荧光光谱学在象牙与猛犸象牙鉴定上的应用

利用红外光谱仪及荧光分光光度计对象牙和猛犸象牙样品进行测试,通过对测试结果的比对、分析,总结二者的谱图特点,旨在探索更准确的象牙与猛犸象牙的检测方法.猛犸象牙内部由于受石化作用小,其红外光谱与象牙的没有本质区别,因此红外光谱仪在象牙饰品与猛犸象牙饰品的检测上难以提供准确信息.荧光光谱的测试结果显示,在280 nm波长光的激发下,由于象牙和猛犸象牙中的氨基酸在微环境及其质量分数不同,象牙的发射光谱峰值在307 nm处,猛犸象牙的发射光谱峰值在315 nm处,且象牙的荧光强度高于猛犸象牙.同步荧光光谱测试中△λ分别取15,60 nm,分别测试样品中的酪氨酸、色氨酸,测试结果显示两类牙质测试图谱谱形一致但强度差异明显,即荧光分光光度计在象牙和猛犸象牙的检测上可提供有效的信息.     

A Middle Devensian woolly rhinoceros (Coelodonta antiquitatis) from Whitemoor Haye Quarry,Staffordshire (UK): palaeoenvironmental context and significance

This paper reports the discovery of a rare partial skeleton of a woolly rhinoceros (Coelodonta antiquitatis Blumenbach, 1799) and associated fauna from a low Pleistocene terrace of the River Tame at Whitemoor Haye, Staffordshire, UK. A study of the sedimentary deposits around the rhino skeleton and associated organic‐rich clasts containing pollen, plant and arthropod remains suggests that the animal was rapidly buried on a braided river floodplain surrounded by a predominantly treeless, herb‐rich grassland. Highlights of the study include the oldest British chironomid record published to date and novel analysis of the palaeoflow regime using caddisfly remains. For the first time, comparative calculations of coleopteran and chironomid palaeotemperatures have been made on the same samples, suggesting a mean July temperature of 8–11 °C and a mean December temperature of between ?22 and ?16 °C. Radiocarbon age estimates on skeletal material, supported by optically stimulated luminescence ages from surrounding sediments, indicate that the rhino lived around 41–43 k cal a BP. The combined geochronological, stratigraphic and palaeoenvironmental evidence places the assemblage firmly within the Middle Devensian (Marine Oxygen Isotope Stage 3). This would agree with other regional evidence for the timing of aggradation for the lowest terrace of the Trent and its tributary systems. Copyright © 2012 John Wiley & Sons, Ltd.     

Holes in the spinous processes of woolly mammoth vertebrae: spatial and temporal distribution,and the causes of pathology formation

The latest data on holes in the spinous processes of the vertebrae of woolly mammoths, a rare pathology, are presented. This was identified at 19 sites of northern Eurasia. Such destructive changes are recorded ca. 34–12k ¹⁴C a bp , and only two sites dated to >50k and >41k ¹⁴C a bp. The main hypotheses about hole formation are: vertebral abnormalities; bone infections; genetic traits; and unfavourable geochemical environment. The pathology occurred in mammoths of all age groups, and could have arisen at the embryonic stage. There are two types: classic holes associated with osteolytic changes; and very rarely tumour-like lesions. The most likely cause of the lesions is alimentary osteodystrophy caused by chronic mineral starvation. The aetiology of this disease is usually associated with a deficiency or excess of macro- and microelements in the geochemical landscape, and through forage and water this leads to a severe metabolic disorder. Analysis of palaeopathological data shows two waves of geochemical stress in animals, ca. 26–18k and ca. 16–12k ¹⁴C a bp. Therefore, the woolly mammoth extinction can be viewed as a non-linear function, with two peaks of high mortality corresponding to the Last Glacial Maximum and the Lateglacial.     

猛犸牙与象牙的微生长结构及红外吸收光谱的差异性

猛犸象属古脊椎动物,其现存的猛犸牙多呈半化石状态。采用SEM,FTIR等分析测试仪器对猛犸牙和象牙的微生长结构、胶原蛋白等差异特征进行了研究。结果表明,象牙和猛犸牙主要由胶原蛋白和羟基磷酸钙组成,由胶原蛋白酰胺键致特征的红外吸收谱带分别位于1 663 cm-1（νC-O）,1 558 cm-1（νC-H）和1 240 cm-1（δN-H）处。石化作用导致胶原蛋白酰胺键受到不同程度的破坏,致使猛犸牙中胶原蛋白的红外吸收谱带强度递减。象牙与猛犸牙指向牙心的两组粗勒兹纹理的夹角存在着明显的差异,前者的最大夹角〉120°,后者的最大夹角〈95°。象牙的粗勒兹纹层具纤束状交织结构,结构致密、坚韧、细腻;猛犸牙的粗勒兹纹层多具叶片状结构,胶原蛋白纤束体数量明显减少,结构疏松,质地干涩,孔隙度增大,微裂隙发育,韧性变差。     

Pleistocene fluvial sediments,palaeontology and archaeology of the upper River Thames at Latton,Wiltshire, England

Pleistocene fluvial sediments of the Northmoor Member of the Upper Thames Formation exposed at Latton, Wiltshire, record episodic deposition close to the Churn–Thames confluence possibly spanning the interval from Marine Isotope Stages (MIS) 7 to 2. The sequence is dominated by gravel facies, indicating deposition by a high‐energy, gravel‐bed river. A number of fine‐grained organic sediment bodies within the sequence have yielded palaeoenvironmental and biostratigraphical data from Mollusca, Coleoptera, vertebrates, pollen and plant macrofossils. The basal deposit (Facies Association A) contains faunal material indicating temperate conditions. Most of the palaeontological evidence including a distinctive small form of mammoth (Mammuthus cf. trogontherii), together with the U‐series age estimate of >147.4 ± 20 kyr suggest correlation with MIS 7. The overlying deposits (Facies Associations B and C) represent deposition under a range of climatic conditions. Two fine‐grained organic deposits occurred within Association B; one (Association Ba) in the northern part of the pit as a channel fill and the other (Association Bb) in its southern part as a scour‐fill deposit. The coleopteran assemblages from Ba, indicate that it accumulated under temperate oceanic conditions, while Bb, which also yielded a radiocarbon age estimate of 39 560 ± 780 ¹⁴C yr BP, was formed under much colder and more continental climatic conditions. The sequence is considered to represent deposition within an alluvial fan formed at the Churn–Thames confluence; a depositional scenario which may account for the juxtaposition of sediments and fossils of widely differing age within the same altitudinal range. Copyright © 2006 John Wiley & Sons, Ltd.     

Freshwater organic deposits and stratified sediments between Early and Late Midlandian (Devensian) till sheets,at Aghnadarragh,County Antrim,Northern Ireland

The following events have been identified from a complex sequence of Midlandian (Devensian) sediments recently exposed at Aghnadarragh, County Antrim: (1) A lower till interpreted as Early Midlandian was deposited by a major lowland ice sheet which moved south-eastwards from central Ulster across the Lough Neagh depression. (2) Deglacial conditions were followed by a periglacial phase characterised by ice-wedge growth and sedimentation by gravelly debris flows. The latter contain the oldest known remains of Mammuthus primigenius in Ireland. (3) An Early Midlandian interstadial is represented by a woody detritus peat, with evidence of Betula, Pinuos and Picea woodlands and a rich beetle fauna. Wood from this horizon has been shown to be beyond the range of radiocarbon dating (>48 180 BP). (4) Interstadial conditions were succeeded by a cold, non-glacial phase dominated by in-channel gravelly flows and deposition of organic muds which contain plant and insect fossils. These horizons are older than 46 850 BP. (5) An upper, non-drumlinised till was deposited during the Late-Midlandian by a major lowland ice sheet which moved generally eastwards across the Lough Neagh Lowlands from central Ulster. This glaciation probably reached its maximum at ca 20–24 ka. (6) Drumlin formation occurred in the Lough Neagh Lowlands towards the end of the Late-Midlandian. The limiting moraines are dated to 17 ka. The lower till at Aghnadarragh is the first positive record of a major lowland ice sheet in Ireland during the early part of the last cold stage. The Early Midlandian interstadial peats have not been documented elsewhere in Ireland and correlate broadly with the Chelford Interstadial complex of the English Midlands. Related exposures elsewhere in Ulster confirm that the middle part of the last cold stage was free of major lowland ice masses but deposits of this period are absent from Aghnadarragh.     

Patterns of faunal extinction and paleoclimatic change from mid-Holocene mammoth and polar bear remains, Pribilof Islands, Alaska

Qagnaxˆ Cave, a lava tube cave on St. Paul Island in the Pribilofs, has recently produced a mid-Holocene vertebrate faunal assemblage including woolly mammoth, polar bear, caribou, and Arctic fox. Several dates on the mammoth remains converge on 5700 ¹⁴C yr BP. These dates, ~ 2300 yr younger than mammoth dates previously published from the Pribilof Islands, make these the youngest remains of proboscideans, and of non-extinct Quaternary megafauna, recovered from North America. Persistence of mammoths on the Pribilofs is most parsimoniously explained by the isolation of the Pribilofs and the lack of human presence in pre-Russian contact times, but an additional factor may have been the local existence of high-quality forage in the form of grasses enriched by nutrients derived from local Holocene tephras. This interpretation is reinforced by stable carbon and nitrogen isotope values obtained from the mammoth remains. The endpoint of mammoth survival in the Pribilofs is unknown, but maybe coterminous with the arrival of polar bears whose remains in the cave date to the Neoglacial cold period of ~ 4500 to 3500 ¹⁴C yr BP. The polar bear record corroborates a widespread cooling of the Bering Sea region at that time.     

Late middle pleistocene interglacial deposits at upper strensham,worcestershire, england

Pleistocene deposits containing the disarticulated skeleton of a mammoth, and associated faunal and floral remains, were discovered in July 1990 at Upper Strensham, Worcestershire. The environmental evidence from the fauna and flora together with limited geological evidence, indicates that the deposits accumulated within a low energy fluvial environment with a surrounding marsh and restricted tree cover on, or close to, the floodplain. The patchy occurrence of trees in a species-rich grassland is discussed, and the climatic significance of the fauna and flora is considered. The Strensham site lies within the valley of the River Avon, which is known to contain at least five altitudinally distinct river terraces. The deposits at Strensham lie beneath a terraced surface that cannot be accommodated within the existing framework of terrace development in the valley, and evidence is presented which may suggest that these deposits form a previously unrecognised fluvial unit, the Strensham Member of the Avon Valley Formation. Amino-acid age estimates from shells taken from the fossiliferous sediments of the Strensham Member suggest a correlation with Oxygen Isotope Stage 7. This correlation suggests that the temperate deposits at this site should be correlated with the temperate phase recorded at Marsworth, Buckinghamshire and Stoke Goldington in the valley of the Great Ouse.