Synthetic SH seismograms in a laterally varying medium by the discrete wavenumber method

Summary. We present a new method to calculate the SH wavefield produced by a seismic source in a half-space with an irregular buried interface. The diffracting interface is represented by a distribution of body forces. The Green's functions needed to solve the boundary conditions are evaluated using the discrete wavenumber method. Our approach relies on the introduction of a periodicity in the source-medium configuration and on the discretization of the interface at regular spacing. The technique developed is applicable to boundaries of arbitrary shapes and is valid at all frequencies. Some examples of calculation in simple configurations are presented showing the capabilities of the method.     

A Critical review of theoretical models of negatively polarized light scattered by atmosphereless solar system bodies

About a dozen physical mechanisms and models aspire to explain the negative polarization of light scattered by atmosphereless celestial bodies. This is too large a number for the reliable interpretation of observational data. Through a comparative analysis of the models, our main goal is to answer the question: Does any one model have an advantage over the others? Our analysis is based on new laboratory polarimetric and photometric data as well as on theoretical results. We show that the widely used models due to Hopfield and Wolff cannot realistically explain the phase-angle dependence of the degree of polarization observed at small phase angles. The so-called interference or coherent backscattering mechanism is the most promising model. Models based on that mechanism use well-defined physical parameters to explain both negative polarization and the opposition effect. They are supported by laboratory experiments, particularly those showing enhancement of negative polarization with decreasing particle size down to the wavelength of light. According to the interference mechanism, pronounced negative branches of polarization, like those of C-class asteroids, may indicate a high degree of optical inhomogeneity of light-scattering surfaces at small scales. The mechanism also seems appropriate for treating the negative polarization and opposition effects of cometary dust comae, planetary rings, and the zodiacal light.     

雾化进样石墨炉原子吸收光谱法的研究 Ⅰ.直接雾化进样装置及其性能

介绍一种自行设计和加工的直接雾化石墨炉进样装置的结构、工作原理和操作方法。该装置由微机控制与石墨炉加热程序同步工作,可以实现自动控制和自动测量。对雾化进样石墨炉分析的仪器参数和实验条件进行了研究和选择。结果表明,该装置与石墨炉结合具有自动化程度高、重现性好、样品利用率高和分析速度快等特点。     

Laue diffraction lenses for astrophysics: From theory to experiments

Based on the laws of X-ray diffraction in crystals, Laue lenses offer a promising way to achieve the sensitivity and angular resolution leap required for the next generation of hard X-ray and gamma-ray telescopes.The present paper describes the instrumental responses of Laue diffraction lenses designed for nuclear astrophysics. Different possible geometries are discussed, as well as the corresponding spectral and imaging capabilities. These theoretical predictions are then compared with Monte-Carlo simulations and experimental results (ground and stratospheric observations from the CLAIRE project). PACS 95.55.Ka, 61.50.Ah, 61.10.−i, 41.50.+h     

Techniques to measure grain-size distributions of loamy sediments: a comparative study of ten instruments for wet analysis

Ten instruments for measuring the grain‐size distribution of loamy sediments in water were tested in a comparative study. Instruments tested were: the Malvern Mastersizer S, the Coulter LS 200, the Fritsch Analysette 22 (version C), the Horiba Partica LA‐950, the Sedigraph 5100, the Atterberg cylinder, the Coulter Multisizer 3, the CIS‐100, the EyeTech and the image analysis software Histolab. The first four instruments use laser diffraction. The Sedigraph and Atterberg cylinder are based on sedimentation. The Coulter Multisizer 3 uses impedance measurements and the last three instruments use optical techniques. Grain‐size analyses were carried out on four sediments with median grain diameters of approximately 35, 30, 12 and 9 μm, respectively, and with no particles >90 μm. The laser diffraction instruments produced the best results for the various criteria considered in this study, followed by the Coulter Multisizer 3 (electrical sensing zone technique), the sedimentation techniques and the optical methods. However, the study also showed that there is no such thing as an ‘ideal’ method because techniques may score differently according to the criterion tested. An appropriate evaluation thus requires that various criteria be considered. Issues to be taken into account are: type of sediment, quantity of sediment available, speed of measurement, complexity of the measurement protocol, processing of the data, reproducibility of the results and the specific aims of the study undertaken.     

Dynamic recrystallization near the brittle-plastic transition in naturally and experimentally deformed quartz aggregates

The electron backscattering diffraction technique (EBSD) was used to analyze bulging recrystallization microstructures from naturally and experimentally deformed quartz aggregates, both of which are characterized by porphyroclasts with finely serrated grain boundaries and grain boundary bulges set in a matrix of very fine recrystallized grains. For the Tonale mylonites we investigated, a temperature range of 300–380 °C, 0.25 GPa confining pressure, a flow stress range of ~ 0.1–0.2 GPa, and a strain rate of ~ 10^− 13 s^− 1 were estimated. Experimental samples of Black Hills quartzite were analyzed, which had been deformed in axial compression at 700 °C, 1.2–1.5 GPa confining pressure, a flow stress of ~ 0.3–0.4 GPa, a strain rate of ~ 10^− 6 s^− 1, and to 44% to 73% axial shortening. Using orientation imaging we investigated the dynamic recrystallization microstructures and discuss which processes may contribute to their development. Our results suggest that several deformation processes are important for the dismantling of the porphyroclasts and the formation of recrystallized grains. Grain boundary bulges are not only formed by local grain boundary migration, but they also display a lattice misorientation indicative of subgrain rotation. Dynamic recrystallization affects especially the rims of host porphyroclasts with a hard orientation, i.e. with an orientation unsuitable for easy basal slip. In addition, Dauphiné twins within porphyroclasts are preferred sites for recrystallization. We interpret large misorientation angles in the experimental samples, which increase with increasing strain, as formed by the activity of fluid-assisted grain boundary sliding.     

电感耦合等离子体发射光谱法同时测定玻璃中铝钙铁钾镁钠钛硫

通过选择分析谱线、处理样品方法和消除干扰因素等实验,建立了电感耦合等离子体发射光谱法同时测定玻璃中的Al2O3、CaO、Fe2O3、K2O、MgO、Na2O、TiO2和SO3的方法,克服了利用常规化学法测定玻璃中各氧化物步骤繁琐、耗时长、工作量大的不足。方法的回收率为95.0%~103.0%,精密度(RSD,n=10)为0.20%~1.72%。方法具有快速、简便、线性范围宽等优点,分析误差满足常规化学分析法的要求。用于钠钙硅玻璃及其制品的分析,结果令人满意。     

氢化物发生-原子荧光光谱法直接测定地球化学样品中痕量碲

采用硝酸-氢氟酸-高氯酸溶解样品,以Fe3+作减缓剂,不需分离富集,用氢化物发生-原子荧光光谱法直接测定地球化学样品中痕量碲。对测定介质、KBH4浓度、铁盐的作用等条件进行试验。方法检出限为0.0031μg/g,精密度(RSD,n=11)<6.10%。方法用于国家一级地球化学标准物质中痕量碲的测定,结果与标准值一致。     

纺织品中偶氮染料还原液内芳香胺的电喷雾电离质谱分析

在优化的条件下,用电喷雾电离质谱(ESI-MS)检测了多种纺织品中由偶氮染料还原获得的芳香胺。当毛细管温度为100℃、鞘气流速为25单位、进样流速为10μL/min、电压为5kV时,信号的总离子流强度高且较稳定。实验分析了19种致癌芳香胺标准溶液的二级质谱,获得了相应物质的特征碎片离子;在此基础上,建立了基于ESI-MS对毛巾、棉布等样品中芳香胺进行快速定性分析的方法,具有灵敏度高、特异性好、检测速度快等优点。     

能量色散X射线荧光光谱法测定钼矿石中钼铅铁铜

建立了能量色散X射线荧光光谱法测定钼矿石中钼、铅、铁、铜的方法,讨论了粒度效应、矿物效应的影响因素,确定了采取粉末样品,用系列标准样品建立工作曲线,通过元素间相互校正消除基体效应,用内控标准样品考察了方法的精密度(RSD,n=11)为0.44%～15.4%。实际样品的测定结果和化学法相符,可满足日常分析工作需要。