically significant differences (P > 0.01) in metal concentrations between the bloom and non-bloom stations were not observed except for Copper. Metals such as Lead, Copper and Cobalt were removed from the seawater at all places where bloom was observed. Cadmium was found to be slowly released during the decaying process of the bloom.     

新型充气钻井液在新疆严重漏失地层的应用

利用特殊植物纤维KWS作为泥浆处理剂的新型充气钻井液，不仅具有常规充气钻井液低密度、排粉能力强、节约用水等优点，还可以不受钠、钙离子的影响，提高钻井泡沫稳定性和钻井液抗盐能力。通过采用此种新型充气钻井液，利用其低密度特性、特殊泥饼、泡沫的群体封堵作用和泡沫的疏水屏蔽作用，成功解决了裂隙地层的漏失问题，恢复了钻探生产。在我国西部干旱缺水漏失地区具有良好的应用前景。     

Kinetic and equilibrium studies of copper-dissolved organic matter complexation in water column of the stratified Krka River estuary (Croatia)

An interaction of dissolved natural organic matter (DNOM) with copper ions in the water column of the stratified Krka River estuary (Croatia) was studied. The experimental methodology was based on the differential pulse anodic stripping voltammetric (DPASV) determination of labile copper species by titrating the sample using increments of copper additions uniformly distributed on the logarithmic scale. A classical at-equilibrium approach (determination of copper complexing capacity, CuCC) and a kinetic approach (tracing of equilibrium reconstitution) of copper complexation were considered and compared. A model of discrete distribution of organic ligands forming inert copper complexes was applied. For both approaches, a home-written fitting program was used for the determination of apparent stability constants (K_i^equ), total ligands concentration (L_iT) and association/dissociation rate constants (k_i¹,k_i^- 1).A non-conservative behaviour of dissolved organic matter (DOC) and total copper concentration in a water column was registered. An enhanced biological activity at the freshwater–seawater interface (FSI) triggered an increase of total copper concentration and total ligand concentration in this water layer. The copper complexation in fresh water of Krka River was characterised by one type of binding ligands, while in most of the estuarine and marine samples two classes of ligands were identified. The distribution of apparent stability constants (log K₁^equ: 11.2–13.0, log K₂^equ:8.8–10.0) showed increasing trend towards higher salinities, indicating stronger copper complexation by autochthonous seawater organic matter.Copper complexation parameters (ligand concentrations and apparent stability constants) obtained by at-equilibrium model are in very good accordance with those of kinetic model. Calculated association rate constants (k₁¹:6.1–20 × 10³ (M s)^− 1, k₂¹: 1.3–6.3 × 10³ (M s)^− 1) indicate that copper complexation by DNOM takes place relatively slowly. The time needed to achieve a new pseudo-equilibrium induced by an increase of copper concentration (which is common for Krka River estuary during summer period due to the nautical traffic), is estimated to be from 2 to 4 h.It is found that in such oligotrophic environment (dissolved organic carbon content under 83 µM_C, i.e. 1 mg_CL^− 1) an increase of the total copper concentration above 12 nM could enhance a free copper concentration exceeding the level considered as potentially toxic for microorganisms (10 pM).     

充气欠平衡钻井液技术在DP4井水平段的应用

DP4井是中石化华北分公司在鄂尔多斯盆地大牛地气田布置的一口充气欠平衡水平井,该井目的层为盒1段,地层压系数较低,压力系数范围0．83—0．99（平均0．93）,为了有效保护气层,DP4井水平段全过程采用了充气欠平衡钻井工艺技术。欠平衡钻井工艺采用充气钻井液技术,通过该工艺在DP4井的实施,在盒1气层保护上取得较大成功。主要介绍了充气欠平衡钻井液技术的技术工艺、实施过程和现场实施情况,并对充气欠平衡钻井液技术在该井实施效果进行了分析评价。     

基于FEA的填充墙与隔震器协同抗震系统性能分析

隔震器与填充墙对建筑抗震性能有很大作用。为了探究填充墙布置形式及填充材料和隔震器协同作用对钢筋混凝土框架结构动力特性及抗震性能的影响,采用等效斜撑理论,对3种不同填充墙布置形式与隔震器协同作用的抗震系统方案进行对比分析,研究发现顶层不布置填充墙与隔震器协同抗震系统钢筋混凝土框架结构的抗震性能最佳。在此系统上分析了不同填充材料对钢筋混凝土框架结构抗震性能的影响,结果表明,加气混凝土砌块填充墙的钢筋混凝土框架结构抗震性能最好。     

配BFG蒸压加气混凝土砌块砌体基本力学性能数值模拟

将蒸压加气混凝土(AAC)砌体填充墙采用薄灰缝专用砂浆砌筑,并在灰缝中配置玄武岩纤维格栅(BFG),可以提高墙体的抗压强度和延性。为了研究配BFG的AAC砌块砌体的基本力学性能,设计了9组27个试件进行抗压和抗剪试验。在试验的基础上,首先分析了砌体的抗压和抗剪性能,给出抗压上升段本构方程和抗压、抗剪强度建议公式;其次运用ABAQUS对砌体的抗压和抗剪性能进行模拟,通过比较模拟结果与试验结果,验证了有限元模型的合理性;最后分析了模型受压时的应力-应变关系,给出抗压下降段本构方程。研究表明:荷载施加处,接触面上剪应力集中是砌体通缝抗剪破坏的主要原因;本构方程可为配BFG蒸压加气混凝土砌体填充墙抗震性能的研究提供参考。     

节能住宅地震反应分析

为研究节能房屋的抗震能力,本文基于墙体试验研究成果,建立了墙体的恢复力模型及其抗震抗剪强度公式,并对内砖外加气混凝土砌块墙体节能房屋进行了地震反应分析.本项研究为节能住宅的推广应用提供了抗震设计依据.     

无人机航空伽马能谱数据处理中大气氡的修正

介绍了无人机航空伽马能谱数据处理中大气氡修正的一种方法——能谱比法的原理与方法、数据处理过程及其在无人机航空伽马能谱数据处理中的应用。使用该方法对喀什地区的无人机航空伽马能谱进行修正,修正后的航放U较好地反映了该区的地质情况,可以应用到生产实践中去。     

组合生物技术处理制药废水及其生物相

为有效治理化学制药废水和生物制药废水,采用水解酸化-活性污泥[-曝气生物滤池组合工艺对制药废水进行室内模拟生物处理研究。结果表明：该工艺对出水COD、BOD₅的去除率均大于90%,已达到《污水综合排放标准》（GB 8978-1996）二级标准。对生物相的显微镜观察分析表明,污泥絮体和生物膜生长良好,并出现变形虫、轮虫和漫游虫等原生和后生动物。对各构筑物中的细菌进行分离纯化,同时应用BIOLOG细菌鉴定系统进行鉴定,分别得到8株、3株、6株可培养的细菌。     

柴达木盆地石炭系地球物理特征及解释

柴达木盆地具有丰富的油气资源,柴北缘、柴西、粜东三湖地区分别以侏罗系、古近系、新近系和第四系为主要勘探目的层.随着北疆石炭系研究的进展和钻探的成功,石炭系已经成为中国西部地区重要的勘探层系,柴达木盆地的石炭系也引起了勘探家的注意,地面地质调查表明石炭系为柴达木盆地一套潜在烃源岩.为了落实石炭系在柴达木盆地内的分布,笔者充分利用近10年来在柴达木盆地及周缘完成的重、磁、电等资料进行了针对石炭系的资料解释、剥层反演和综合研究,明确了石炭系的分布特征,为柴达木盆地石炭系油气勘探指明了方向.