A dated cave sediment record of Pleistocene transgressions on Berry Head,Southwest England

Berry Head, a limestone headland in Torbay, southwest England, exhibits a series of subaerial marine erosion platforms and raised beaches spanning an altitude range of 97 m. Solution caves on the headland show preferred horizontal development at elevations that are correlated with the marine erosion platforms, and developed in a marine/freshwater mixing zone whose position was controlled by high sea-level still-stands. Corbridge Cave in Berry Head Quarry lies below the raised beaches in Torbay, and contains evidence of three marine transgressions in the form of fine-grained marine ponding deposits with a marine microfauna. Uranium-series dating of intercalated speleothems indicates that a transgression during oxygen isotope stage 5e reached an elevation of 5.8 m OD, while an earlier transgression (probably during stage 7) reached at least 7.2 m OD. These findings are used to constrain possible interpretations of the aminostratigraphy of raised beaches in Southwest Britain, and a correlation of the Unnamed Stage of Bowen, Sykes, Reeves, Miller, Andrews, Brew and Hare with oxygen isotope stage 5e is proposed.     

Exposure dating and reinterpretation of coarse debris accumulations (‘rock glaciers’) in the Cairngorm Mountains,Scotland

Relict rock glaciers have considerable potential for contributing to palaeoclimatic reconstruction, but this potential is often undermined by lack of dating control and problems of interpretation. Here we reinvestigate and date four proposed ‘rock glaciers’ in the Cairngorm Mountains and show that the morphology of only one of these appears consistent with that of a true rock glacier produced by creep of underlying ice or ice‐rich sediment. All four features comprise rockslide or rock avalanche runout debris, and the possibility that all four represent unmodified runout accumulations cannot be discounted. Surface exposure dating of the four debris accumulations using cosmogenic ¹⁰Be produced uncertainty‐weighted mean ages of 15.4 ± 0.8 ka, 16.2 ± 1.0 ka, 12.1 ± 0.6 ka and 12.7 ± 0.8 ka. All four ages imply emplacement under cold stadial conditions, two prior to the Windermere Interstade of ca. 14.5–12.9 cal. ka BP and two during the Loch Lomond Stade of ca. 12.9–11.5 cal. ka BP. The above ages indicate that paraglacial rock‐slope failure on granite rockwalls occurred within a few millennia after deglaciation. The mean exposure ages obtained for runout debris at two sites – Strath Nethy (16.2 ± 1.0 ka) and Lairig Ghru (15.4 ± 0.8 ka) – are consistent with basal radiocarbon ages from Loch Etteridge, 22 km to the southwest (mean = 15.6 ± 0.3 cal. ka BP) and imply widespread deglaciation of the Cairngorms and adjacent valleys before 15 ka and possibly 16 ka. Copyright © 2008 John Wiley & Sons, Ltd.     

Luminescence dating of sand–loess sequences and response of Mu Us and Otindag sand fields (north China) to climatic changes

The sand–loess transition zone in north China is sensitive to climate change, and is an ideal place to investigate past environmental changes. However, past climate change at millennial–centennial timescales in this region has not been well reconstructed because of limited numerical dating. Alternations of sandy loam soils with aeolian sand layers in the Mu Us and Otindag sand fields, which lie along the sand–loess transition zone, indicate multiple intervals of dune activity and stability. This change is probably a response to variations of the East Asian monsoon climate during the late Quaternary. The single aliquot regeneration (SAR) optically stimulated luminescence (OSL) dating protocol, which has been successfully applied to aeolian deposits worldwide, is applied to these two sand fields in this study. The OSL ages provide reliable constraints for reconstruction of past climate changes at suborbital timescale. Sections in both sand fields contain aeolian sand beds recording millennial‐scale episodes of dry climate and widespread dune activation, including episodes at about the same time as Heinrich Event 5 and the Younger Dryas in the North Atlantic region. These results demonstrate the potential of aeolian sediments in semi‐arid north China to record millennial‐scale climatic events, and also suggest that dry–wet climate variation at the desert margin in China may be linked to climatic change elsewhere in the Northern Hemisphere, through atmospheric circulation. This article was published online on 27 November 2008. An error was subsequently identified. This notice is included in the online and print versions to indicate that both have been corrected (16 December 2008). Copyright © 2008 John Wiley & Sons, Ltd.     

Pan-African eclogite facies metamorphism of ultramafic rocks in the Shackleton Range, Antarctica

In the Shackleton Range of East Antarctica, garnet-bearing ultramafic rocks occur as lenses in supracrustal high-grade gneisses. In the presence of olivine, garnet is an unmistakable indicator of eclogite facies metamorphic conditions. The eclogite facies assemblages are only present in ultramafic rocks, particularly in pyroxenites, whereas other lithologies – including metabasites – lack such assemblages. We conclude that under high-temperature conditions, pyroxenites preserve high-pressure assemblages better than isofacial metabasites, provided the pressure is high enough to stabilize garnet–olivine assemblages (i.e. ≥18–20 kbar). The Shackleton Range ultramafic rocks experienced a clockwise P–T path and peak conditions of 800–850 °C and 23–25 kbar. These conditions correspond to ∼70 km depth of burial and a metamorphic gradient of 11–12 °C km⁻¹ that is typical of a convergent plate-margin setting. The age of metamorphism is defined by two garnet–whole-rock Sm–Nd isochrons that give ages of 525 ± 5 and 520 ± 14 Ma corresponding to the time of the Pan-African orogeny. These results are evidence of a Pan-African suture zone within the northern Shackleton Range. This suture marks the site of a palaeo-subduction zone that likely continues to the Herbert Mountains, where ophiolitic rocks of Neoproterozoic age testify to an ocean basin that was closed during Pan-African collision. The garnet-bearing ultramafic rocks in the Shackleton Range are the first known example of eclogite facies metamorphism in Antarctica that is related to the collision of East and West Gondwana and the first example of Pan-African eclogite facies ultramafic rocks worldwide. Eclogites in the Lanterman Range of the Transantarctic Mountains formed during subduction of the palaeo-Pacific beneath the East Antarctic craton.     

A 20‐ka climate record from Central Himalayan loess deposits

The southwest monsoon that dominated Central Himalaya has preserved loessic silt deposits preserved in patches that are proximal to periglacial areas. The occurrence of such silts suggests contemporary prevalence of cold and dry northwesterly winds. Field stratigraphy, geochemistry, mineral magnetism, infrared stimulated luminescence (IRSL) and radiocarbon dating has enabled reconstruction of an event chronology during the past 20 ka. Three events of loess accretion could be identified. The first two events of loess deposition occurred betweem 20 and 9 ka and were separated by a phase of moderate weathering. Pedogenesis at the end of this event gave rise to a well‐developed soil that was bracketed around 9 to > 4 ka. This was followed by the third phase of loess accretion that occurred around 4 to > 1 ka. Episodes of loess deposition and soil formation are interpreted in terms of changes in the strength of the Indian southwest monsoon. Copyright © 2005 John Wiley & Sons, Ltd.     

The Preboreal climate reversal and a subsequent solar‐forced climate shift

Accurate chronologies are essential for linking palaeoclimate archives. Carbon‐14 wiggle‐match dating was used to produce an accurate chronology for part of an early Holocene peat sequence from the Borchert (The Netherlands). Following the Younger Dryas–Preboreal transition, two climatic shifts could be inferred. Around 11 400 cal. yr BP the expansion of birch (Betula) forest was interrupted by a dry continental phase with dominantly open grassland vegetation, coeval with the PBO (Preboreal Oscillation), as observed in the GRIP ice core. At 11 250 cal. yr BP a sudden shift to a humid climate occurred. This second change appears to be contemporaneous with: (i) a sharp increase of atmospheric ¹⁴C; (ii) a temporary decline of atmospheric CO₂; and (iii) an increase in the GRIP ¹⁰Be flux. The close correspondence with excursions of cosmogenic nuclides points to a decline in solar activity, which may have forced the changes in climate and vegetation at around 11 250 cal. yr BP. Copyright © 2004 John Wiley & Sons, Ltd.     

High resolution paleoenvironmental and chronological investigations of Norse landnám at Tasiusaq, Eastern Settlement, Greenland

High-resolution paleoenvironmental data from a peat profile with a small pollen source area are used to reconstruct the impacts of landnám on vegetation and soils at a Norse farm complex (∅2 at Tasiusaq) comprising two farms in the Eastern Settlement of Greenland. Analyses include the AMS ¹⁴C dating of plant macrofossil samples and the use of Bayesian radiocarbon calibration to construct improved age-depth models for Norse cultural horizons. The onset of a regional landnám may be indicated by the clearance of Betula pubescens woodland immediately prior to local settlement. The latter is dated to AD 950-1020 (2σ) and is characterised by possible burning of Betula glandulosa scrub to provide grassland pasture for domestic stock. Clearance and grazing resulted in accelerated levels of soil erosion at a westerly farm. This was followed by an easterly migration of settlement and agriculture. Site constraints prevent an assessment of the demise of the easterly farm, but pressures of overgrazing and land degradation may have been the major factors responsible for the abandonment of the earlier farm.     

Variscan basic dykes in the Pelagonian (Northern Greece and south FYROM): Geodynamic significance based on petrological, geochemical and geochronological studies

Dolerite dykes intruding Variscan plutonites were studied in terms of mineralogy, petrology, geochemistry and geochronology. The main mineral constituents were studied and the sequence of crystallization has been derived. The geochemical characteristic indicate mantle origin of the dolerites and magma sources different from the hosting granitoids. From SHRIMP analyses of five spots on four different zircon crystals, resulted a 292.0±4.1 Ma age that is interpreted as the time of crystallization of the dolerite. The hosting granitoids are probably the result of mixing between two possible end-members: enriched mantle and acid metaigneous or lower crustal metasediments.

The Variscan age of the dolerites, in combination with the geochemical characteristics, indicated that the enriched mantle basaltic material should be the source of the dolerite veins. These mantle-derived basaltic melts may represent the underplated material, which probably provided the necessary thermal input to the dehydration melting in the lower crust. The dolerites should have intruded the newly formed batholiths before or at the first stages of their uplift, recording the last events of the Variscan subduction.     

Laser ablation coupled with ICP-MS applied to U–Pb zircon geochronology: A review of recent advances

Improvements in the technology of laser ablation and ICP-MS instruments make LA-MC-ICPMS a rapid, precise and accurate method for U–Pb zircon geochronology. In this review we describe the main stages of the evolution of this in situ approach from the early 1990s to the present time. Some key points have been progressively improved. The crater size has been reduced to achieve real in situ measurements. The laser wavelength has been reduced as well as the duration of each pulse in order to lower inter-element fractionation. The blank from the gas has to be lowered as far as possible. Double focusing instruments and magnetic field sectors allow flat-topped peaks required for precise isotope ratio measurement to be obtained. The use of a multi-ion counting system significantly improves the sensitivity of the method and the static mode of integration favours the precision of measurement of the transient signal originating from a noisy laser ablated particle beam.Combining the use of a 213 nm UV laser and a MC-ICPMS equipped with a multi-ion counting system operating in static mode, the common precisions achieved for the key ratios ²⁰⁷Pb/²⁰⁶Pb and ²⁰⁶Pb/²³⁸U are better than 1% and 3% (2σ) respectively, including error propagation associated with standard normalization. Until now, the use of a zircon standard has remained necessary to ensure the accuracy of the calculated age. A strategy for common-Pb correction is proposed according to the age of the zircon and according to the Th/U ratio of the grains. After recording sixteen to twenty spot analyses the precision usually achieved on the age is about 1% and even significantly better for Proterozoic samples.In order to show the performance achieved by modern LA-MC-ICPMS geochronology, we tested four zircon samples covering a wide age range from 290 to 2440 Ma. These new age determinations can be compared in term of precision and accuracy since they have already been dated by reference methods (ID-TIMS and SHRIMP). Further developments in the technology of ion counters equipping modern MC-ICPMS and in laser systems will certainly be applied to a large field of geochronology studies in the near future as an alternative to SIMS for in situ age determination.     

Genesis of monazite and Y zoning in garnet from the Black Hills, South Dakota

The paragenesis of monazite in metapelitic rocks from the contact aureole of the Harney Peak Granite, Black Hills, South Dakota, was investigated using zoning patterns of monazite and garnet, electron microprobe dating of monazite, bulk-rock compositions, and major phase mineral equilibria. The area is characterized by low-pressure and high-temperature metamorphism with metamorphic zones ranging from garnet to sillimanite zones. Garnet porphyroblasts containing euhedral Y annuli are observed from the garnet to sillimanite zones. Although major phase mineral equilibria predict resorption of garnet at the staurolite isograd and regrowth at the andalusite isograd, textural and mass balance analyses suggest that the formation of the Y annuli is not related to the resorption-and-regrowth of garnet having formed instead during garnet growth in the garnet zone. Monazite grains in Black Hills pelites were divided into two generations on the basis of zoning patterns of Y and U: monazite 1 with low-Y and -U and monazite 2 with high-Y and -U. Monazite 1 occurs in the garnet zone and persists into the sillimanite zone as cores shielded by monazite 2 which starts to form in the andalusite zone. Pelites containing garnet porphyroblasts with Y annuli and monazite 1 with patchy Th zoning are more calcic than those with garnet with no Y annuli and monazite with concentric Th zoning. Monazite 1 is attributed to breakdown of allanite in the garnet zone, additionally giving rise to the Y annuli observed in garnet. Monazite 2 grows in the andalusite zone, probably at the expense of garnet and monazite 1 in the andalusite and sillimanite zones. The ages of the two different generations of monazite are within the precision of chemical dating of electron microprobe. The electron microprobe ages of all monazites from the Black Hills show a single ca. 1713 Ma population, close to the intrusion age of the Harney Peak Granite (1715 Ma). This study demonstrates that Y zoning in garnet and monazite are critical to the interpretation of monazite petrogenesis and therefore monazite ages.